IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v284y2023ics0360544223016614.html
   My bibliography  Save this article

Synthesis of mono, bi, and trimetallic Sn–Ni–Cu based ionic micro-emulsion catalysts and optimization of catalytic performance in heavy oil upgrading

Author

Listed:
  • Abdi-Khanghah, Mahdi
  • Jafari, Arezou
  • Ahmadi, Goodarz
  • Hemmati-Sarapardeh, Abdolhossein

Abstract

In this study, to synthesize an active and feasible mono, bi, and trimetallic Sn–Ni–Cu/ionic microemulsion catalysts (IMECs), a novel synthesis process was proposed. All synthesized catalytic solutions and IMECs were characterized using conductivity, refractivity index (RI), inductively coupled plasma (ICP) and light microscope, physical stability, and Fourier transformed infrared spectroscopy (FTIR), respectively. Then, the interaction of catalyst formulation with operational parameters on the upgrading was experimentally evaluated. Statistical modeling was performed using the mixture-process algorithm of Design of Experiments (DOE). Experimental results and catalysts characterization specially FTIR outcomes reveal that shifting NO3−peaks of the trimetallic IMEC confirms the suitable preparation of IMEC. Moreover, trimetallic IMEC formulation of 23.09% Sn, 60.648% Ni, and 16.268% Cu which shows viscosity and produced gas weight percent (PGWP) of 586.99 cP and 1.269%, respectively, is the optimum catalyst formulation. Reaction temperature and catalysts wt% of 73 °C and 0.2% can be considered as the optimum operational condition. Finally, at 70 °C, increasing the amount of catalysts causes an increase in the speed of heavy to middle hydrocarbon reactions with reducing the effect of the mass transfer controlling mechanism. On the other hand, the reaction controlling mechanism for the production of light hydrocarbon from heavy oil was eliminated by changing the reaction temperature from 70 to 90 °C.

