IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v348y2023ics0306261923009297.html
   My bibliography  Save this article

Experimental and simulation of PEM water electrolyser with Pd/PN-CNPs electrodes for hydrogen evolution reaction: Performance assessment and validation

Author

Listed:
  • Kumar, S. Shiva
  • Ni, Aleksey
  • Himabindu, V.
  • Lim, Hankwon

Abstract

Water electrolysis using a proton exchange membrane (PEM) offers a sustainable solution for green hydrogen production from intermittent renewable energy sources. However, the utilization of costly electrode materials and cell components has resulted in expensive hydrogen production costs and limited its commercial applications. Furthermore, the management of gas-liquid flow and thermal distributions presents significant challenges in the operation of PEM water electrolysers. In this study, a COMSOL Multiphysics model was developed for a 25 cm2 single cell PEM water electrolyser with parallel flow field configurations to investigate its performance including operating principles, mechanisms, and ion transport properties. Subsequently, the model was validated with in-house experimental data at different operating conditions. Impressively, it effectively predicted the current-voltage polarization curves, demonstrating strong correlation with the experimental data. For a more rigorous comparison between experimental and numerical simulation, the normalized root mean square deviation was calculated for current-voltage polarization curves at various temperatures, ranging from 30 °C to 80 °C. The deviation was observed to be around 1.1% across all the temperatures, an acceptably low error value. In addition, the model was used to analyze the reactant flow and thermal distributions. This work can provide both experimental and simulation support for the selection and optimization of operating conditions, including flow fields in PEM water electrolysers.

