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Analysis of thermal properties of gypsum materials incorporated with microencapsulated phase change materials based on silica

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  • Zhang, Yi
  • Tao, Wen
  • Wang, Kehan
  • Li, Dongxu

Abstract

Microencapsulated phase change materials (MePCMs) were prepared in this study through sol-gel synthesis; these materials consisted of SiO2 as shell and paraffin as core materials, and were subsequently incorporated in gypsum. Further, this study examined the thermal regulation performance of gypsum materials. Fourier transform infrared spectra confirmed the encapsulation of the paraffin with SiO2 shell. Scanning electron microscope (SEM) results showed that the microcapsules obtained at a pH of 2.5 exhibit a regular spherical structure, excellent dispersibility, and compact surface structure. The MePCMs were found to reveal high thermal performance and encapsulation efficiency even in this synthetic condition. This is because the SiO2 shell with its high compactness imparts high thermal stability and a good anti-osmosis performance to the microcapsules. Further, gypsum materials achieved high mechanical strength, compactness, thermal conductivity, and a good thermal regulation performance with the weight ratio of MePCMs at 10 wt%. The results showed that the MePCMs in the gypsum matrix exhibited advantageous application prospects for the thermal regulation in buildings.

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  • Zhang, Yi & Tao, Wen & Wang, Kehan & Li, Dongxu, 2020. "Analysis of thermal properties of gypsum materials incorporated with microencapsulated phase change materials based on silica," Renewable Energy, Elsevier, vol. 149(C), pages 400-408.
    • Handle: RePEc:eee:renene:v:149:y:2020:i:c:p:400-408
    DOI: 10.1016/j.renene.2019.12.051
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    2. Musavi, Seyed Mostapha & Barahuie, Farahnaz & Irani, Mohsen & Safamanesh, Ali & Malekpour, Abdurahman, 2021. "Enhanced properties of phase change material -SiO2-graphene nanocomposite for developing structural–functional integrated cement for solar energy absorption and storage," Renewable Energy, Elsevier, vol. 174(C), pages 918-927.
    3. Tao, Jialu & Luan, Jingde & Liu, Yue & Qu, Daoyu & Yan, Zheng & Ke, Xin, 2022. "Technology development and application prospects of organic-based phase change materials: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    4. Wang, Linqiang & Liang, Weidong & Wang, Chengjun & Fan, Yukang & Liu, Yi & Xiao, Chaohu & Sun, Hanxue & Zhu, Zhaoqi & Li, An, 2021. "Dodecylamine/Ti3C2-pectin form-stable phase change composites with enhanced light-to-thermal conversion and mechanical properties," Renewable Energy, Elsevier, vol. 176(C), pages 663-674.

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