Suggested Citation

  • Abdi-Khanghah, Mahdi & Jafari, Arezou & Ahmadi, Goodarz & Hemmati-Sarapardeh, Abdolhossein, 2023. "Synthesis of mono, bi, and trimetallic Sn–Ni–Cu based ionic micro-emulsion catalysts and optimization of catalytic performance in heavy oil upgrading," Energy, Elsevier, vol. 284(C).
    • Handle: RePEc:eee:energy:v:284:y:2023:i:c:s0360544223016614
    DOI: 10.1016/j.energy.2023.128267
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544223016614
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2023.128267?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Aune, Finn Roar & Grimsrud, Kristine & Lindholt, Lars & Rosendahl, Knut Einar & Storrøsten, Halvor Briseid, 2017. "Oil consumption subsidy removal in OPEC and other Non-OECD countries: Oil market impacts and welfare effects," Energy Economics, Elsevier, vol. 68(C), pages 395-409.
    2. Chen, Yanling & He, Jing & Wang, Yuanqing & Li, Pei, 2010. "GC-MS used in study on the mechanism of the viscosity reduction of heavy oil through aquathermolysis catalyzed by aromatic sulfonic H3PMo12O40," Energy, Elsevier, vol. 35(8), pages 3454-3460.
    3. Alade, Olalekan S. & Mahmoud, Mohamed & Al Shehri, Dhafer & Mokheimer, Esmail M.A. & Sasaki, Kyuro & Ohashi, Ryo & Kamal, Muhammad Shahzad & Muhammad, Isah & Al-Nakhli, Ayman, 2022. "Experimental and numerical studies on production scheme to improve energy efficiency of bitumen production through insitu oil-in-water (O/W) emulsion," Energy, Elsevier, vol. 244(PA).
    4. Li, Pengliang & Liu, Zhenyi & Li, Mingzhi & Zhao, Yao & Li, Xuan & Wan, Song & Ma, Yuanyuan & He, Yanghua, 2020. "Investigation on the low temperature oxidation of light oil for safely enhancing oil recovery at high temperatures and pressures," Energy, Elsevier, vol. 200(C).
    5. Lyu, Yang & Huang, Qiyu, 2023. "Flow characteristics of heavy oil-water flow during high water-content cold transportation," Energy, Elsevier, vol. 262(PA).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Korrakot Phomsoda & Nattapong Puttanapong & Mongkut Piantanakulchai, 2021. "Economic Impacts of Thailand’s Biofuel Subsidy Reallocation Using a Dynamic Computable General Equilibrium (CGE) Model," Energies, MDPI, vol. 14(8), pages 1-21, April.
    2. Zakia Batool & Sajjad Ali & Abdul Rehman, 2022. "Environmental Impact of ICT on Disaggregated Energy Consumption in China: A Threshold Regression Analysis," Sustainability, MDPI, vol. 14(23), pages 1-17, November.
    3. Kheiravar, Khaled H, 2019. "Economic and Econometric Analyses of the World Petroleum Industry, Energy Subsidies, and Air Pollution," Institute of Transportation Studies, Working Paper Series qt3gj151w9, Institute of Transportation Studies, UC Davis.
    4. Zhao, Xu & Luo, Dongkun & Lu, Kun & Wang, Xiaoyu & Dahl, Carol, 2019. "How the removal of producer subsidies influences oil and gas extraction: A case study in the Gulf of Mexico," Energy, Elsevier, vol. 166(C), pages 1000-1012.
    5. Djoni Hartono & Ahmad Komarulzaman & Tony Irawan & Anda Nugroho, 2020. "Phasing out Energy Subsidies to Improve Energy Mix: A Dead End," Energies, MDPI, vol. 13(9), pages 1-15, May.
    6. Aldubyan, Mohammad & Gasim, Anwar, 2021. "Energy price reform in Saudi Arabia: Modeling the economic and environmental impacts and understanding the demand response," Energy Policy, Elsevier, vol. 148(PB).
    7. Renbao Zhao & Tiantian Wang & Lijuan Chen & Jingjun Pan & Shutong Li & Dong Zhao & Long Chen & Jiaying Wang, 2022. "Evolution of the Pseudo-Components of Heavy Oil during Low Temperature Oxidation Processes," Energies, MDPI, vol. 15(14), pages 1-14, July.
    8. Berk, Istemi & Çam , Eren, 2019. "The Shift in Global Crude Oil Market Structure: A model-based analysis of the period 2013–2017," EWI Working Papers 2019-5, Energiewirtschaftliches Institut an der Universitaet zu Koeln (EWI).
    9. Huang, Lijuan & Wang, Yu & Li, Zongfa & Zhang, Liang & Yin, Yuchuan & Chen, Chao & Ren, Shaoran, 2021. "Experimental study on piloted ignition temperature and auto ignition temperature of heavy oils at high pressure," Energy, Elsevier, vol. 229(C).
    10. Atalla, Tarek N. & Gasim, Anwar A. & Hunt, Lester C., 2018. "Gasoline demand, pricing policy, and social welfare in Saudi Arabia: A quantitative analysis," Energy Policy, Elsevier, vol. 114(C), pages 123-133.
    11. Zhong, Jie & Wang, Pan & Zhang, Yang & Yan, Youguo & Hu, Songqing & Zhang, Jun, 2013. "Adsorption mechanism of oil components on water-wet mineral surface: A molecular dynamics simulation study," Energy, Elsevier, vol. 59(C), pages 295-300.
    12. Zhang, Jun, 2023. "Performance of high temperature steam injection in horizontal wells of heavy oil reservoirs," Energy, Elsevier, vol. 282(C).
    13. Qi, Chang & Ding, Jianfei & Wang, Yue & Ning, Ye & Wang, Yalei & Liang, He & Yan, Xingqing & Yu, Jianliang, 2023. "Investigation of the upper flammability limit of ethylene/propane mixtures in air at high temperatures and pressures," Energy, Elsevier, vol. 281(C).
    14. Berk, Istemi & Çam, Eren, 2020. "The shift in global crude oil market structure: A model-based analysis of the period 2013–2017," Energy Policy, Elsevier, vol. 142(C).
    15. Li, Pengliang & Liu, Zhenyi & Li, Mingzhi & Zhao, Yao & Qian, Xinming & Ren, Yuan, 2023. "Investigation on the reaction mechanism of methane combustion near flammability limits at elevated pressures and temperaturaes," Energy, Elsevier, vol. 269(C).
    16. Karanfil, Fatih & Pierru, Axel, 2021. "The opportunity cost of domestic oil consumption for an oil exporter: Illustration for Saudi Arabia," Energy Economics, Elsevier, vol. 96(C).
    17. Evans, Olaniyi & Nwaogwugwu, Isaac & Vincent, Olusegun & Wale-Awe, Olawale & Mesagan, Ekundayo & Ojapinwa, Taiwo, 2023. "The socio-economics of the 2023 fuel subsidy removal in Nigeria," MPRA Paper 118360, University Library of Munich, Germany.
    18. Xie, Yiwei & Li, Hongying & Xu, Miaomiao & Su, Yang & Zhang, Chaoyue & Han, Shanpeng & Zhang, Jinjun, 2023. "Effect of shear on durability of viscosity reduction of electrically-treated waxy crude oils," Energy, Elsevier, vol. 284(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:284:y:2023:i:c:s0360544223016614. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.