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Enhancing methanol-to-power: A comprehensive evaluation of an integrated methanol-reforming, high-temperature proton exchange membrane fuel cell, and organic Rankine cycle system

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  • Taweekayujan, Supawat
  • Prasertcharoensuk, Phuet
  • Chen, Yong-Song
  • Arpornwichanop, Amornchai

Abstract

This study proposes an innovative hybrid system integrating sorption-enhanced chemical looping reforming of methanol, a high-temperature proton exchange membrane fuel cell, and an organic Rankine cycle to enhance energy efficiency and sustainability. The novelty lies in combining these subsystems to perform a comprehensive analysis for maximizing hydrogen production, recovering high-quality waste heat, and improving economic viability by leveraging advanced thermodynamic and exergoecnomic optimization. A detailed energy, exergy, and exergoeconomic analysis was conducted using Aspen Plus simulations, revealing that irreversibilities in the afterburner, stack fuel cell, and fuel reactor contribute to 73.7 % of the total exergy destruction. Exergoeconomic analysis identified the evaporator as the costliest component due to significant exergy losses. Parametric analyses demonstrated that increasing catalyst and absorbent molar flow rate ratios enhanced net power generation but increased costs. For the fuel cell section, optimizing the oxygen flowrate ratio, current density, and temperature improved performance and reduced the costs rate, though excessive current density led to efficiency losses. Higher fuel cell temperatures and optimized intermediate pressures in the organic Rankine cycle system improved efficiency and decreased costs. This study provides valuable insights for designing and optimizing advanced energy systems combining methanol reforming, fuel cell, and organic Rankine cycle, emphasizing the importance of balancing variables for overall system efficiency and economic viability.

Suggested Citation

  • Taweekayujan, Supawat & Prasertcharoensuk, Phuet & Chen, Yong-Song & Arpornwichanop, Amornchai, 2025. "Enhancing methanol-to-power: A comprehensive evaluation of an integrated methanol-reforming, high-temperature proton exchange membrane fuel cell, and organic Rankine cycle system," Energy, Elsevier, vol. 321(C).
    • Handle: RePEc:eee:energy:v:321:y:2025:i:c:s0360544225009430
    DOI: 10.1016/j.energy.2025.135301
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    1. Lu, Xinyu & Du, Banghua & Zhu, Wenchao & Yang, Yang & Xie, Changjun & Tu, Zhengkai & Zhao, Bo & Zhang, Leiqi & Wang, Jianqiang & Yang, Zheng, 2024. "Multi-criteria assessment of an auxiliary energy system for desalination plant based on PEMFC-ORC combined heat and power," Energy, Elsevier, vol. 290(C).
    2. Wang, Chenfang & Li, Qingshan & Wang, Chunmei & Zhang, Yangjun & Zhuge, Weilin, 2021. "Thermodynamic analysis of a hydrogen fuel cell waste heat recovery system based on a zeotropic organic Rankine cycle," Energy, Elsevier, vol. 232(C).
    3. Li, Yanju & Li, Dongxu & Ma, Zheshu & Zheng, Meng & Lu, Zhanghao & Song, Hanlin & Guo, Xinjia & Shao, Wei, 2022. "Performance analysis and optimization of a novel vehicular power system based on HT-PEMFC integrated methanol steam reforming and ORC," Energy, Elsevier, vol. 257(C).
    4. Habibollahzade, Ali & Gholamian, Ehsan & Behzadi, Amirmohammad, 2019. "Multi-objective optimization and comparative performance analysis of hybrid biomass-based solid oxide fuel cell/solid oxide electrolyzer cell/gas turbine using different gasification agents," Applied Energy, Elsevier, vol. 233, pages 985-1002.
    5. Satanphol, K. & Pridasawas, W. & Suphanit, B., 2017. "A study on optimal composition of zeotropic working fluid in an Organic Rankine Cycle (ORC) for low grade heat recovery," Energy, Elsevier, vol. 123(C), pages 326-339.
    6. Bing Xu & Dongxu Li & Zheshu Ma & Meng Zheng & Yanju Li, 2021. "Thermodynamic Optimization of a High Temperature Proton Exchange Membrane Fuel Cell for Fuel Cell Vehicle Applications," Mathematics, MDPI, vol. 9(15), pages 1-14, July.
    7. Crivellari, Anna & Cozzani, Valerio & Dincer, Ibrahim, 2019. "Exergetic and exergoeconomic analyses of novel methanol synthesis processes driven by offshore renewable energies," Energy, Elsevier, vol. 187(C).
    8. Chen, Zhijie & Zuo, Wei & Zhou, Kun & Li, Qingqing & Huang, Yuhan & E, Jiaqiang, 2023. "Multi-factor impact mechanism on the performance of high temperature proton exchange membrane fuel cell," Energy, Elsevier, vol. 278(PB).
    9. Li, Na & Cui, Xiaoti & Zhu, Jimin & Zhou, Mengfan & Liso, Vincenzo & Cinti, Giovanni & Sahlin, Simon Lennart & Araya, Samuel Simon, 2023. "A review of reformed methanol-high temperature proton exchange membrane fuel cell systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    10. Xie, Nan & Xiao, Zhenyu & Du, Wei & Deng, Chengwei & Liu, Zhiqiang & Yang, Sheng, 2023. "Thermodynamic and exergoeconomic analysis of a proton exchange membrane fuel cell/absorption chiller CCHP system based on biomass gasification," Energy, Elsevier, vol. 262(PB).
    Full references (including those not matched with items on IDEAS)

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