IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v114y2017ipbp733-743.html
   My bibliography  Save this article

A calcium chloride hexahydrate/expanded perlite composite with good heat storage and insulation properties for building energy conservation

Author

Listed:
  • Fu, Lulu
  • Wang, Qianhao
  • Ye, Rongda
  • Fang, Xiaoming
  • Zhang, Zhengguo

Abstract

A porous supporting matrix, expanded perlite (EP) is composited with a salt hydrate mixture of CaCl2·6H2O and SrCl2·6H2O (98:2 in mass ratio), to develop a nonflammable thermal storage material for building use. The salt hydrate is uniformly adsorbed on sheets of EP, and a maximum absorption capacity test shows EP can contain as high as 55 wt% the salt hydrate and keep the stable form. It is shown that the melting temperature of the composite PCM is 27.38 °C, close to that of CaCl2·6H2O, and its latent heat is 87.44 J/g, equivalent to the calculated value based on the mass fraction of CaCl2·6H2O in the composite. EP further reduces the salt hydrate thermal conductivity by over 70% to enhance its thermal insulation, and suppresses the supercooling. A 1000 heating-cooling cycles test verifies the CaCl2·6H2O/EP composite possesses good thermal reliability. The CaCl2·6H2O/EP composite is then fabricated into a board for replacing the foam board employed as the core in a commercial foam insulating brick to obtain a PCM brick. It is found that, when applied as the roof of a test room, the PCM brick has the function of decreasing the indoor peak temperature and causing the hysteresis in the indoor temperature rise, compared with the foam insulation brick. The nonflammability along with good thermal storage and insulation properties makes the CaCl2·6H2O/EP composite PCM show great promises for use in building energy conservation.

