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Improved Poly(vinyl alcohol) (PVA) based matrix as a potential solid electrolyte for electrochemical energy conversion devices, obtained by gamma irradiation

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  • Stoševski, Ivan
  • Krstić, Jelena
  • Vokić, Nikola
  • Radosavljević, Miljan
  • Popović, Zorica Kačarević
  • Miljanić, Šćepan

Abstract

PVA (Poly(vinyl alcohol)) matrixes were developed for potential application in electrochemical energy conversion devices, like batteries, alkaline fuel cells and electrolyzers. They were prepared by ɣ-irradiation of aqueous PVA solutions, followed by different post irradiation treatments. By immersion in an electrolyte they become membranes with high ionic conductivities. The treatments were shown as the key factor determining the conductivity, through affecting their structure. An improved structure has large fractional free volume, and allows high electrolyte uptake and thus high conductivity (0.30 S cm−1–0.34 S cm−1). The structure, as well as the conductivity, has not been changed even after a period of 14 months, although the membranes have been exposed to strong alkaline medium. Besides high and long-term conductivity of the KOH doped membranes, other important properties for application in the devices were investigated, like thermal stability and gas crossover through the membranes. The 10%PVA25kGy membrane doped with saturated LiNO3 solution was tested in a rechargeable aqueous Li-ion battery. Due to its high conductivity it allowed an electrode material to have the same coulombic efficiency as it would have in liquid LiNO3, showing good compatibility with the material. All these properties make the memebranes attractive candidates for possible application in the electrochemical devices.

Suggested Citation

  • Stoševski, Ivan & Krstić, Jelena & Vokić, Nikola & Radosavljević, Miljan & Popović, Zorica Kačarević & Miljanić, Šćepan, 2015. "Improved Poly(vinyl alcohol) (PVA) based matrix as a potential solid electrolyte for electrochemical energy conversion devices, obtained by gamma irradiation," Energy, Elsevier, vol. 90(P1), pages 595-604.
    • Handle: RePEc:eee:energy:v:90:y:2015:i:p1:p:595-604
    DOI: 10.1016/j.energy.2015.07.096
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    References listed on IDEAS

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    1. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    2. Zhang, Houcheng & Lin, Guoxing & Chen, Jincan, 2011. "The performance analysis and multi-objective optimization of a typical alkaline fuel cell," Energy, Elsevier, vol. 36(7), pages 4327-4332.
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    1. Selvaraj Rajesh Kumar & Wei-Ting Ma & Hsin-Chun Lu & Li-Wei Teng & Hung-Chun Hsu & Chao-Ming Shih & Chun-Chen Yang & Shingjiang Jessie Lue, 2017. "Surfactant-Assisted Perovskite Nanofillers Incorporated in Quaternized Poly (Vinyl Alcohol) Composite Membrane as an Effective Hydroxide-Conducting Electrolyte," Energies, MDPI, vol. 10(5), pages 1-22, May.
    2. Murashko, Kirill & Nevstrueva, Daria & Pihlajamäki, Arto & Koiranen, Tuomas & Pyrhönen, Juha, 2017. "Cellulose and activated carbon based flexible electrical double-layer capacitor electrode: Preparation and characterization," Energy, Elsevier, vol. 119(C), pages 435-441.
    3. Stoševski, Ivan & Krstić, Jelena & Milikić, Jadranka & Šljukić, Biljana & Kačarević-Popović, Zorica & Mentus, Slavko & Miljanić, Šćepan, 2016. "Radiolitically synthesized nano Ag/C catalysts for oxygen reduction and borohydride oxidation reactions in alkaline media, for potential applications in fuel cells," Energy, Elsevier, vol. 101(C), pages 79-90.
    4. Liew, Chiam-Wen & Ramesh, S. & Arof, A.K., 2016. "Enhanced capacitance of EDLCs (electrical double layer capacitors) based on ionic liquid-added polymer electrolytes," Energy, Elsevier, vol. 109(C), pages 546-556.

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