Suggested Citation

  • Kumar, S. Shiva & Ni, Aleksey & Himabindu, V. & Lim, Hankwon, 2023. "Experimental and simulation of PEM water electrolyser with Pd/PN-CNPs electrodes for hydrogen evolution reaction: Performance assessment and validation," Applied Energy, Elsevier, vol. 348(C).
    • Handle: RePEc:eee:appene:v:348:y:2023:i:c:s0306261923009297
    DOI: 10.1016/j.apenergy.2023.121565
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261923009297
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2023.121565?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Hughes, J.P. & Clipsham, J. & Chavushoglu, H. & Rowley-Neale, S.J. & Banks, C.E., 2021. "Polymer electrolyte electrolysis: A review of the activity and stability of non-precious metal hydrogen evolution reaction and oxygen evolution reaction catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    2. Scheepers, Fabian & Stähler, Markus & Stähler, Andrea & Rauls, Edward & Müller, Martin & Carmo, Marcelo & Lehnert, Werner, 2021. "Temperature optimization for improving polymer electrolyte membrane-water electrolysis system efficiency," Applied Energy, Elsevier, vol. 283(C).
    3. Ruiz Diaz, Daniela Fernanda & Valenzuela, Edgar & Wang, Yun, 2022. "A component-level model of polymer electrolyte membrane electrolysis cells for hydrogen production," Applied Energy, Elsevier, vol. 321(C).
    4. Lin, Rui & Lu, Ying & Xu, Ji & Huo, Jiawei & Cai, Xin, 2022. "Investigation on performance of proton exchange membrane electrolyzer with different flow field structures," Applied Energy, Elsevier, vol. 326(C).
    5. Upadhyay, Mukesh & Kim, Ayeon & Paramanantham, SalaiSargunan S. & Kim, Heehyang & Lim, Dongjun & Lee, Sunyoung & Moon, Sangbong & Lim, Hankwon, 2022. "Three-dimensional CFD simulation of proton exchange membrane water electrolyser: Performance assessment under different condition," Applied Energy, Elsevier, vol. 306(PA).
    6. Hu, Kewei & Fang, Jiakun & Ai, Xiaomeng & Huang, Danji & Zhong, Zhiyao & Yang, Xiaobo & Wang, Lei, 2022. "Comparative study of alkaline water electrolysis, proton exchange membrane water electrolysis and solid oxide electrolysis through multiphysics modeling," Applied Energy, Elsevier, vol. 312(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Su, Chao & Chen, Zhidong & Wu, Zexuan & Zhang, Jing & Li, Kaiyang & Hao, Junhong & Kong, Yanqiang & Zhang, Naiqiang, 2024. "Experimental and numerical study of thermal coupling on catalyst-coated membrane for proton exchange membrane water electrolyzer," Applied Energy, Elsevier, vol. 357(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Taehyung Koo & Rockkil Ko & Dongwoo Ha & Jaeyoung Han, 2023. "Development of Model-Based PEM Water Electrolysis HILS (Hardware-in-the-Loop Simulation) System for State Evaluation and Fault Detection," Energies, MDPI, vol. 16(8), pages 1-18, April.
    2. Li, Yuxuan & Li, Hongkun & Liu, Weiqun & Zhu, Qiao, 2024. "Optimization of membrane thickness for proton exchange membrane electrolyzer considering hydrogen production efficiency and hydrogen permeation phenomenon," Applied Energy, Elsevier, vol. 355(C).
    3. Lin, Rui & Lu, Ying & Xu, Ji & Huo, Jiawei & Cai, Xin, 2022. "Investigation on performance of proton exchange membrane electrolyzer with different flow field structures," Applied Energy, Elsevier, vol. 326(C).
    4. Wang, Jianxiao & An, Qi & Zhao, Yue & Pan, Guangsheng & Song, Jie & Hu, Qinran & Tan, Chin-Woo, 2023. "Role of electrolytic hydrogen in smart city decarbonization in China," Applied Energy, Elsevier, vol. 336(C).
    5. Lamichhane, Pradeep & Pourali, Nima & Scott, Lauren & Tran, Nam N. & Lin, Liangliang & Gelonch, Marc Escribà & Rebrov, Evgeny V. & Hessel, Volker, 2024. "Critical review: ‘Green’ ethylene production through emerging technologies, with a focus on plasma catalysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    6. Dong, Tianshu & Duan, Xiudong & Huang, Yuanyuan & Huang, Danji & Luo, Yingdong & Liu, Ziyu & Ai, Xiaomeng & Fang, Jiakun & Song, Chaolong, 2024. "Enhancement of hydrogen production via optimizing micro-structures of electrolyzer on a microfluidic platform," Applied Energy, Elsevier, vol. 356(C).
    7. Su, Chao & Chen, Zhidong & Wu, Zexuan & Zhang, Jing & Li, Kaiyang & Hao, Junhong & Kong, Yanqiang & Zhang, Naiqiang, 2024. "Experimental and numerical study of thermal coupling on catalyst-coated membrane for proton exchange membrane water electrolyzer," Applied Energy, Elsevier, vol. 357(C).
    8. Nikolaos Margaritis & Christos Evaggelou & Panagiotis Grammelis & Roberto Arévalo & Haris Yiannoulakis & Polykarpos Papageorgiou, 2023. "Application of Flexible Tools in Magnesia Sector: The Case of Grecian Magnesite," Sustainability, MDPI, vol. 15(16), pages 1-30, August.
    9. Xu, Chenyang & Wang, Jian & Wang, Jianzhong & Yang, Kun & Li, Guangzhong & Gao, Wenbin & Wang, Hao & Zhao, Shaoyang, 2024. "Structural optimization study on porous transport layers of sintered titanium for polymer electrolyte membrane electrolyzers," Applied Energy, Elsevier, vol. 357(C).
    10. Abdollahipour, Armin & Sayyaadi, Hoseyn, 2022. "A novel electrochemical refrigeration system based on the combined proton exchange membrane fuel cell-electrolyzer," Applied Energy, Elsevier, vol. 316(C).
    11. Giuseppe Corda & Antonio Cucurachi & Stefano Fontanesi & Alessandro d’Adamo, 2023. "Three-Dimensional CFD Simulation of a Proton Exchange Membrane Electrolysis Cell," Energies, MDPI, vol. 16(16), pages 1-17, August.
    12. Hassan Salihi & Hyunchul Ju, 2023. "Two-Phase Modeling and Simulations of a Polymer Electrolyte Membrane Water Electrolyzer Considering Key Morphological and Geometrical Features in Porous Transport Layers," Energies, MDPI, vol. 16(2), pages 1-18, January.
    13. Mohsen Fallah Vostakola & Hasan Ozcan & Rami S. El-Emam & Bahman Amini Horri, 2023. "Recent Advances in High-Temperature Steam Electrolysis with Solid Oxide Electrolysers for Green Hydrogen Production," Energies, MDPI, vol. 16(8), pages 1-50, April.
    14. Liu, Hongwei & Ren, He & Gu, Yajing & Lin, Yonggang & Hu, Weifei & Song, Jiajun & Yang, Jinhong & Zhu, Zengxin & Li, Wei, 2023. "Design and on-site implementation of an off-grid marine current powered hydrogen production system," Applied Energy, Elsevier, vol. 330(PB).
    15. Nie, Wen & Jiang, Chenwang & Sun, Ning & Guo, Lidian & Xue, Qianqian & Liu, Qiang & Liu, Chengyi & Cha, Xingpeng & Yi, Shixing, 2023. "Analysis of multi-factor ventilation parameters for reducing energy air pollution in coal mines," Energy, Elsevier, vol. 278(PA).
    16. Badakhsh, Arash & Mothilal Bhagavathy, Sivapriya, 2024. "Caveats of green hydrogen for decarbonisation of heating in buildings," Applied Energy, Elsevier, vol. 353(PB).
    17. Srivastava, Nitish & Saquib, Mohammad & Rajput, Pramod & Bhosale, Amit C. & Singh, Rhythm & Arora, Pratham, 2023. "Prospects of solar-powered nitrogenous fertilizers," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).
    18. Fu, J.L. & Qu, Z.G. & Zhang, J.F. & Zhang, G.B., 2023. "Performance analysis of PEMEC with non-uniform deformation based on a comprehensive numerical framework coupling image recognition and CFD," Applied Energy, Elsevier, vol. 350(C).
    19. Sadiq, Muhammad & Alshehhi, Reem J. & Urs, Rahul Rajeevkumar & Mayyas, Ahmad T., 2023. "Techno-economic analysis of Green-H2@Scale production," Renewable Energy, Elsevier, vol. 219(P1).
    20. Jivan Thakare & Jahangir Masud, 2022. "Magnéli TiO 2 as a High Durability Support for the Proton Exchange Membrane (PEM) Fuel Cell Catalysts," Energies, MDPI, vol. 15(12), pages 1-10, June.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:348:y:2023:i:c:s0306261923009297. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.