IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v380y2025ics0306261924023250.html
   My bibliography  Save this article

Passive thermal management of CO2 Methanation using phase change material with high thermal conductivity

Author

Listed:
  • Koide, Hiroaki
  • Gunji, Akira
  • Sugimasa, Masatoshi
  • Kawaguchi, Takahiro
  • Tamzysi, Cholila
  • Nomura, Takahiro

Abstract

CO2 methanation is a promising technology for fuel decarbonization. Since methanation is an exothermic reaction, thermal management of the reactor is an important issue. This study investigated the effect of applying metallic phase change material(PCM) for reactor thermal management. In this study, Zn-30 %Al alloy(melting point: 429–509 °C)-based PCM composites were mixed with catalysts in a bench scale reactor, then steady-state and transient methanation were examined. The results at steady state indicated peak temperature was reduced from 464 °C to 411 °C compared to conventional single-catalyst condition. This corresponded to 38 % reduction in the temperature difference between peak and base temperature. Furthermore, temperature distribution in the whole reactor was homogenized, achieving a dispersion of the local thermal stress. This was due to high thermal conductivity of metallic PCM. Then, transient thermal management of PCM was evaluated. Periods for temperature increase between 430 and 450 °C, including PCM melting point, was prolonged 45 min compared to the condition without PCM. This resulted 71 % suppression of exothermic speed. This was due to complex effects of latent heat and high thermal conductivity of metallic PCM, offering thermal buffer in case of catalyst thermal runaway. These results showed the introduction of metallic PCM into methanation reactor provides novel thermal management.

