IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v145y2018icp486-495.html
   My bibliography  Save this article

A study of the relationship between coulombic efficiency and capacity degradation of commercial lithium-ion batteries

Author

Listed:
  • Yang, Fangfang
  • Wang, Dong
  • Zhao, Yang
  • Tsui, Kwok-Leung
  • Bae, Suk Joo

Abstract

High coulombic efficiency (CE) usually indicates a long battery cycle life. However, the relationship between long-term CE evolution and battery degradation is not fully understood yet. This paper explores the behavior of long-term CE and clarifies its relationship with capacity degradation. Cycle life tests are conducted on two types of mainstream commercial lithium-ion batteries. An incremental capacity (IC) analysis is then employed to identify battery aging mechanisms. Experimental observations along with in-depth discussions are presented regarding battery degradation, aging mechanisms, and CE evolution. From the experimental results, two typical degradation patterns are recognized. From the IC analysis, we observed that, in addition to a loss of lithium inventory, a loss of active material accelerates battery degradation and brings down CE values. From an electrochemical perspective, this paper establishes the relationship between CE evolution and capacity degradation. This relationship can help develop battery degradation models, estimate battery health states, and provide early failure warnings for a battery management system.

Suggested Citation

  • Yang, Fangfang & Wang, Dong & Zhao, Yang & Tsui, Kwok-Leung & Bae, Suk Joo, 2018. "A study of the relationship between coulombic efficiency and capacity degradation of commercial lithium-ion batteries," Energy, Elsevier, vol. 145(C), pages 486-495.
  • Handle: RePEc:eee:energy:v:145:y:2018:i:c:p:486-495
    DOI: 10.1016/j.energy.2017.12.144
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217321874
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2017.12.144?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Xuebing Han & Minggao Ouyang & Languang Lu & Jianqiu Li, 2014. "Cycle Life of Commercial Lithium-Ion Batteries with Lithium Titanium Oxide Anodes in Electric Vehicles," Energies, MDPI, vol. 7(8), pages 1-15, July.
    2. Yang, Fangfang & Xing, Yinjiao & Wang, Dong & Tsui, Kwok-Leung, 2016. "A comparative study of three model-based algorithms for estimating state-of-charge of lithium-ion batteries under a new combined dynamic loading profile," Applied Energy, Elsevier, vol. 164(C), pages 387-399.
    3. Ng, Kong Soon & Moo, Chin-Sien & Chen, Yi-Ping & Hsieh, Yao-Ching, 2009. "Enhanced coulomb counting method for estimating state-of-charge and state-of-health of lithium-ion batteries," Applied Energy, Elsevier, vol. 86(9), pages 1506-1511, September.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yang, Fangfang & Li, Weihua & Li, Chuan & Miao, Qiang, 2019. "State-of-charge estimation of lithium-ion batteries based on gated recurrent neural network," Energy, Elsevier, vol. 175(C), pages 66-75.
    2. Yang, Fangfang & Song, Xiangbao & Dong, Guangzhong & Tsui, Kwok-Leung, 2019. "A coulombic efficiency-based model for prognostics and health estimation of lithium-ion batteries," Energy, Elsevier, vol. 171(C), pages 1173-1182.
    3. Panpan Hu & W. F. Tang & C. H. Li & Shu-Lun Mak & C. Y. Li & C. C. Lee, 2023. "Joint State of Charge (SOC) and State of Health (SOH) Estimation for Lithium-Ion Batteries Packs of Electric Vehicles Based on NSSR-LSTM Neural Network," Energies, MDPI, vol. 16(14), pages 1-19, July.
    4. Lin, Cheng & Mu, Hao & Xiong, Rui & Cao, Jiayi, 2017. "Multi-model probabilities based state fusion estimation method of lithium-ion battery for electric vehicles: State-of-energy," Applied Energy, Elsevier, vol. 194(C), pages 560-568.
    5. Yang, Fangfang & Zhang, Shaohui & Li, Weihua & Miao, Qiang, 2020. "State-of-charge estimation of lithium-ion batteries using LSTM and UKF," Energy, Elsevier, vol. 201(C).
