IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v32y2007i4p528-539.html
   My bibliography  Save this article

Dissolution of steelmaking slags in acetic acid for precipitated calcium carbonate production

Author

Listed:
  • Teir, Sebastian
  • Eloneva, Sanni
  • Fogelholm, Carl-Johan
  • Zevenhoven, Ron

Abstract

A promising option for long-term storage of CO2 is to fixate carbon dioxide as magnesium- and calcium carbonates. Slags from iron and steel works are potential raw materials for carbonation due to their high contents of calcium silicates. Precipitated calcium carbonate (PCC) is used as filler and coating materials in paper. If slag could be used instead of limestone for producing PCC, considerable energy savings and carbon dioxide emissions reductions could be achieved. In this paper, the leaching of calcium from iron and steel slags using acetic acid was investigated. Thermodynamic equilibrium calculations at atmospheric gas pressures showed that extraction of calcium is exothermic and feasible at temperatures lower than 156°C, while the precipitation of calcium carbonate is endothermic and feasible at temperatures above 45°C. The formation of calcium- and magnesium acetate in the solution was found to be thermodynamically possible. Laboratory-scale batch experiments showed that iron and steel slags rapidly dissolve in acetic acid in a few minutes and the exothermic nature of the reaction was verified. While silicon was successfully removed by filtration using solution temperatures of 70–80°C, further separation methods are required for removing iron, aluminum and magnesium from the solution.

