IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v277y2023ics0360544223010770.html
   My bibliography  Save this article

Study of NO emission from CH4-air, oxygen-enriched, and oxy-CH4 combustion under HTC and MILD regimes: Impact of wall thermal condition in different oxidant temperature and dilution level

Author

Listed:
  • Shaker, Ahmad
  • Fordoei, E. Ebrahimi
  • Boyaghchi, Fateme Ahmadi

Abstract

The present work investigates the effect of wall thermal conditions on the NO emission in the different inlet temperatures and oxidant dilution levels. The studies are performed for the CH4-air, oxygen-enriched, and oxy-CH4 combustion under the HTC and MILD regimes by numerical simulation of the non-premixed furnace and chemical calculations of the WSR reactor. It is found that higher heat loss from the wall and more replacement of CO2 with N2 facilitate the establishment of the MILD regime and significant reduction of NO production. The results show an optimum point for achieving the minimum heat loss and NO emission. Under the MILD regime, dominant mechanisms in the NO emission are prompt through reaction CH + N2⇌HCN + N and thermal routes for the CH4-air condition and N2O-intermediate by reactions N2O + O⇌2NO and N2O + H⇌N2+OH and thermal mechanisms for oxy-CH4 combustion. In both atmospheres, the thermal route plays the main role in the low heat loss from walls, while other routes are more active in the low maximum flame temperature. Reaction N + NO⇌N2+O by supplying O radical from reactions O + CO + M⇌CO2+M and H + O2+M⇌HO2+M is activated by increasing O2 level, while reactions N + NO⇌N2+O and N + OH⇌NO + H show the main contribution in the sensitivity analysis of NO.