    6. Xin Lu & Hui Li & Jun Xu & Siyuan Chen & Ning Chen, 2018. "Rapid Estimation Method for State of Charge of Lithium-Ion Battery Based on Fractional Continual Variable Order Model," Energies, MDPI, vol. 11(4), pages 1-18, March.
    7. Meng, Fanbing & Yang, Fangfang & Yang, Jun & Xie, Min, 2023. "A power model considering initial battery state for remaining useful life prediction of lithium-ion batteries," Reliability Engineering and System Safety, Elsevier, vol. 237(C).
    8. Li, Shi & Pischinger, Stefan & He, Chaoyi & Liang, Liliuyuan & Stapelbroek, Michael, 2018. "A comparative study of model-based capacity estimation algorithms in dual estimation frameworks for lithium-ion batteries under an accelerated aging test," Applied Energy, Elsevier, vol. 212(C), pages 1522-1536.
    9. Wang, Ju & Xiong, Rui & Li, Linlin & Fang, Yu, 2018. "A comparative analysis and validation for double-filters-based state of charge estimators using battery-in-the-loop approach," Applied Energy, Elsevier, vol. 229(C), pages 648-659.
    10. Shehzar Shahzad Sheikh & Mahnoor Anjum & Muhammad Abdullah Khan & Syed Ali Hassan & Hassan Abdullah Khalid & Adel Gastli & Lazhar Ben-Brahim, 2020. "A Battery Health Monitoring Method Using Machine Learning: A Data-Driven Approach," Energies, MDPI, vol. 13(14), pages 1-16, July.
    11. Farmann, Alexander & Waag, Wladislaw & Sauer, Dirk Uwe, 2016. "Application-specific electrical characterization of high power batteries with lithium titanate anodes for electric vehicles," Energy, Elsevier, vol. 112(C), pages 294-306.
    12. Yang, Duo & Wang, Yujie & Pan, Rui & Chen, Ruiyang & Chen, Zonghai, 2018. "State-of-health estimation for the lithium-ion battery based on support vector regression," Applied Energy, Elsevier, vol. 227(C), pages 273-283.
    13. Wenxian Duan & Chuanxue Song & Silun Peng & Feng Xiao & Yulong Shao & Shixin Song, 2020. "An Improved Gated Recurrent Unit Network Model for State-of-Charge Estimation of Lithium-Ion Battery," Energies, MDPI, vol. 13(23), pages 1-19, December.
    14. Guoqing Jin & Lan Li & Yidan Xu & Minghui Hu & Chunyun Fu & Datong Qin, 2020. "Comparison of SOC Estimation between the Integer-Order Model and Fractional-Order Model Under Different Operating Conditions," Energies, MDPI, vol. 13(7), pages 1-17, April.
    15. Hu, Lin & Hu, Xiaosong & Che, Yunhong & Feng, Fei & Lin, Xianke & Zhang, Zhiyong, 2020. "Reliable state of charge estimation of battery packs using fuzzy adaptive federated filtering," Applied Energy, Elsevier, vol. 262(C).
    16. Bhattacharjee, Vikram & Khan, Irfan, 2018. "A non-linear convex cost model for economic dispatch in microgrids," Applied Energy, Elsevier, vol. 222(C), pages 637-648.
    17. Berecibar, M. & Gandiaga, I. & Villarreal, I. & Omar, N. & Van Mierlo, J. & Van den Bossche, P., 2016. "Critical review of state of health estimation methods of Li-ion batteries for real applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 572-587.
    18. He, Hongwen & Xiong, Rui & Peng, Jiankun, 2016. "Real-time estimation of battery state-of-charge with unscented Kalman filter and RTOS μCOS-II platform," Applied Energy, Elsevier, vol. 162(C), pages 1410-1418.
    19. Ozkurt, Celil & Camci, Fatih & Atamuradov, Vepa & Odorry, Christopher, 2016. "Integration of sampling based battery state of health estimation method in electric vehicles," Applied Energy, Elsevier, vol. 175(C), pages 356-367.
    20. Chen, Zheng & Zhao, Hongqian & Shu, Xing & Zhang, Yuanjian & Shen, Jiangwei & Liu, Yonggang, 2021. "Synthetic state of charge estimation for lithium-ion batteries based on long short-term memory network modeling and adaptive H-Infinity filter," Energy, Elsevier, vol. 228(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:145:y:2018:i:c:p:486-495. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.