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A high-performance alkaline exchange membrane direct formate fuel cell

Author

Listed:
  • Zeng, L.
  • Tang, Z.K.
  • Zhao, T.S.

Abstract

This paper reports on a single alkaline exchange membrane direct formate fuel cell (AEM DFFC) consisting of a carbon-supported palladium catalyst at the anode, a quaternized polysulfone membrane, and a non-precious Fe–Co catalyst at the cathode. It is demonstrated that the AEM DFFC yields a peak power density of 130mWcm−2 with 5M potassium formate (HCOOK) at 80°C. It is further shown that with the addition of KOH to the anolyte, the peak power density rises to as high as 250mWcm−2 at the same operating temperature. In addition, the AEM DFFC was also tested at 100mAcm−2 for more than 130h and no significant degradation in performance is found. The results reported in this work suggest that formate salt (HCOOM, M+=Na+ or K+) is a potential fuel for alkaline-type direct liquid fuel cells.

Suggested Citation

  • Zeng, L. & Tang, Z.K. & Zhao, T.S., 2014. "A high-performance alkaline exchange membrane direct formate fuel cell," Applied Energy, Elsevier, vol. 115(C), pages 405-410.
    • Handle: RePEc:eee:appene:v:115:y:2014:i:c:p:405-410
    DOI: 10.1016/j.apenergy.2013.11.039
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    Citations

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    Cited by:

    1. Do-Hyeong Kim & Moon-Sung Kang, 2020. "Pore-Filled Anion-Exchange Membranes with Double Cross-Linking Structure for Fuel Cells and Redox Flow Batteries," Energies, MDPI, vol. 13(18), pages 1-16, September.
    2. Wang, L.Q. & Bellini, M. & Filippi, J. & Folliero, M. & Lavacchi, A. & Innocenti, M. & Marchionni, A. & Miller, H.A. & Vizza, F., 2016. "Energy efficiency of platinum-free alkaline direct formate fuel cells," Applied Energy, Elsevier, vol. 175(C), pages 479-487.
    3. Muneeb, Omar & Do, Emily & Boyd, Desiree & Perez, Josh & Haan, John L., 2019. "PdCu/C anode catalysts for the alkaline ascorbate fuel cell," Applied Energy, Elsevier, vol. 235(C), pages 473-479.
    4. Deng, Hao & Wang, Dawei & Wang, Renfang & Xie, Xu & Yin, Yan & Du, Qing & Jiao, Kui, 2016. "Effect of electrode design and operating condition on performance of hydrogen alkaline membrane fuel cell," Applied Energy, Elsevier, vol. 183(C), pages 1272-1278.
    5. Saric, Steven & Biggs, Brenna & Janbahan, Mika & Hamilton, Ryan & Do, Huy K. & Mayoral, Salvador & Haan, John L., 2016. "An integrated device to convert carbon dioxide to energy," Applied Energy, Elsevier, vol. 183(C), pages 1346-1350.
    6. Hamish Andrew Miller & Jacopo Ruggeri & Andrea Marchionni & Marco Bellini & Maria Vincenza Pagliaro & Carlo Bartoli & Andrea Pucci & Elisa Passaglia & Francesco Vizza, 2018. "Improving the Energy Efficiency of Direct Formate Fuel Cells with a Pd/C-CeO 2 Anode Catalyst and Anion Exchange Ionomer in the Catalyst Layer," Energies, MDPI, vol. 11(2), pages 1-12, February.
    7. Yue, Pengtao & Kang, Zhongyin & Fu, Qian & Li, Jun & Zhang, Liang & Zhu, Xun & Liao, Qiang, 2021. "Life cycle and economic analysis of chemicals production via electrolytic (bi)carbonate and gaseous CO2 conversion," Applied Energy, Elsevier, vol. 304(C).
    8. Chao, Shujun & Zhang, Yatian & Wang, Kui & Bai, Zhengyu & Yang, Lin, 2016. "Flower–like Ni and N codoped hierarchical porous carbon microspheres with enhanced performance for fuel cell storage," Applied Energy, Elsevier, vol. 175(C), pages 421-428.

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