Suggested Citation

  • Koide, Hiroaki & Gunji, Akira & Sugimasa, Masatoshi & Kawaguchi, Takahiro & Tamzysi, Cholila & Nomura, Takahiro, 2025. "Passive thermal management of CO2 Methanation using phase change material with high thermal conductivity," Applied Energy, Elsevier, vol. 380(C).
    • Handle: RePEc:eee:appene:v:380:y:2025:i:c:s0306261924023250
    DOI: 10.1016/j.apenergy.2024.124942
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261924023250
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2024.124942?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kawaguchi, Takahiro & Sakai, Hiroki & Sheng, Nan & Kurniawan, Ade & Nomura, Takahiro, 2020. "Microencapsulation of Zn-Al alloy as a new phase change material for middle-high-temperature thermal energy storage applications," Applied Energy, Elsevier, vol. 276(C).
    2. Philipp Biegger & Florian Kirchbacher & Ana Roza Medved & Martin Miltner & Markus Lehner & Michael Harasek, 2018. "Development of Honeycomb Methanation Catalyst and Its Application in Power to Gas Systems," Energies, MDPI, vol. 11(7), pages 1-17, June.
    3. Thema, M. & Bauer, F. & Sterner, M., 2019. "Power-to-Gas: Electrolysis and methanation status review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 775-787.
    4. Fukahori, Ryo & Nomura, Takahiro & Zhu, Chunyu & Sheng, Nan & Okinaka, Noriyuki & Akiyama, Tomohiro, 2016. "Macro-encapsulation of metallic phase change material using cylindrical-type ceramic containers for high-temperature thermal energy storage," Applied Energy, Elsevier, vol. 170(C), pages 324-328.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Costa, Sol Carolina & Kenisarin, Murat, 2022. "A review of metallic materials for latent heat thermal energy storage: Thermophysical properties, applications, and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    2. Sayama, Shogo & Yamamoto, Seiji, 2022. "A 6-kW thermally self-sustained two-stage CO2 methanation reactor: design and experimental evaluation of steady-state performance under full-load conditions," Applied Energy, Elsevier, vol. 325(C).
    3. Andrea Barbaresi & Mirko Morini & Agostino Gambarotta, 2022. "Review on the Status of the Research on Power-to-Gas Experimental Activities," Energies, MDPI, vol. 15(16), pages 1-32, August.
    4. Zhao, Kuan & Wang, Jifen & Xie, Huaqing, 2024. "A multifunctional flexible composite phase-change film with excellent solar driven thermal management," Renewable Energy, Elsevier, vol. 227(C).
    5. Ye, Yang & Lu, Jianfeng & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2020. "Numerical simulation on the storage performance of a phase change materials based metal hydride hydrogen storage tank," Applied Energy, Elsevier, vol. 278(C).
    6. Koide, Hiroaki & Kurniawan, Ade & Takahashi, Tatsuya & Kawaguchi, Takahiro & Sakai, Hiroki & Sato, Yusuke & Chiu, Justin NW. & Nomura, Takahiro, 2022. "Performance analysis of packed bed latent heat storage system for high-temperature thermal energy storage using pellets composed of micro-encapsulated phase change material," Energy, Elsevier, vol. 238(PC).
    7. Georgios Varvoutis & Athanasios Lampropoulos & Evridiki Mandela & Michalis Konsolakis & George E. Marnellos, 2022. "Recent Advances on CO 2 Mitigation Technologies: On the Role of Hydrogenation Route via Green H 2," Energies, MDPI, vol. 15(13), pages 1-38, June.
    8. Navarro, J.C. & Baena-Moreno, F.M. & Centeno, M.A. & Laguna, O.H. & Almagro, J.F. & Odriozola, J.A., 2023. "Process design and utilisation strategy for CO2 capture in flue gases. Technical assessment and preliminary economic approach for steel mills," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    9. Nomura, Takahiro & Zhu, Chunyu & Nan, Sheng & Tabuchi, Kazuki & Wang, Shuangfeng & Akiyama, Tomohiro, 2016. "High thermal conductivity phase change composite with a metal-stabilized carbon-fiber network," Applied Energy, Elsevier, vol. 179(C), pages 1-6.
    10. Yu, De-Hai & He, Zhi-Zhu, 2019. "Shape-remodeled macrocapsule of phase change materials for thermal energy storage and thermal management," Applied Energy, Elsevier, vol. 247(C), pages 503-516.
    11. Chauvy, Remi & Dubois, Lionel & Lybaert, Paul & Thomas, Diane & De Weireld, Guy, 2020. "Production of synthetic natural gas from industrial carbon dioxide," Applied Energy, Elsevier, vol. 260(C).
    12. Zhao, Y. & You, Y. & Liu, H.B. & Zhao, C.Y. & Xu, Z.G., 2018. "Experimental study on the thermodynamic performance of cascaded latent heat storage in the heat charging process," Energy, Elsevier, vol. 157(C), pages 690-706.
    13. Bidart, Christian & Wichert, Martin & Kolb, Gunther & Held, Michael, 2022. "Biogas catalytic methanation for biomethane production as fuel in freight transport - A carbon footprint assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    14. Corey Duncan & Robin Roche & Samir Jemei & Marie-Cécile Péra, 2022. "Techno-economical modelling of a power-to-gas system for plant configuration evaluation in a local context," Post-Print hal-03692975, HAL.
    15. Ye, Yang & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2021. "The storage performance of metal hydride hydrogen storage tanks with reaction heat recovery by phase change materials," Applied Energy, Elsevier, vol. 299(C).
    16. Rezaee Jordehi, Ahmad & Mansouri, Seyed Amir & Tostado-Véliz, Marcos & Sirjani, Reza & Safaraliev, Murodbek & Nasir, Mohammad, 2024. "A three-level model for integration of hydrogen refuelling stations in interconnected power-gas networks considering vehicle-to-infrastructure (V2I) technology," Energy, Elsevier, vol. 308(C).
    17. Michael Sterner & Michael Specht, 2021. "Power-to-Gas and Power-to-X—The History and Results of Developing a New Storage Concept," Energies, MDPI, vol. 14(20), pages 1-18, October.
    18. Sánchez, Antonio & Martín, Mariano & Zhang, Qi, 2021. "Optimal design of sustainable power-to-fuels supply chains for seasonal energy storage," Energy, Elsevier, vol. 234(C).
    19. Drechsler, Carsten & Agar, David W., 2020. "Intensified integrated direct air capture - power-to-gas process based on H2O and CO2 from ambient air," Applied Energy, Elsevier, vol. 273(C).
    20. Speckmann, Friedrich-W. & Keiner, Dominik & Birke, Kai Peter, 2020. "Influence of rectifiers on the techno-economic performance of alkaline electrolysis in a smart grid environment," Renewable Energy, Elsevier, vol. 159(C), pages 107-116.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:380:y:2025:i:c:s0306261924023250. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.