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High temperature calorimetry and use of magnesium chloride for thermal energy storage

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  • Zhao, Weihuan
  • Zheng, Ying
  • Sabol, Joseph C.
  • Tuzla, Kemal
  • Neti, Sudhakar
  • Oztekin, Alparslan
  • Chen, John C.

Abstract

The primary objective of this study is to develop encapsulated phase change materials (EPCMs) capable of storing thermal energy at temperatures above 750 °C. EPCM with magnesium chloride as phase change material (PCM) are considered here for application in concentrated solar power (CSP) systems. MgCl2 is an effective storage medium because of its high melting temperature, 714 °C, and high latent heat of fusion, 454 kJ/kg. A specialized calorimeter with requisite size and high temperature capability is designed and built to prove the storage capability of MgCl2 EPCM. The calorimeter is also used to determine heat capacities for MgCl2 in both liquid and solid states as well as its latent heat of fusion. Calorimetric tests for the thermal storage capacities of three MgCl2 EPCM samples show excellent agreement with published data. Based on the measured properties, the latent heat of phase change can contribute about 84% of the storage capacity of MgCl2 PCM for a 100 °C temperature swing bracketing the salt's melting point. Repeated thermal-cycles show sustained performance of MgCl2 EPCM capsules with no discernible diminishment in storage capacity.

Suggested Citation

  • Zhao, Weihuan & Zheng, Ying & Sabol, Joseph C. & Tuzla, Kemal & Neti, Sudhakar & Oztekin, Alparslan & Chen, John C., 2013. "High temperature calorimetry and use of magnesium chloride for thermal energy storage," Renewable Energy, Elsevier, vol. 50(C), pages 988-993.
    • Handle: RePEc:eee:renene:v:50:y:2013:i:c:p:988-993
    DOI: 10.1016/j.renene.2012.08.036
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    References listed on IDEAS

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    1. Kenisarin, Murat & Mahkamov, Khamid, 2007. "Solar energy storage using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1913-1965, December.
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    1. Zhu, Ming & Nan, Wenguang & Wang, Yueshe, 2023. "Analysis on the thermal behaviour of the latent heat storage system using S-CO2 and H-PCM," Renewable Energy, Elsevier, vol. 208(C), pages 240-250.
    2. Jacob, Rhys & Bruno, Frank, 2015. "Review on shell materials used in the encapsulation of phase change materials for high temperature thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 79-87.
    3. Solomon, Laura & Elmozughi, Ali F. & Oztekin, Alparslan & Neti, Sudhakar, 2015. "Effect of internal void placement on the heat transfer performance – Encapsulated phase change material for energy storage," Renewable Energy, Elsevier, vol. 78(C), pages 438-447.
    4. Songgang Qiu & Laura Solomon & Garrett Rinker, 2017. "Development of an Integrated Thermal Energy Storage and Free-Piston Stirling Generator for a Concentrating Solar Power System," Energies, MDPI, vol. 10(9), pages 1-17, September.
    5. Gupta, Rajan & Shinde, Shraddha & Yella, Aswani & Subramaniam, C. & Saha, Sandip K., 2020. "Thermomechanical characterisations of PTFE, PEEK, PEKK as encapsulation materials for medium temperature solar applications," Energy, Elsevier, vol. 194(C).
    6. Jacob, Rhys & Belusko, Martin & Liu, Ming & Saman, Wasim & Bruno, Frank, 2019. "Using renewables coupled with thermal energy storage to reduce natural gas consumption in higher temperature commercial/industrial applications," Renewable Energy, Elsevier, vol. 131(C), pages 1035-1046.
    7. Amaral, C. & Vicente, R. & Marques, P.A.A.P. & Barros-Timmons, A., 2017. "Phase change materials and carbon nanostructures for thermal energy storage: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1212-1228.
    8. Songgang Qiu & Laura Solomon & Ming Fang, 2018. "Study of Material Compatibility for a Thermal Energy Storage System with Phase Change Material," Energies, MDPI, vol. 11(3), pages 1-18, March.

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