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Corrosion behaviors of metals in biodiesel from rapeseed oil and methanol

Author

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  • Hu, Enzhu
  • Xu, Yufu
  • Hu, Xianguo
  • Pan, Lijun
  • Jiang, Shaotong

Abstract

The effect of biodiesel fuel made from rapeseed oil and methanol on the corrosion properties of copper, mild carbon steel, aluminum, and stainless steel was studied and compared with those of commercial diesel fuel. The results show that the metals mentioned above corroded with variable degrees as they were immersed in the biodiesel fuel at 43°C for 60 days. Their corrosion rates were 0.02334, 0.01819, 0.00324, and 0.00087mm/year, respectively. However, the corrosion rates of the metals immersed in commercial diesel fuel were relatively lower under the same corrosion conditions. The effects of biodiesel on the corrosion of copper and mild carbon steel were more significant than on aluminum and stainless steel. The corrosion process of metal surfaces in the biodiesel was mainly attributed to the chemical corrosion according to the experimental results with the help of SEM/EDS, AAS, and XPS.

Suggested Citation

  • Hu, Enzhu & Xu, Yufu & Hu, Xianguo & Pan, Lijun & Jiang, Shaotong, 2012. "Corrosion behaviors of metals in biodiesel from rapeseed oil and methanol," Renewable Energy, Elsevier, vol. 37(1), pages 371-378.
    • Handle: RePEc:eee:renene:v:37:y:2012:i:1:p:371-378
    DOI: 10.1016/j.renene.2011.07.010
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    Cited by:

    1. Serqueira, Dalyelli S. & Pereira, Jian F.S. & Squissato, André L. & Rodrigues, Mônica A. & Lima, Renata C. & Faria, Anízio M. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2021. "Oxidative stability and corrosivity of biodiesel produced from residual cooking oil exposed to copper and carbon steel under simulated storage conditions: Dual effect of antioxidants," Renewable Energy, Elsevier, vol. 164(C), pages 1485-1495.
    2. Rochelle, David & Najafi, Hamidreza, 2019. "A review of the effect of biodiesel on gas turbine emissions and performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 105(C), pages 129-137.
    3. Rocabruno-Valdés, C.I. & González-Rodriguez, J.G. & Díaz-Blanco, Y. & Juantorena, A.U. & Muñoz-Ledo, J.A. & El-Hamzaoui, Y. & Hernández, J.A., 2019. "Corrosion rate prediction for metals in biodiesel using artificial neural networks," Renewable Energy, Elsevier, vol. 140(C), pages 592-601.
    4. Nasha Wei & Zhi Chen & Yuandong Xu & Fengshou Gu & Andrew Ball, 2021. "The Investigation into the Tribological Impact of Alternative Fuels on Engines Based on Acoustic Emission," Energies, MDPI, vol. 14(8), pages 1-20, April.
    5. Sundus, F. & Fazal, M.A. & Masjuki, H.H., 2017. "Tribology with biodiesel: A study on enhancing biodiesel stability and its fuel properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 399-412.
    6. Jin, Dingfeng & Zhou, Xuehua & Wu, Panpan & Jiang, Li & Ge, Hongliang, 2015. "Corrosion behavior of ASTM 1045 mild steel in palm biodiesel," Renewable Energy, Elsevier, vol. 81(C), pages 457-463.
    7. Xu, Yufu & Peng, Yubin & Zheng, Xiaojing & Dearn, Karl D. & Xu, Hongming & Hu, Xianguo, 2015. "Synthesis and tribological studies of nanoparticle additives for pyrolysis bio-oil formulated as a diesel fuel," Energy, Elsevier, vol. 83(C), pages 80-88.
    8. Kugelmeier, Cristie Luis & Monteiro, Marcos Roberto & da Silva, Rodrigo & Kuri, Sebastião Elias & Sordi, Vitor Luiz & Della Rovere, Carlos Alberto, 2021. "Corrosion behavior of carbon steel, stainless steel, aluminum and copper upon exposure to biodiesel blended with petrodiesel," Energy, Elsevier, vol. 226(C).
    9. Fernandes, David M. & Squissato, André L. & Lima, Alexandre F. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2019. "Corrosive character of Moringa oleifera Lam biodiesel exposed to carbon steel under simulated storage conditions," Renewable Energy, Elsevier, vol. 139(C), pages 1263-1271.
    10. Carmen Mata & Jakub Piaszyk & José Antonio Soriano & José Martín Herreros & Athanasios Tsolakis & Karl Dearn, 2020. "Impact of Alternative Paraffinic Fuels on the Durability of a Modern Common Rail Injection System," Energies, MDPI, vol. 13(16), pages 1-14, August.
    11. M. Shahabuddin & M. Mofijur & Md. Bengir Ahmed Shuvho & M. A. K. Chowdhury & M. A. Kalam & H. H. Masjuki & M. A. Chowdhury, 2021. "A Study on the Corrosion Characteristics of Internal Combustion Engine Materials in Second-Generation Jatropha Curcas Biodiesel," Energies, MDPI, vol. 14(14), pages 1-15, July.
    12. Aamir Shehzad & Arslan Ahmed & Moinuddin Mohammed Quazi & Muhammad Jamshaid & S. M. Ashrafur Rahman & Masjuki Haji Hassan & Hafiz Muhammad Asif Javed, 2021. "Current Research and Development Status of Corrosion Behavior of Automotive Materials in Biofuels," Energies, MDPI, vol. 14(5), pages 1-36, March.
    13. Li, Yu & Tan, Zhiwu & Zhu, Youjian & Zhang, Wennan & Du, Zhenyi & Shao, Jingai & Jiang, Long & Yang, Haiping & Chen, Hanping, 2022. "Effects of P-based additives on agricultural biomass torrefaction and particulate matter emissions from fuel combustion," Renewable Energy, Elsevier, vol. 190(C), pages 66-77.
    14. Chen, Tao & Hu, Run-Ze & Yao, Xiao-Hui & Yang, Qiang & Shuai, Shi-Min & Wang, Jun & Xu, Ming & Zhang, Dong-Yang & Fu, Yu-Jie & Li, Long & Zhao, Wei-Guo, 2020. "Effect of Pyrola extract on the stability of palm biodiesel upon exposure to copper," Renewable Energy, Elsevier, vol. 149(C), pages 1282-1289.
    15. Thangavelu, Saravana Kannan & Ahmed, Abu Saleh & Ani, Farid Nasir, 2016. "Impact of metals on corrosive behavior of biodiesel–diesel–ethanol (BDE) alternative fuel," Renewable Energy, Elsevier, vol. 94(C), pages 1-9.
    16. Saluja, Rajesh Kumar & Kumar, Vineet & Sham, Radhey, 2016. "Stability of biodiesel – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 866-881.

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    Keywords

    Biodiesel; Diesel; Metal; Corrosion;
    All these keywords.

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