Suggested Citation

  • Fu, Lulu & Wang, Qianhao & Ye, Rongda & Fang, Xiaoming & Zhang, Zhengguo, 2017. "A calcium chloride hexahydrate/expanded perlite composite with good heat storage and insulation properties for building energy conservation," Renewable Energy, Elsevier, vol. 114(PB), pages 733-743.
    • Handle: RePEc:eee:renene:v:114:y:2017:i:pb:p:733-743
    DOI: 10.1016/j.renene.2017.07.091
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148117307188
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2017.07.091?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Karaipekli, Ali & Sarı, Ahmet, 2008. "Capric–myristic acid/expanded perlite composite as form-stable phase change material for latent heat thermal energy storage," Renewable Energy, Elsevier, vol. 33(12), pages 2599-2605.
    2. Cabeza, L.F. & Castell, A. & Barreneche, C. & de Gracia, A. & Fernández, A.I., 2011. "Materials used as PCM in thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1675-1695, April.
    3. Biswas, Kaushik & Lu, Jue & Soroushian, Parviz & Shrestha, Som, 2014. "Combined experimental and numerical evaluation of a prototype nano-PCM enhanced wallboard," Applied Energy, Elsevier, vol. 131(C), pages 517-529.
    4. Koca, Ahmet & Oztop, Hakan F. & Koyun, Tansel & Varol, Yasin, 2008. "Energy and exergy analysis of a latent heat storage system with phase change material for a solar collector," Renewable Energy, Elsevier, vol. 33(4), pages 567-574.
    5. Li, Wei & Zhang, Rong & Jiang, Nan & Tang, Xiao-fen & Shi, Hai-feng & Zhang, Xing-xiang & Zhang, Yuankai & Dong, Lin & Zhang, Ningxin, 2013. "Composite macrocapsule of phase change materials/expanded graphite for thermal energy storage," Energy, Elsevier, vol. 57(C), pages 607-614.
    6. Ye, Hong & Long, Linshuang & Zhang, Haitao & Zou, Ruqiang, 2014. "The performance evaluation of shape-stabilized phase change materials in building applications using energy saving index," Applied Energy, Elsevier, vol. 113(C), pages 1118-1126.
    7. Ramakrishnan, Sayanthan & Sanjayan, Jay & Wang, Xiaoming & Alam, Morshed & Wilson, John, 2015. "A novel paraffin/expanded perlite composite phase change material for prevention of PCM leakage in cementitious composites," Applied Energy, Elsevier, vol. 157(C), pages 85-94.
    8. Zhou, D. & Zhao, C.Y. & Tian, Y., 2012. "Review on thermal energy storage with phase change materials (PCMs) in building applications," Applied Energy, Elsevier, vol. 92(C), pages 593-605.
    9. Solé, Aran & Miró, Laia & Barreneche, Camila & Martorell, Ingrid & Cabeza, Luisa F., 2013. "Review of the T-history method to determine thermophysical properties of phase change materials (PCM)," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 425-436.
    10. Zhang, Zhengguo & Shi, Guoquan & Wang, Shuping & Fang, Xiaoming & Liu, Xiaohong, 2013. "Thermal energy storage cement mortar containing n-octadecane/expanded graphite composite phase change material," Renewable Energy, Elsevier, vol. 50(C), pages 670-675.
    11. Memon, Shazim Ali & Cui, H.Z. & Zhang, Hang & Xing, Feng, 2015. "Utilization of macro encapsulated phase change materials for the development of thermal energy storage and structural lightweight aggregate concrete," Applied Energy, Elsevier, vol. 139(C), pages 43-55.
    12. Cheng, Wenlong & Xie, Biao & Zhang, Rongming & Xu, Zhiming & Xia, Yuting, 2015. "Effect of thermal conductivities of shape stabilized PCM on under-floor heating system," Applied Energy, Elsevier, vol. 144(C), pages 10-18.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wu, Shaofei & Yan, Ting & Kuai, Zihan & Pan, Weiguo, 2020. "Preparation and thermal property analysis of a novel phase change heat storage material," Renewable Energy, Elsevier, vol. 150(C), pages 1057-1065.
    2. Qiu, Lin & Ouyang, Yuxin & Feng, Yanhui & Zhang, Xinxin, 2019. "Review on micro/nano phase change materials for solar thermal applications," Renewable Energy, Elsevier, vol. 140(C), pages 513-538.
    3. Xiao, Qiangqiang & Fan, Jiaxin & Li, Li & Xu, Tao & Yuan, Wenhui, 2018. "Solar thermal energy storage based on sodium acetate trihydrate phase change hydrogels with excellent light-to-thermal conversion performance," Energy, Elsevier, vol. 165(PB), pages 1240-1247.
    4. Zhang, Suling & Wu, Wei & Wang, Shuangfeng, 2018. "Experimental investigations of Alum/expanded graphite composite phase change material for thermal energy storage and its compatibility with metals," Energy, Elsevier, vol. 161(C), pages 508-516.
    5. Yu, Kunyang & Liu, Yushi & Yang, Yingzi, 2021. "Review on form-stable inorganic hydrated salt phase change materials: Preparation, characterization and effect on the thermophysical properties," Applied Energy, Elsevier, vol. 292(C).
    6. Lin, Xuemin & Ling, Ziye & Fang, Xiaoming & Zhang, Zhengguo, 2022. "Flexibility and shape memory of phase change material capable of rapid electric heating function for wearable thermotherapy," Applied Energy, Elsevier, vol. 327(C).
