IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v190y2017icp1221-1233.html
   My bibliography  Save this article

Molybdenum sulphides on carbon supports as electrocatalysts for hydrogen evolution in acidic industrial wastewater

Author

Listed:
  • Kokko, M.
  • Bayerköhler, F.
  • Erben, J.
  • Zengerle, R.
  • Kurz, Ph.
  • Kerzenmacher, S.

Abstract

Microbial electrolysis cells (MECs) are an attractive future alternative technology to generate renewable hydrogen and simultaneously treat wastewaters. The thermodynamics of hydrogen evolution in MECs can be greatly improved by operating the cathode at acidic pH in combination with a neutral pH microbial anode. This can easily be achieved with acidic industrial wastewaters that have to be neutralised before discharge. For the hydrogen evolution reaction (HER) in acidic wastewater, efficient and inexpensive catalysts are required that are compatible with the often complex chemical composition of wastewaters. In this study, molybdenum sulphides (MoSx) on different carbon supports were successfully used for hydrogen evolution in different acidic media. At first, the cathodes were screened by linear sweep voltammetry in sulphuric acid (pH 0) or phosphate buffer (pH 2.2). After this, the overpotentials for H2 production of the best cathodes and their long term performances (⩾1week) were determined in acidic industrial wastewater (pH 2.4) obtained from a plant mainly producing cellulose acetate. For the most promising MoSx cathodes, the overpotentials for HER (at 3mAcm−2) were only ∼40mV higher than for a platinum electrode. Most importantly, the catalytic efficiency of the MoSx electrodes improved in the wastewater over time (7–17days), while Pt electrodes were found to be slowly deactivated. Thus, MoSx emerges as an affordable, efficient and especially durable electrocatalyst for HER in real acidic wastewaters and this could be an important contribution to take energy production from wastewaters in the form of hydrogen towards practical applications.

