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A single-phase transesterification of linseed oil using different co-solvents and hydrogel in the presence of calcium oxide: An optimization study

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  • Gargari, M. Hashemzadeh
  • Sadrameli, S.M.

Abstract

A single-phase transesterification of linseed oil has been investigated in the presence of heterogeneous base catalyst (CaO) with different co-solvents and hydrogel as a water absorber. Di-ethyl ether, tetrahydrofuran, biodiesel, n-hexane were depleted as co-solvents to improve the mutual solubility of the oil and methanol. The molar ratio of methanol to oil, the molar ratio of co-solvent to methanol, and catalyst concentration are among the integral parameters that influence the FAME yield. The results of transesterification processes with co-solvent and without co-solvent were compared with each other, thus, T-test and F-test depicted striking level of modification. Response surface methodology was carried out to optimize the main process parameters. The maximum FAME yield of 98.77% was reached under the following optimum conditions: molar ratio of methanol to oil 9.41:1, molar ratio of DEE to methanol of 1.11:1, catalyst concentration of 0.98 wt%, temperature of 30 °C, agitation rate of 650 rpm, and reaction time of 60 min.

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  • Gargari, M. Hashemzadeh & Sadrameli, S.M., 2019. "A single-phase transesterification of linseed oil using different co-solvents and hydrogel in the presence of calcium oxide: An optimization study," Renewable Energy, Elsevier, vol. 139(C), pages 426-434.
    • Handle: RePEc:eee:renene:v:139:y:2019:i:c:p:426-434
    DOI: 10.1016/j.renene.2019.02.086
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    1. Bahadorian, Amirmahdi & Sadrameli, Seyed Mojtaba & Pahlavanzadeh, Hassan & Ilani Kashkouli, Mohammad Nabi, 2023. "Optimization study of linseed biodiesel production via in-situ transesterification and slow pyrolysis of obtained linseed residue," Renewable Energy, Elsevier, vol. 203(C), pages 10-19.

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