    7. Lin, Yaxue & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal performances and applications of thermal energy storage systems with inorganic phase change materials," Energy, Elsevier, vol. 165(PA), pages 685-708.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Akeiber, Hussein & Nejat, Payam & Majid, Muhd Zaimi Abd. & Wahid, Mazlan A. & Jomehzadeh, Fatemeh & Zeynali Famileh, Iman & Calautit, John Kaiser & Hughes, Ben Richard & Zaki, Sheikh Ahmad, 2016. "A review on phase change material (PCM) for sustainable passive cooling in building envelopes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 1470-1497.
    2. Soares, N. & Santos, P. & Gervásio, H. & Costa, J.J. & Simões da Silva, L., 2017. "Energy efficiency and thermal performance of lightweight steel-framed (LSF) construction: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 194-209.
    3. Drissi, Sarra & Ling, Tung-Chai & Mo, Kim Hung & Eddhahak, Anissa, 2019. "A review of microencapsulated and composite phase change materials: Alteration of strength and thermal properties of cement-based materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 110(C), pages 467-484.
    4. Khadiran, Tumirah & Hussein, Mohd Zobir & Zainal, Zulkarnain & Rusli, Rafeadah, 2016. "Advanced energy storage materials for building applications and their thermal performance characterization: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 916-928.
    5. Mingli Li & Guoqing Gui & Zhibin Lin & Long Jiang & Hong Pan & Xingyu Wang, 2018. "Numerical Thermal Characterization and Performance Metrics of Building Envelopes Containing Phase Change Materials for Energy-Efficient Buildings," Sustainability, MDPI, vol. 10(8), pages 1-23, July.
    6. Monika Gandhi & Ashok Kumar & Rajasekar Elangovan & Chandan Swaroop Meena & Kishor S. Kulkarni & Anuj Kumar & Garima Bhanot & Nishant R. Kapoor, 2020. "A Review on Shape-Stabilized Phase Change Materials for Latent Energy Storage in Buildings," Sustainability, MDPI, vol. 12(22), pages 1-17, November.
    7. Zeng, Cheng & Liu, Shuli & Shukla, Ashish, 2017. "Adaptability research on phase change materials based technologies in China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 145-158.
    8. Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
    9. M. M. Mousa & A. M. Bayomy & M. Z. Saghir, 2020. "Experimental and Numerical Study on Energy Piles with Phase Change Materials," Energies, MDPI, vol. 13(18), pages 1-21, September.
    10. Ramakrishnan, Sayanthan & Wang, Xiaoming & Sanjayan, Jay & Wilson, John, 2017. "Thermal performance assessment of phase change material integrated cementitious composites in buildings: Experimental and numerical approach," Applied Energy, Elsevier, vol. 207(C), pages 654-664.
    11. Memon, Shazim Ali, 2014. "Phase change materials integrated in building walls: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 870-906.
    12. Ge, Haoshan & Li, Haiyan & Mei, Shengfu & Liu, Jing, 2013. "Low melting point liquid metal as a new class of phase change material: An emerging frontier in energy area," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 331-346.
    13. Kahwaji, Samer & Johnson, Michel B. & Kheirabadi, Ali C. & Groulx, Dominic & White, Mary Anne, 2016. "Stable, low-cost phase change material for building applications: The eutectic mixture of decanoic acid and tetradecanoic acid," Applied Energy, Elsevier, vol. 168(C), pages 457-464.
    14. Chandel, S.S. & Agarwal, Tanya, 2017. "Review of current state of research on energy storage, toxicity, health hazards and commercialization of phase changing materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 581-596.
    15. Ren, Miao & Liu, Yushi & Gao, Xiaojian, 2020. "Incorporation of phase change material and carbon nanofibers into lightweight aggregate concrete for thermal energy regulation in buildings," Energy, Elsevier, vol. 197(C).
    16. Ye, Rongda & Lin, Wenzhu & Yuan, Kunjie & Fang, Xiaoming & Zhang, Zhengguo, 2017. "Experimental and numerical investigations on the thermal performance of building plane containing CaCl2·6H2O/expanded graphite composite phase change material," Applied Energy, Elsevier, vol. 193(C), pages 325-335.
    17. Zeinelabdein, Rami & Omer, Siddig & Gan, Guohui, 2018. "Critical review of latent heat storage systems for free cooling in buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2843-2868.
    18. Ohayon-Lavi, Avia & Lavi, Adi & Alatawna, Amr & Ruse, Efrat & Ziskind, Gennady & Regev, Oren, 2021. "Graphite-based shape-stabilized composites for phase change material applications," Renewable Energy, Elsevier, vol. 167(C), pages 580-590.
    19. Kenisarin, Murat & Mahkamov, Khamid, 2016. "Passive thermal control in residential buildings using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 371-398.
    20. Faraj, Khaireldin & Khaled, Mahmoud & Faraj, Jalal & Hachem, Farouk & Castelain, Cathy, 2020. "Phase change material thermal energy storage systems for cooling applications in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:114:y:2017:i:pb:p:733-743. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.