Suggested Citation

  • Kokko, M. & Bayerköhler, F. & Erben, J. & Zengerle, R. & Kurz, Ph. & Kerzenmacher, S., 2017. "Molybdenum sulphides on carbon supports as electrocatalysts for hydrogen evolution in acidic industrial wastewater," Applied Energy, Elsevier, vol. 190(C), pages 1221-1233.
    • Handle: RePEc:eee:appene:v:190:y:2017:i:c:p:1221-1233
    DOI: 10.1016/j.apenergy.2016.12.097
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916318670
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.12.097?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Hosseini, Seyed Ehsan & Wahid, Mazlan Abdul, 2016. "Hydrogen production from renewable and sustainable energy resources: Promising green energy carrier for clean development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 850-866.
    2. Kadier, Abudukeremu & Kalil, Mohd Sahaid & Abdeshahian, Peyman & Chandrasekhar, K. & Mohamed, Azah & Azman, Nadia Farhana & Logroño, Washington & Simayi, Yibadatihan & Hamid, Aidil Abdul, 2016. "Recent advances and emerging challenges in microbial electrolysis cells (MECs) for microbial production of hydrogen and value-added chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 501-525.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Liang, Dandan & Zhang, Lijuan & He, Weihua & Li, Chao & Liu, Junfeng & Liu, Shaoqin & Lee, Hyung-Sool & Feng, Yujie, 2020. "Efficient hydrogen recovery with CoP-NF as cathode in microbial electrolysis cells," Applied Energy, Elsevier, vol. 264(C).
    2. Fischer, Fabian, 2018. "Photoelectrode, photovoltaic and photosynthetic microbial fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 16-27.
    3. Tian, Hailin & Li, Jie & Yan, Miao & Tong, Yen Wah & Wang, Chi-Hwa & Wang, Xiaonan, 2019. "Organic waste to biohydrogen: A critical review from technological development and environmental impact analysis perspective," Applied Energy, Elsevier, vol. 256(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shirzad, Mohammad & Kazemi Shariat Panahi, Hamed & Dashti, Behrouz B. & Rajaeifar, Mohammad Ali & Aghbashlo, Mortaza & Tabatabaei, Meisam, 2019. "A comprehensive review on electricity generation and GHG emission reduction potentials through anaerobic digestion of agricultural and livestock/slaughterhouse wastes in Iran," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 571-594.
    2. Khan, Mohd Atiqueuzzaman & Ngo, Huu Hao & Guo, Wenshan & Liu, Yiwen & Zhang, Xinbo & Guo, Jianbo & Chang, Soon Woong & Nguyen, Dinh Duc & Wang, Jie, 2018. "Biohydrogen production from anaerobic digestion and its potential as renewable energy," Renewable Energy, Elsevier, vol. 129(PB), pages 754-768.
    3. Lucey, Brian & Yahya, Muhammad & Khoja, Layla & Uddin, Gazi Salah & Ahmed, Ali, 2024. "Interconnectedness and risk profile of hydrogen against major asset classes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).
    4. Yang, Wei & Bao, Jingjing & Liu, Hongtao & Zhang, Jun & Guo, Lin, 2023. "Low-grade heat to hydrogen: Current technologies, challenges and prospective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    5. Rousseau, Raphaël & Etcheverry, Luc & Roubaud, Emma & Basséguy, Régine & Délia, Marie-Line & Bergel, Alain, 2020. "Microbial electrolysis cell (MEC): Strengths, weaknesses and research needs from electrochemical engineering standpoint," Applied Energy, Elsevier, vol. 257(C).
    6. Al-Qahtani, Amjad & Parkinson, Brett & Hellgardt, Klaus & Shah, Nilay & Guillen-Gosalbez, Gonzalo, 2021. "Uncovering the true cost of hydrogen production routes using life cycle monetisation," Applied Energy, Elsevier, vol. 281(C).
    7. Yoon, Kwangsuk & Lee, Sang Soo & Ok, Yong Sik & Kwon, Eilhann E. & Song, Hocheol, 2019. "Enhancement of syngas for H2 production via catalytic pyrolysis of orange peel using CO2 and bauxite residue," Applied Energy, Elsevier, vol. 254(C).
    8. Barbara Uliasz-Misiak & Joanna Lewandowska-Śmierzchalska & Rafał Matuła & Radosław Tarkowski, 2022. "Prospects for the Implementation of Underground Hydrogen Storage in the EU," Energies, MDPI, vol. 15(24), pages 1-17, December.
    9. Felix T. Haase & Arno Bergmann & Travis E. Jones & Janis Timoshenko & Antonia Herzog & Hyo Sang Jeon & Clara Rettenmaier & Beatriz Roldan Cuenya, 2022. "Size effects and active state formation of cobalt oxide nanoparticles during the oxygen evolution reaction," Nature Energy, Nature, vol. 7(8), pages 765-773, August.
    10. Mostafa Ahmed & Mohamed Abdelrahem & Ibrahim Harbi & Ralph Kennel, 2020. "An Adaptive Model-Based MPPT Technique with Drift-Avoidance for Grid-Connected PV Systems," Energies, MDPI, vol. 13(24), pages 1-25, December.
    11. Kumar, Aman & Singh, Ekta & Mishra, Rahul & Lo, Shang Lien & Kumar, Sunil, 2023. "Global trends in municipal solid waste treatment technologies through the lens of sustainable energy development opportunity," Energy, Elsevier, vol. 275(C).
    12. Qolipour, Mojtaba & Mostafaeipour, Ali & Tousi, Omid Mohseni, 2017. "Techno-economic feasibility of a photovoltaic-wind power plant construction for electric and hydrogen production: A case study," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 113-123.
    13. María Pilar González-Vázquez & Roberto García & Covadonga Pevida & Fernando Rubiera, 2017. "Optimization of a Bubbling Fluidized Bed Plant for Low-Temperature Gasification of Biomass," Energies, MDPI, vol. 10(3), pages 1-16, March.
    14. Stolarski, Mariusz J. & Dudziec, Paweł & Krzyżaniak, Michał & Graban, Łukasz & Lajszner, Waldemar & Olba–Zięty, Ewelina, 2024. "How do key for the bioenergy industry properties of baled biomass change over two years of storage?," Renewable Energy, Elsevier, vol. 224(C).
    15. Baena-Moreno, Francisco M. & Pastor-Pérez, Laura & Zhang, Zhien & Reina, T.R., 2020. "Stepping towards a low-carbon economy. Formic acid from biogas as case of study," Applied Energy, Elsevier, vol. 268(C).
    16. Lim, Dongjun & Lee, Boreum & Lee, Hyunjun & Byun, Manhee & Lim, Hankwon, 2022. "Projected cost analysis of hybrid methanol production from tri-reforming of methane integrated with various water electrolysis systems: Technical and economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    17. Farboud Khatami & Erfan Goharian, 2022. "Beyond Profitable Shifts to Green Energies, towards Energy Sustainability," Sustainability, MDPI, vol. 14(8), pages 1-28, April.
    18. Teixeira, Fátima C. & Teixeira, António P.S. & Rangel, C.M., 2022. "New proton conductive membranes of indazole- and condensed pyrazolebisphosphonic acid-Nafion membranes for PEMFC," Renewable Energy, Elsevier, vol. 196(C), pages 1187-1196.
    19. Olabi, A.G. & Wilberforce, Tabbi & Abdelkareem, Mohammad Ali, 2021. "Fuel cell application in the automotive industry and future perspective," Energy, Elsevier, vol. 214(C).
    20. Jahangiri, Mehdi & Rezaei, Mostafa & Mostafaeipour, Ali & Goojani, Afsaneh Raiesi & Saghaei, Hamed & Hosseini Dehshiri, Seyyed Jalaladdin & Hosseini Dehshiri, Seyyed Shahabaddin, 2022. "Prioritization of solar electricity and hydrogen co-production stations considering PV losses and different types of solar trackers: A TOPSIS approach," Renewable Energy, Elsevier, vol. 186(C), pages 889-903.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:190:y:2017:i:c:p:1221-1233. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.