Suggested Citation

  • Teir, Sebastian & Eloneva, Sanni & Fogelholm, Carl-Johan & Zevenhoven, Ron, 2007. "Dissolution of steelmaking slags in acetic acid for precipitated calcium carbonate production," Energy, Elsevier, vol. 32(4), pages 528-539.
    • Handle: RePEc:eee:energy:v:32:y:2007:i:4:p:528-539
    DOI: 10.1016/j.energy.2006.06.023
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544206001617
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2006.06.023?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kakizawa, M. & Yamasaki, A. & Yanagisawa, Y., 2001. "A new CO2 disposal process via artificial weathering of calcium silicate accelerated by acetic acid," Energy, Elsevier, vol. 26(4), pages 341-354.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Bernard Jomari B. Razote & Mark Kenneth M. Maranan & Ramon Christian P. Eusebio & Richard D. Alorro & Arnel B. Beltran & Aileen H. Orbecido, 2019. "Determination of the Carbon Dioxide Sequestration Potential of a Nickel Mine Mixed Dump through Leaching Tests," Energies, MDPI, vol. 12(15), pages 1-19, July.
    2. Xiaolong Wang & Aimaro Sanna & M. Mercedes Maroto‐Valer & Tom Paulson, 2015. "Carbon dioxide capture and storage by pH swing mineralization using recyclable ammonium salts and flue gas mixtures," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 5(4), pages 389-402, August.
    3. Paulina Rusanowska & Marcin Zieliński & Marcin Dębowski, 2023. "Removal of CO 2 from Biogas during Mineral Carbonation with Waste Materials," IJERPH, MDPI, vol. 20(9), pages 1-10, April.
    4. Sanna, Aimaro & Dri, Marco & Hall, Matthew R. & Maroto-Valer, Mercedes, 2012. "Waste materials for carbon capture and storage by mineralisation (CCSM) – A UK perspective," Applied Energy, Elsevier, vol. 99(C), pages 545-554.
    5. Enze Ren & Siyang Tang & Changjun Liu & Hairong Yue & Chun Li & Bin Liang, 2020. "Carbon dioxide mineralization for the disposition of blast‐furnace slag: reaction intensification using NaCl solutions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(2), pages 436-448, April.
    6. Park, Sangwon, 2018. "CO2 reduction-conversion to precipitates and morphological control through the application of the mineral carbonation mechanism," Energy, Elsevier, vol. 153(C), pages 413-421.
    7. Said, Arshe & Mattila, Hannu-Petteri & Järvinen, Mika & Zevenhoven, Ron, 2013. "Production of precipitated calcium carbonate (PCC) from steelmaking slag for fixation of CO2," Applied Energy, Elsevier, vol. 112(C), pages 765-771.
    8. Jo, Hoyong & Lee, Min-Gu & Park, Jinwon & Jung, Kwang-Deog, 2017. "Preparation of high-purity nano-CaCO3 from steel slag," Energy, Elsevier, vol. 120(C), pages 884-894.
    9. Zhang, Huining & Gao, Chong & Chen, Ben & Tang, Jiang & He, Dongfeng & Xu, Anjun, 2018. "Stainless steel tailings accelerated direct carbonation process at low pressure: Carbonation efficiency evaluation and chromium leaching inhibition correlation analysis," Energy, Elsevier, vol. 155(C), pages 772-781.
    10. Jun-Hwan Bang & Seung-Woo Lee & Chiwan Jeon & Sangwon Park & Kyungsun Song & Whan Joo Jo & Soochun Chae, 2016. "Leaching of Metal Ions from Blast Furnace Slag by Using Aqua Regia for CO 2 Mineralization," Energies, MDPI, vol. 9(12), pages 1-13, November.
    11. Natalia Czaplicka & Donata Konopacka-Łyskawa, 2020. "Utilization of Gaseous Carbon Dioxide and Industrial Ca-Rich Waste for Calcium Carbonate Precipitation: A Review," Energies, MDPI, vol. 13(23), pages 1-25, November.
    12. Lee, Myung gyu & Jang, Young Nam & Ryu, Kyung won & Kim, Wonbeak & Bang, Jun-Hwan, 2012. "Mineral carbonation of flue gas desulfurization gypsum for CO2 sequestration," Energy, Elsevier, vol. 47(1), pages 370-377.
    13. Naraharisetti, Pavan Kumar & Yeo, Tze Yuen & Bu, Jie, 2019. "New classification of CO2 mineralization processes and economic evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 99(C), pages 220-233.
    14. Li, Hongwei & Tang, Zhigang & Xing, Xiao & Guo, Dong & Cui, Longpeng & Mao, Xian-zhong, 2018. "Study of CO2 capture by seawater and its reinforcement," Energy, Elsevier, vol. 164(C), pages 1135-1144.
    15. Noor Allesya Alis Ramli & Faradiella Mohd Kusin & Verma Loretta M. Molahid, 2021. "Influencing Factors of the Mineral Carbonation Process of Iron Ore Mining Waste in Sequestering Atmospheric Carbon Dioxide," Sustainability, MDPI, vol. 13(4), pages 1-17, February.
    16. Quader, M. Abdul & Ahmed, Shamsuddin & Ghazilla, Raja Ariffin Raja & Ahmed, Shameem & Dahari, Mahidzal, 2015. "A comprehensive review on energy efficient CO2 breakthrough technologies for sustainable green iron and steel manufacturing," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 594-614.
    17. Ukwattage, N.L. & Ranjith, P.G. & Wang, S.H., 2013. "Investigation of the potential of coal combustion fly ash for mineral sequestration of CO2 by accelerated carbonation," Energy, Elsevier, vol. 52(C), pages 230-236.
    18. Hosseini, Tahereh & Haque, Nawshad & Selomulya, Cordelia & Zhang, Lian, 2016. "Mineral carbonation of Victorian brown coal fly ash using regenerative ammonium chloride – Process simulation and techno-economic analysis," Applied Energy, Elsevier, vol. 175(C), pages 54-68.
    19. Eloneva, Sanni & Said, Arshe & Fogelholm, Carl-Johan & Zevenhoven, Ron, 2012. "Preliminary assessment of a method utilizing carbon dioxide and steelmaking slags to produce precipitated calcium carbonate," Applied Energy, Elsevier, vol. 90(1), pages 329-334.
    20. Lombardi, Lidia & Carnevale, Ennio, 2013. "Economic evaluations of an innovative biogas upgrading method with CO2 storage," Energy, Elsevier, vol. 62(C), pages 88-94.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sanna, Aimaro & Dri, Marco & Hall, Matthew R. & Maroto-Valer, Mercedes, 2012. "Waste materials for carbon capture and storage by mineralisation (CCSM) – A UK perspective," Applied Energy, Elsevier, vol. 99(C), pages 545-554.
    2. Noor Allesya Alis Ramli & Faradiella Mohd Kusin & Verma Loretta M. Molahid, 2021. "Influencing Factors of the Mineral Carbonation Process of Iron Ore Mining Waste in Sequestering Atmospheric Carbon Dioxide," Sustainability, MDPI, vol. 13(4), pages 1-17, February.
    3. Lombardi, L. & Carnevale, E.A., 2016. "Analysis of an innovative process for landfill gas quality improvement," Energy, Elsevier, vol. 109(C), pages 1107-1117.
    4. Enze Ren & Siyang Tang & Changjun Liu & Hairong Yue & Chun Li & Bin Liang, 2020. "Carbon dioxide mineralization for the disposition of blast‐furnace slag: reaction intensification using NaCl solutions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(2), pages 436-448, April.
    5. Natalia Czaplicka & Donata Konopacka-Łyskawa, 2020. "Utilization of Gaseous Carbon Dioxide and Industrial Ca-Rich Waste for Calcium Carbonate Precipitation: A Review," Energies, MDPI, vol. 13(23), pages 1-25, November.
    6. Naraharisetti, Pavan Kumar & Yeo, Tze Yuen & Bu, Jie, 2019. "New classification of CO2 mineralization processes and economic evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 99(C), pages 220-233.
    7. Mihee Lim & Gi-Chun Han & Ji-Whan Ahn & Kwang-Suk You, 2010. "Environmental Remediation and Conversion of Carbon Dioxide (CO 2 ) into Useful Green Products by Accelerated Carbonation Technology," IJERPH, MDPI, vol. 7(1), pages 1-26, January.
    8. Eloneva, Sanni & Teir, Sebastian & Salminen, Justin & Fogelholm, Carl-Johan & Zevenhoven, Ron, 2008. "Fixation of CO2 by carbonating calcium derived from blast furnace slag," Energy, Elsevier, vol. 33(9), pages 1461-1467.
    9. Kodama, Satoshi & Nishimoto, Taiki & Yamamoto, Naoki & Yogo, Katsunori & Yamada, Koichi, 2008. "Development of a new pH-swing CO2 mineralization process with a recyclable reaction solution," Energy, Elsevier, vol. 33(5), pages 776-784.
    10. Bernard Jomari B. Razote & Mark Kenneth M. Maranan & Ramon Christian P. Eusebio & Richard D. Alorro & Arnel B. Beltran & Aileen H. Orbecido, 2019. "Determination of the Carbon Dioxide Sequestration Potential of a Nickel Mine Mixed Dump through Leaching Tests," Energies, MDPI, vol. 12(15), pages 1-19, July.
    11. Hyun Sic Park & JunYoung Han & Ju Sung Lee & Kwang-Mo Kim & Hyung Jun Jo & Byoung Ryul Min, 2016. "Comparison of Two Processes Forming CaCO 3 Precipitates by Electrolysis," Energies, MDPI, vol. 9(12), pages 1-8, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:32:y:2007:i:4:p:528-539. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.