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The performance of all vanadium redox flow batteries at below-ambient temperatures

Author

Listed:
  • Pan, Jianxin
  • Huang, Mianyan
  • Li, Xue
  • Wang, Shubo
  • Li, Weihua
  • Ma, Tao
  • Xie, Xiaofeng
  • Ramani, Vijay

Abstract

Temperature is a key parameter influencing the operation of the VFB (all vanadium redox flow battery). The electrochemical kinetics of both positive and negative vanadium redox couples were studied using CV (cyclic voltammetry). The CV results showed that the anodic peak current for the VO2+/VO2+ couple and the cathodic peak current for the V3+/V2+ decreased with temperature. The peak potential difference ΔEp for VO2+/VO2+ couple varied slightly with decrease in temperature while that for V3+/V2+ increased sharply from 276 mV at 30 °C to 481 mV at −10 °C, indicating that this reaction become more irreversible at the low temperature. Two VFB single cells operating at 0 and 20 °C were cycled and their performance was compared. While the low temperature reduced vanadium crossover and benefitted the coulombic efficiency, a concomitant lowering in the rate of proton transport resulted in an increase in ohmic over-potential and hence a lower voltage efficiency. The efficiencies and capacity of a VFB stack were monitored in controlled environments. The static resistance of the stack varied slightly between 26.5 and 29.0 mΩ at 5 and 10 °C, but increased to 38.1 mΩ on average at −2 °C.

Suggested Citation

  • Pan, Jianxin & Huang, Mianyan & Li, Xue & Wang, Shubo & Li, Weihua & Ma, Tao & Xie, Xiaofeng & Ramani, Vijay, 2016. "The performance of all vanadium redox flow batteries at below-ambient temperatures," Energy, Elsevier, vol. 107(C), pages 784-790.
    • Handle: RePEc:eee:energy:v:107:y:2016:i:c:p:784-790
    DOI: 10.1016/j.energy.2016.04.075
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    References listed on IDEAS

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    1. Yin, Cong & Gao, Yan & Guo, Shaoyun & Tang, Hao, 2014. "A coupled three dimensional model of vanadium redox flow battery for flow field designs," Energy, Elsevier, vol. 74(C), pages 886-895.
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    4. Vynnycky, M., 2011. "Analysis of a model for the operation of a vanadium redox battery," Energy, Elsevier, vol. 36(4), pages 2242-2256.
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    Cited by:

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    2. Chen, Wei & Kang, Jialun & Shu, Qing & Zhang, Yunsong, 2019. "Analysis of storage capacity and energy conversion on the performance of gradient and double-layered porous electrode in all-vanadium redox flow batteries," Energy, Elsevier, vol. 180(C), pages 341-355.
    3. Kim, Jungmyung & Park, Heesung, 2018. "Impact of nanofluidic electrolyte on the energy storage capacity in vanadium redox flow battery," Energy, Elsevier, vol. 160(C), pages 192-199.
    4. Kim, Jungmyung & Park, Heesung, 2019. "Electrokinetic parameters of a vanadium redox flow battery with varying temperature and electrolyte flow rate," Renewable Energy, Elsevier, vol. 138(C), pages 284-291.

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