Suggested Citation

  • Shaker, Ahmad & Fordoei, E. Ebrahimi & Boyaghchi, Fateme Ahmadi, 2023. "Study of NO emission from CH4-air, oxygen-enriched, and oxy-CH4 combustion under HTC and MILD regimes: Impact of wall thermal condition in different oxidant temperature and dilution level," Energy, Elsevier, vol. 277(C).
  • Handle: RePEc:eee:energy:v:277:y:2023:i:c:s0360544223010770
    DOI: 10.1016/j.energy.2023.127683
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544223010770
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2023.127683?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Tu, Yaojie & Xu, Mingchen & Zhou, Dezhi & Wang, Qingxiang & Yang, Wenming & Liu, Hao, 2019. "CFD and kinetic modelling study of methane MILD combustion in O2/N2, O2/CO2 and O2/H2O atmospheres," Applied Energy, Elsevier, vol. 240(C), pages 1003-1013.
    2. Fordoei, Esmaeil Ebrahimi & Boyaghchi, Fateme Ahmadi, 2022. "Influence of wall thermal conditions on the ignition, flame structure, and temperature behaviors in air-fuel, oxygen-enhanced, and oxy-fuel combustion under the MILD and high-temperature regimes," Energy, Elsevier, vol. 255(C).
    3. Yin, Chungen & Yan, Jinyue, 2016. "Oxy-fuel combustion of pulverized fuels: Combustion fundamentals and modeling," Applied Energy, Elsevier, vol. 162(C), pages 742-762.
    4. Fordoei, E. Ebrahimi & Mazaheri, Kiumars & Mohammadpour, Amirreza, 2021. "Numerical study on the heat transfer characteristics, flame structure, and pollutants emission in the MILD methane-air, oxygen-enriched and oxy-methane combustion," Energy, Elsevier, vol. 218(C).
    5. Cheong, Kin-Pang & Li, Pengfei & Wang, Feifei & Mi, Jianchun, 2017. "Emissions of NO and CO from counterflow combustion of CH4 under MILD and oxyfuel conditions," Energy, Elsevier, vol. 124(C), pages 652-664.
    6. Cheong, Kin-Pang & Wang, Guochang & Si, Jicang & Mi, Jianchun, 2021. "Nonpremixed MILD combustion in a laboratory-scale cylindrical furnace: Occurrence and identification," Energy, Elsevier, vol. 216(C).
    7. Sorrentino, Giancarlo & Sabia, Pino & Bozza, Pio & Ragucci, Raffaele & de Joannon, Mara, 2017. "Impact of external operating parameters on the performance of a cyclonic burner with high level of internal recirculation under MILD combustion conditions," Energy, Elsevier, vol. 137(C), pages 1167-1174.
    8. He, Yizhuo & Zou, Chun & Song, Yu & Liu, Yang & Zheng, Chuguang, 2016. "Numerical study of characteristics on NO formation in methane MILD combustion with simultaneously hot and diluted oxidant and fuel (HDO/HDF)," Energy, Elsevier, vol. 112(C), pages 1024-1035.
    9. Mardani, A. & Fazlollahi Ghomshi, A., 2016. "Numerical study of oxy-fuel MILD (moderate or intense low-oxygen dilution combustion) combustion for CH4–H2 fuel," Energy, Elsevier, vol. 99(C), pages 136-151.
    10. Khabbazian, Ghasem & Aminian, Javad & Khoshkhoo, Ramin Haghighi, 2022. "Experimental and numerical investigation of MILD combustion in a pilot-scale water heater," Energy, Elsevier, vol. 239(PA).
    11. Li, Zhiyi & Cuoci, Alberto & Sadiki, Amsini & Parente, Alessandro, 2017. "Comprehensive numerical study of the Adelaide Jet in Hot-Coflow burner by means of RANS and detailed chemistry," Energy, Elsevier, vol. 139(C), pages 555-570.
    12. Wang, G. & Si, J. & Xu, M. & Mi, J., 2019. "MILD combustion versus conventional bluff-body flame of a premixed CH4/air jet in hot coflow," Energy, Elsevier, vol. 187(C).
    13. Cheong, Kin-Pang & Wang, Guochang & Wang, Bo & Zhu, Rong & Ren, Wei & Mi, Jianchun, 2019. "Stability and emission characteristics of nonpremixed MILD combustion from a parallel-jet burner in a cylindrical furnace," Energy, Elsevier, vol. 170(C), pages 1181-1190.
    14. Wang, Qiangxiang & Xie, Mengqian & Tu, Yaojie & Liu, Hao & Li, Weijie, 2022. "Numerical study of fuel-NO formation and reduction in a reversed flow MILD combustion furnace firing ammonia-doped methane," Energy, Elsevier, vol. 252(C).
    15. Kuang, Yucheng & He, Boshu & Wang, Chaojun & Tong, Wenxiao & He, Di, 2021. "Numerical analyses of MILD and conventional combustions with the Eddy Dissipation Concept (EDC)," Energy, Elsevier, vol. 237(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Hu, Fan & Li, Pengfei & Cheng, Pengfei & Shi, Guodong & Gao, Yan & Liu, Yaowei & Ding, Cuijiao & Yang, Chao & Liu, Zhaohui, 2023. "Comparative study on homogeneous NO-reburning in flameless and swirl flame combustion," Energy, Elsevier, vol. 283(C).
    2. Fordoei, Esmaeil Ebrahimi & Boyaghchi, Fateme Ahmadi, 2022. "Influence of wall thermal conditions on the ignition, flame structure, and temperature behaviors in air-fuel, oxygen-enhanced, and oxy-fuel combustion under the MILD and high-temperature regimes," Energy, Elsevier, vol. 255(C).
