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Magnetic biochar obtained through catalytic pyrolysis of macroalgae: A promising anode material for Li-ion batteries

Author

Listed:
  • Salimi, Pejman
  • Norouzi, Omid
  • Pourhoseini, S.E.M.
  • Bartocci, Pietro
  • Tavasoli, Ahmad
  • Di Maria, Francesco
  • Pirbazari, S.M.
  • Bidini, Gianni
  • Fantozzi, Francesco

Abstract

In this work, Cladophora glomerata, a harmful seaweed, is converted into an olive-shaped magnetic biochar by a slow pyrolysis process catalyzed by iron. The resultant magnetic biochar has a high surface area of 296.4 m2 g−1 with a carbon-rich structure that makes it suitable to be used as an electrode in Li-ion batteries. The catalytic pyrolysis process showed significant effect on steam reforming, ketonization and deoxygenation and/or denitrogenation reactions. The overall quality of the pyrolysis products increases: the gas contains a higher percentage of hydrogen (up to 22%), while the oil is enriched in furans (with a selectivity of about 14%). The electrochemistry behavior of magnetic biochar has been also evaluated, using galvanostatic charge–discharge, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) analyses. The electrochemical results indicated a higher initial specific discharge capacity (740 mAh g−1) and great cyclic stability for magnetic electrode as compared to the biochar electrode.

Suggested Citation

  • Salimi, Pejman & Norouzi, Omid & Pourhoseini, S.E.M. & Bartocci, Pietro & Tavasoli, Ahmad & Di Maria, Francesco & Pirbazari, S.M. & Bidini, Gianni & Fantozzi, Francesco, 2019. "Magnetic biochar obtained through catalytic pyrolysis of macroalgae: A promising anode material for Li-ion batteries," Renewable Energy, Elsevier, vol. 140(C), pages 704-714.
    • Handle: RePEc:eee:renene:v:140:y:2019:i:c:p:704-714
    DOI: 10.1016/j.renene.2019.03.077
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    3. Malyan, Sandeep K. & Kumar, Smita S. & Fagodiya, Ram Kishor & Ghosh, Pooja & Kumar, Amit & Singh, Rajesh & Singh, Lakhveer, 2021. "Biochar for environmental sustainability in the energy-water-agroecosystem nexus," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    4. Li, Dong & Guo, Yanchuan & Li, Yi & Liu, Zhengang & Chen, Zeliang, 2022. "Waste-biomass tar functionalized carbon spheres with N/P Co-doping and hierarchical pores as sustainable low-cost energy storage materials," Renewable Energy, Elsevier, vol. 188(C), pages 61-69.
    5. Apip Amrullah & Obie Farobie & Asep Bayu & Novi Syaftika & Edy Hartulistiyoso & Navid R. Moheimani & Surachai Karnjanakom & Yukihiko Matsumura, 2022. "Slow Pyrolysis of Ulva lactuca (Chlorophyta) for Sustainable Production of Bio-Oil and Biochar," Sustainability, MDPI, vol. 14(6), pages 1-14, March.

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