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Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst

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  • Onyenkeadi, Victor
  • Kellici, Suela
  • Saha, Basudeb

Abstract

The synthesis of 1,2-butylene carbonate (BC) from cycloaddition reaction of 1,2-butylene oxide (BO) and carbon dioxide (CO2) was investigated using several heterogeneous catalysts in the absence of organic solvent. Continuous hydrothermal flow synthesis (CHFS) has been employed as a rapid and cleaner route for the synthesis of a highly efficient graphene-inorganic heterogeneous catalyst, ceria-lanthana-zirconia/graphene nanocomposite, represented as CeLaZr/GO. The heterogeneous catalysts have been characterised using transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD) and nitrogen adsorption/desorption (BET for measuring the surface area/pore size distribution). Ceria-lanthana-zirconia/graphene nanocomposite catalyst (CeLaZr/GO) exhibited high catalytic activity as compared to other reported heterogeneous catalysts in the absence of any organic solvent with a selectivity of 76% and 64% yield of 1,2-butylene carbonate at the reaction conditions of 408 K, 75 bar in 20 h.

Suggested Citation

  • Onyenkeadi, Victor & Kellici, Suela & Saha, Basudeb, 2018. "Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst," Energy, Elsevier, vol. 165(PA), pages 867-876.
    • Handle: RePEc:eee:energy:v:165:y:2018:i:pa:p:867-876
    DOI: 10.1016/j.energy.2018.09.135
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    References listed on IDEAS

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    1. Dinca, Cristian & Slavu, Nela & Cormoş, Călin-Cristian & Badea, Adrian, 2018. "CO2 capture from syngas generated by a biomass gasification power plant with chemical absorption process," Energy, Elsevier, vol. 149(C), pages 925-936.
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    Cited by:

    1. Bisi Olaniyan & Basudeb Saha, 2020. "Comparison of Catalytic Activity of ZIF-8 and Zr/ZIF-8 for Greener Synthesis of Chloromethyl Ethylene Carbonate by CO 2 Utilization," Energies, MDPI, vol. 13(3), pages 1-25, January.
    2. Bisi Olaniyan & Basudeb Saha, 2020. "Multiobjective Optimization for the Greener Synthesis of Chloromethyl Ethylene Carbonate by CO 2 and Epichlorohydrin via Response Surface Methodology," Energies, MDPI, vol. 13(3), pages 1-27, February.
    3. Misbahu Ladan Mohammed & Basudeb Saha, 2022. "Recent Advances in Greener and Energy Efficient Alkene Epoxidation Processes," Energies, MDPI, vol. 15(8), pages 1-15, April.

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