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Experimental study on the operating characteristics of an inner preheating transpiring wall reactor for supercritical water oxidation: Temperature profiles and product properties

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  • Zhang, Fengming
  • Xu, Chunyan
  • Zhang, Yong
  • Chen, Shouyan
  • Chen, Guifang
  • Ma, Chunyuan

Abstract

A new process to generate multiple thermal fluids by supercritical water oxidation (SCWO) was proposed to enhance oil recovery. An inner preheating transpiring wall reactor for SCWO was designed and tested to avoid plugging in the preheating section. Hot water (400–600°C) was used as auxiliary heat source to preheat the feed to the reaction temperature. The effect of different operating parameters on the performance of the inner preheating transpiring wall reactor was investigated, and the optimized operating parameters were determined based on temperature profiles and product properties. The reaction temperature is close to 900°C at an auxiliary heat source flow of 2.79kg/h, and the auxiliary heat source flow is determined at 6–14kg/h to avoid the overheating of the reactor. The useful reaction time is used to quantitatively describe the feed degradation efficiency. The outlet concentration of total organic carbon (TOCout) and CO in the effluent gradually decreases with increasing useful reaction time. The useful reaction time needed for complete oxidation of the feed is 10.5s for the reactor.

Suggested Citation

  • Zhang, Fengming & Xu, Chunyan & Zhang, Yong & Chen, Shouyan & Chen, Guifang & Ma, Chunyuan, 2014. "Experimental study on the operating characteristics of an inner preheating transpiring wall reactor for supercritical water oxidation: Temperature profiles and product properties," Energy, Elsevier, vol. 66(C), pages 577-587.
  • Handle: RePEc:eee:energy:v:66:y:2014:i:c:p:577-587
    DOI: 10.1016/j.energy.2014.02.003
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    Cited by:

    1. Huang, Yingfei & Zhang, Fengming & Liang, Zhaojian & Li, Yufeng & Wu, Tong, 2023. "Effect of hydrothermal flame generation methods on energy consumption and economic performance of supercritical water oxidation systems," Energy, Elsevier, vol. 266(C).
    2. Zhang, Fengming & Li, Yufeng & Jia, Cuijie & Shen, Boya, 2021. "Effect of evaporation on the energy conversion of a supercritical water oxidation system containing a hydrothermal flame," Energy, Elsevier, vol. 226(C).
    3. Knez, Ž. & Markočič, E. & Leitgeb, M. & Primožič, M. & Knez Hrnčič, M. & Škerget, M., 2014. "Industrial applications of supercritical fluids: A review," Energy, Elsevier, vol. 77(C), pages 235-243.
    4. Cabeza, Pablo & Silva Queiroz, Joao Paulo & Criado, Manuel & Jiménez, Cristina & Bermejo, Maria Dolores & Mato, Fidel & Cocero, Maria Jose, 2015. "Supercritical water oxidation for energy production by hydrothermal flame as internal heat source. Experimental results and energetic study," Energy, Elsevier, vol. 90(P2), pages 1584-1594.

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