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Oxidation kinetic modelling of Fe-based oxygen carriers for chemical looping applications: Impact of the topochemical effect

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  • Chen, Yu-Yen
  • Nadgouda, Sourabh
  • Shah, Vedant
  • Fan, Liang-Shih
  • Tong, Andrew

Abstract

Chemical looping is a promising technology for fossil fuel utilization due to its high fuel conversion efficiency with in-situ CO2 capture capability. Metal oxide are used as oxygen carriers (OCs) and circulate between a fuel reactor and an air reactor to perform reduction and oxidation reactions, respectively. In general, OC exiting the fuel reactor is not reduced fully to its metallic state due to many factors including carbon deposition and OC deactivation. Therefore, the effect of the initial reduction state on the OC oxidation in the air reactor is a significant parameter for consideration in developing the oxidation kinetic model. The objective of this work is to develop a physically significant kinetic model that applies to the oxidation of both initially fully and partially reduced OC with air. For this study, 1.5 mm Fe-based OC particle supported with TiO2 was used as the model OC particle due to its complex multistep reaction nature. The oxidation kinetics were experimentally investigated in a thermogravimetric analyzer (TGA). Results indicate a significant difference in the oxidation rate profile for the OCs when oxidized from an initially fully reduced compared to an initially partially reduced state. Elemental mapping via energy-dispersive X-ray spectroscopy (EDS) reveals a shrinking-core type topochemical pattern across the OC particle, which was identified to be the cause of the dependency of kinetics on the initial reduction state. A generalized kinetic model was developed based on the observed shrinking-core behavior without presuming any rate-determining steps and experimentally validated over a broad range of temperatures (800–1000 °C) and oxygen concentrations (5, 7, 10, and 15 mol%). Impacts of particle porosity, size, and core-shell structure on the OC oxidation kinetics were analyzed in the developed oxidation kinetic model to suggest methods of improving the oxidation rate of the OC without modifying the chemical composition.

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  • Chen, Yu-Yen & Nadgouda, Sourabh & Shah, Vedant & Fan, Liang-Shih & Tong, Andrew, 2020. "Oxidation kinetic modelling of Fe-based oxygen carriers for chemical looping applications: Impact of the topochemical effect," Applied Energy, Elsevier, vol. 279(C).
    • Handle: RePEc:eee:appene:v:279:y:2020:i:c:s030626192031196x
    DOI: 10.1016/j.apenergy.2020.115701
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    1. Benincosa, William & Siriwardane, Ranjani & Tian, Hanjing & Riley, Jarrett & Poston, James, 2020. "A particle-scale reduction model of copper iron manganese oxide with CO for chemical looping combustion," Applied Energy, Elsevier, vol. 262(C).
    2. Huang, Jijiang & Liu, Wen & Hu, Wenting & Metcalfe, Ian & Yang, Yanhui & Liu, Bin, 2019. "Phase interactions in Ni-Cu-Al2O3 mixed oxide oxygen carriers for chemical looping applications," Applied Energy, Elsevier, vol. 236(C), pages 635-647.
    3. Zhu, Yanyan & Jin, Nannan & Liu, Ruilin & Sun, Xueyan & Bai, Lei & Tian, Hanjing & Ma, Xiaoxun & Wang, Xiaodong, 2020. "Bimetallic BaFe2MAl9O19 (M = Mn, Ni, and Co) hexaaluminates as oxygen carriers for chemical looping dry reforming of methane," Applied Energy, Elsevier, vol. 258(C).
    4. Rana, Shazadi & Sun, Zhenkun & Mehrani, Poupak & Hughes, Robin & Macchi, Arturo, 2019. "Ilmenite oxidation kinetics for pressurized chemical looping combustion of natural gas," Applied Energy, Elsevier, vol. 238(C), pages 747-759.
    5. Xu, Dikai & Zhang, Yitao & Hsieh, Tien-Lin & Guo, Mengqing & Qin, Lang & Chung, Cheng & Fan, Liang-Shih & Tong, Andrew, 2018. "A novel chemical looping partial oxidation process for thermochemical conversion of biomass to syngas," Applied Energy, Elsevier, vol. 222(C), pages 119-131.
    6. Medrano, J.A. & Hamers, H.P. & Williams, G. & van Sint Annaland, M. & Gallucci, F., 2015. "NiO/CaAl2O4 as active oxygen carrier for low temperature chemical looping applications," Applied Energy, Elsevier, vol. 158(C), pages 86-96.
    7. Hsieh, Tien-Lin & Xu, Dikai & Zhang, Yitao & Nadgouda, Sourabh & Wang, Dawei & Chung, Cheng & Pottimurphy, Yaswanth & Guo, Mengqing & Chen, Yu-Yen & Xu, Mingyuan & He, Pengfei & Fan, Liang-Shih & Tong, 2018. "250 kWth high pressure pilot demonstration of the syngas chemical looping system for high purity H2 production with CO2 capture," Applied Energy, Elsevier, vol. 230(C), pages 1660-1672.
    8. Riley, Jarrett & Siriwardane, Ranjani & Tian, Hanjing & Benincosa, William & Poston, James, 2019. "Particle scale modeling of CuFeAlO4 during reduction with CO in chemical looping applications," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
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