    3. Zhao, Zhenghong & Zhang, Zewu & Zha, Xiaojian & Gao, Ge & Li, Xiaoshan & Wu, Fan & Luo, Cong & Zhang, Liqi, 2023. "Internal association between combustion behavior and NOx emissions of pulverized coal MILD-oxy combustion affected by adding H2O," Energy, Elsevier, vol. 263(PD).
    4. Cheong, Kin-Pang & Wang, Guochang & Si, Jicang & Mi, Jianchun, 2021. "Nonpremixed MILD combustion in a laboratory-scale cylindrical furnace: Occurrence and identification," Energy, Elsevier, vol. 216(C).
    5. Tian, Ye & Zhou, Xiong & Ji, Xuanyu & Bai, Jisong & Yuan, Liang, 2019. "Applying moderate or intense low-oxygen dilution combustion to a co-axial-jet I-shaped recuperative radiant tube for further performance enhancement," Energy, Elsevier, vol. 171(C), pages 149-160.
    6. Wang, Yi & Cheong, Kin-Pang & Wang, Junyang & Liu, Shaotong & Hu, Yong & Chyu, Minking & Mi, Jianchun, 2024. "Operational condition and furnace geometry for premixed C3H8/Air MILD combustion of high thermal-intensity and low emissions," Energy, Elsevier, vol. 288(C).
    7. Hu, Fan & Li, Pengfei & Zhang, Tai & Zu, Daohua & Cheng, Pengfei & Liu, Yaowei & Mi, Jianchun & Liu, Zhaohui, 2022. "Experimental investigation on co-firing residual char and pulverized coal under MILD combustion using low-temperature preheating air," Energy, Elsevier, vol. 244(PA).
    8. Fordoei, E. Ebrahimi & Mazaheri, Kiumars & Mohammadpour, Amirreza, 2021. "Numerical study on the heat transfer characteristics, flame structure, and pollutants emission in the MILD methane-air, oxygen-enriched and oxy-methane combustion," Energy, Elsevier, vol. 218(C).
    9. Jozaalizadeh, Toomaj & Toghraie, Davood, 2019. "Numerical investigation behavior of reacting flow for flameless oxidation technology of MILD combustion: Effect of fluctuating temperature of inlet co-flow," Energy, Elsevier, vol. 178(C), pages 530-537.
    10. Hu, Fan & Xiong, Biao & Liu, Xuhui & Huang, Xiaohong & Li, Yu & Liu, Zhaohui, 2023. "Optimized TGA-based experimental method for studying intrinsic kinetics of coal char oxidation under moderate or intense low-oxygen dilution oxy-fuel conditions," Energy, Elsevier, vol. 265(C).
    11. Sayadzadeh, Mohammad Esmaiel & Samani, Majid Riahi & Toghraie, Davood & Emami, Sobhan & Eftekhari, Seyed Ali, 2023. "Numerical study on pollutant emissions characteristics and chemical and physical exergy analysis in Mild combustion," Energy, Elsevier, vol. 278(PB).
    12. Liu, Jie & Guo, Qiang & Liang, Wenkai & Feng, Xuning & Wang, Hewu, 2024. "On the NTC behaviors in explosion limits of C1 to C3 n-alkane/air mixtures," Energy, Elsevier, vol. 294(C).
    13. Mohammadpour, Mohammadreza & Ashjaee, Mehdi & Houshfar, Ehsan, 2022. "Thermal performance and heat transfer characteristics analyses of oxy-biogas combustion in a swirl stabilized boiler under various oxidizing environments," Energy, Elsevier, vol. 261(PA).
    14. Wang, Qiangxiang & Xie, Mengqian & Tu, Yaojie & Liu, Hao & Li, Weijie, 2022. "Numerical study of fuel-NO formation and reduction in a reversed flow MILD combustion furnace firing ammonia-doped methane," Energy, Elsevier, vol. 252(C).
    15. Yang, Xiao & He, Zhihong & Qiu, Penghua & Dong, Shikui & Tan, Heping, 2019. "Numerical investigations on combustion and emission characteristics of a novel elliptical jet-stabilized model combustor," Energy, Elsevier, vol. 170(C), pages 1082-1097.
    16. Tian, Junjian & Liu, Xiang & Shi, Hao & Yao, Yurou & Ni, Zhanshi & Meng, Kengsheng & Hu, Peng & Lin, Qizhao, 2024. "Experimental study on MILD combustion of methane under non-preheated condition in a swirl combustion furnace," Applied Energy, Elsevier, vol. 363(C).
    17. Liu, Yaming & Chen, Sheng & Liu, Shi & Feng, Yongxin & Xu, Kai & Zheng, Chuguang, 2016. "Methane combustion in various regimes: First and second thermodynamic-law comparison between air-firing and oxyfuel condition," Energy, Elsevier, vol. 115(P1), pages 26-37.
    18. Cheong, Kin-Pang & Wang, Guochang & Wang, Bo & Zhu, Rong & Ren, Wei & Mi, Jianchun, 2019. "Stability and emission characteristics of nonpremixed MILD combustion from a parallel-jet burner in a cylindrical furnace," Energy, Elsevier, vol. 170(C), pages 1181-1190.
    19. Khabbazian, Ghasem & Aminian, Javad & Khoshkhoo, Ramin Haghighi, 2022. "Experimental and numerical investigation of MILD combustion in a pilot-scale water heater," Energy, Elsevier, vol. 239(PA).
    20. Wang, Feifei & Li, Pengfei & Mi, Jianchun & Wang, Jinbo, 2018. "A refined global reaction mechanism for modeling coal combustion under moderate or intense low-oxygen dilution condition," Energy, Elsevier, vol. 157(C), pages 764-777.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:277:y:2023:i:c:s0360544223010770. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.