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Hydrodeoxygenation of phenols, acids, and ketones as model bio-oil for hydrocarbon fuel over Ni-based catalysts modified by Al, La and Ga

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  • Li, Zhiyu
  • Jiang, Enchen
  • Xu, Xiwei
  • Sun, Yan
  • Tu, Ren

Abstract

The large-scale application of bio-oil has been restricted due to its high O content, strong acidity and low heat value. Therefore, the hydrodeoxygenation (HDO) of phenols, acids, and ketones as bio-oil model compounds for hydrocarbon fuel via Ni-based catalysts modified by metal oxides (Al, La and Ga) was investigated. The results showed that the hydrocarbon content was over 70.65% when the mixed supported catalysts Ni/HZSM-5-γ-Al2O3, Ni/HBeta-La2O3 and Ni/HBeta-Ga2O3 were used for the HDO of guaiacol (GUA). Cyclic hydrocarbons and aromatic hydrocarbons were the main products. Among these catalysts, Ni/HZSM-5-γ-Al2O3 was the most effective in the HDO of acetic acid. The conversion and hydrocarbon content were 100.00% and 88.62%, respectively. Long-chain alkanes were the main components of the upgraded liquid. Ni/HZSM-5-γ-Al2O3 was beneficial for the HDO of hydroxyacetone with 100.00% conversion, 80.30% hydrocarbon content and 48.67% yield. The HDO pathways of GUA, acetic acid and hydroxyacetone were as follows: 1) GUA was mainly converted into benzene and its derivatives by transmethylation, isomerization and hydrogenation (HYD). 2) Acetic acid was converted to long-chain alkanes by HYD, self-condensation, saturated HYD and isomerization. 3) Hydroxyacetone was converted into long-chain alkanes by HYD, self-condensation, demethylation, aldol condensation and saturated HYD. This work provides basic data for obtaining renewable hydrocarbon fuel from biomass via HDO with a low-cost catalyst.

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  • Li, Zhiyu & Jiang, Enchen & Xu, Xiwei & Sun, Yan & Tu, Ren, 2020. "Hydrodeoxygenation of phenols, acids, and ketones as model bio-oil for hydrocarbon fuel over Ni-based catalysts modified by Al, La and Ga," Renewable Energy, Elsevier, vol. 146(C), pages 1991-2007.
    • Handle: RePEc:eee:renene:v:146:y:2020:i:c:p:1991-2007
    DOI: 10.1016/j.renene.2019.08.012
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    1. Xu, Xiwei & Jiang, Enchen & Du, Yanhong & Li, Bosong, 2016. "BTX from the gas-phase hydrodeoxygenation and transmethylation of guaiacol at room pressure," Renewable Energy, Elsevier, vol. 96(PA), pages 458-468.
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    Cited by:

    1. Tran, Quoc Khanh & Ly, Hoang Vu & Kwon, Byeongwan & Kim, Seung-Soo & Kim, Jinsoo, 2021. "Catalytic hydrodeoxygenation of guaiacol as a model compound of woody bio-oil over Fe/AC and Ni/γ-Al2O3 catalysts," Renewable Energy, Elsevier, vol. 173(C), pages 886-895.
    2. Lv, Wei & Hu, Xiaohong & Zhu, Yuting & Xu, Ying & Liu, Shijun & Chen, Peili & Wang, Chenguang & Ma, Longlong, 2022. "Molybdenum oxide decorated Ru catalyst for enhancement of lignin oil hydrodeoxygenation to hydrocarbons," Renewable Energy, Elsevier, vol. 188(C), pages 195-210.
    3. Kuang, Yongqi & Li, Hao, 2021. "Targeted engineering of metal@hollow carbon spheres as nanoreactors for biomass hydrodeoxygenation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).

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