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Life cycle and economic analysis of chemicals production via electrolytic (bi)carbonate and gaseous CO2 conversion

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  • Yue, Pengtao
  • Kang, Zhongyin
  • Fu, Qian
  • Li, Jun
  • Zhang, Liang
  • Zhu, Xun
  • Liao, Qiang

Abstract

Electrochemical CO2 reduction provides a new insight to produce value-added chemicals production, but it requires a large amount of energy inputs to support the process of CO2 capture (i.e., desorption and separation process). Carbon-based fuels production via electrolytic (bi)carbonate conversion can bypass the energy-intensive steps (desorption and separation), becoming more environmental-friendly compared to electrolytic gaseous CO2-to-chemicals conversion. Here, we comprehensively explore and assess the energy conversion and environmental impacts, and economic benefits of the (bi)carbonate-to-chemicals and gaseous CO2-to-chemicals conversions using life cycle and economic assessments. The results show that the (bi)carbonate-to-chemicals conversion promote the energy and environmental benefits but reduce the economic benefits. (Bi)carbonate-to-formate and -CO conversion show low net energy ratio (1.90 and 1.93, respectively) and Greenhouse gas emissions (−0.5238 and −0.6287 t CO2-eq/t CO2 gas injection, respectively). While gaseous CO2-to-formate and -CO conversion are more industrially feasible for commercial application due to their lower overpotentials, higher current density, and higher Faradaic efficiency. Additionally, the sensitivity analysis show that the (bi)carbonate-to-chemicals systems are more promising through reducing the overpotential, enhancing the current density and Faradaic efficiency of the systems. This work demonstrates that electrolytic (bi)carbonate-to-chemicals conversion systems are eco-friendly, and give a theoretical guide to develop this energy-efficient CO2 utilization approach.

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  • Yue, Pengtao & Kang, Zhongyin & Fu, Qian & Li, Jun & Zhang, Liang & Zhu, Xun & Liao, Qiang, 2021. "Life cycle and economic analysis of chemicals production via electrolytic (bi)carbonate and gaseous CO2 conversion," Applied Energy, Elsevier, vol. 304(C).
    • Handle: RePEc:eee:appene:v:304:y:2021:i:c:s0306261921011077
    DOI: 10.1016/j.apenergy.2021.117768
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    as
    1. Xue Wang & Ziyun Wang & F. Pelayo García de Arquer & Cao-Thang Dinh & Adnan Ozden & Yuguang C. Li & Dae-Hyun Nam & Jun Li & Yi-Sheng Liu & Joshua Wicks & Zitao Chen & Miaofang Chi & Bin Chen & Ying Wa, 2020. "Efficient electrically powered CO2-to-ethanol via suppression of deoxygenation," Nature Energy, Nature, vol. 5(6), pages 478-486, June.
    2. Xiao, Chao & Fu, Qian & Liao, Qiang & Huang, Yun & Xia, Ao & Chen, Hao & Zhu, Xun, 2020. "Life cycle and economic assessments of biogas production from microalgae biomass with hydrothermal pretreatment via anaerobic digestion," Renewable Energy, Elsevier, vol. 151(C), pages 70-78.
    3. Del Castillo, A. & Alvarez-Guerra, M. & Solla-Gullón, J. & Sáez, A. & Montiel, V. & Irabien, A., 2015. "Electrocatalytic reduction of CO2 to formate using particulate Sn electrodes: Effect of metal loading and particle size," Applied Energy, Elsevier, vol. 157(C), pages 165-173.
    4. Jun Li & Fanglin Che & Yuanjie Pang & Chengqin Zou & Jane Y. Howe & Thomas Burdyny & Jonathan P. Edwards & Yuhang Wang & Fengwang Li & Ziyun Wang & Phil De Luna & Cao-Thang Dinh & Tao-Tao Zhuang & Mak, 2018. "Copper adparticle enabled selective electrosynthesis of n-propanol," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    5. Zeng, L. & Tang, Z.K. & Zhao, T.S., 2014. "A high-performance alkaline exchange membrane direct formate fuel cell," Applied Energy, Elsevier, vol. 115(C), pages 405-410.
    6. Edwards, Jonathan P. & Xu, Yi & Gabardo, Christine M. & Dinh, Cao-Thang & Li, Jun & Qi, ZhenBang & Ozden, Adnan & Sargent, Edward H. & Sinton, David, 2020. "Efficient electrocatalytic conversion of carbon dioxide in a low-resistance pressurized alkaline electrolyzer," Applied Energy, Elsevier, vol. 261(C).
    7. Hengpan Yang & Qing Lin & Chao Zhang & Xinyao Yu & Zhong Cheng & Guodong Li & Qi Hu & Xiangzhong Ren & Qianling Zhang & Jianhong Liu & Chuanxin He, 2020. "Carbon dioxide electroreduction on single-atom nickel decorated carbon membranes with industry compatible current densities," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    8. Sun, Chi-He & Fu, Qian & Liao, Qiang & Xia, Ao & Huang, Yun & Zhu, Xun & Reungsang, Alissara & Chang, Hai-Xing, 2019. "Life-cycle assessment of biofuel production from microalgae via various bioenergy conversion systems," Energy, Elsevier, vol. 171(C), pages 1033-1045.
    9. Xingli Wang & Katharina Klingan & Malte Klingenhof & Tim Möller & Jorge Ferreira de Araújo & Isaac Martens & Alexander Bagger & Shan Jiang & Jan Rossmeisl & Holger Dau & Peter Strasser, 2021. "Morphology and mechanism of highly selective Cu(II) oxide nanosheet catalysts for carbon dioxide electroreduction," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
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    1. Mengran Li & Erdem Irtem & Hugo-Pieter Iglesias van Montfort & Maryam Abdinejad & Thomas Burdyny, 2022. "Energy comparison of sequential and integrated CO2 capture and electrochemical conversion," Nature Communications, Nature, vol. 13(1), pages 1-11, December.

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