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Diesel autothermal reforming with hydrogen peroxide for low-oxygen environments

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  • Han, Gwangwoo
  • Lee, Sangho
  • Bae, Joongmyeon

Abstract

To operate fuel cells effectively in low-oxygen environments, such as in submarines and unmanned underwater vehicles, a hydrogen source with high hydrogen storage density is required. In this paper, diesel autothermal reforming (ATR) with hydrogen peroxide as an alternative oxidant is proposed as a hydrogen production method. Diesel fuel has higher hydrogen density than metal hydrides or other hydrocarbons. In addition, hydrogen peroxide can decompose into steam and oxygen, which are required for diesel ATR. Moreover, both diesel fuel and hydrogen peroxide are liquid states, enabling easy storage for submarine applications. Hydrogen peroxide exhibited the same characteristics as steam and oxygen when used as an oxidant in diesel reforming when pre-decomposition method was used. The thermodynamically calculated operating conditions were a steam-to-carbon ratio (SCR) of 3.0, an oxygen-to-carbon ratio (OCR) of 0.5, and temperatures below 700°C to account for safety issues associated with hydrogen peroxide use and exothermic reactions. Catalytic activity and stability tests over Ni–Ru (19.5–0.5wt.%)/Ce0.9Gd0.1O2−x were conducted using various diesel compounds. Furthermore, long-term diesel ATR tests were conducted for 200h using Korean commercial diesel. The degradation rate was 3.67%/100h without the production of ethylene.

Suggested Citation

  • Han, Gwangwoo & Lee, Sangho & Bae, Joongmyeon, 2015. "Diesel autothermal reforming with hydrogen peroxide for low-oxygen environments," Applied Energy, Elsevier, vol. 156(C), pages 99-106.
    • Handle: RePEc:eee:appene:v:156:y:2015:i:c:p:99-106
    DOI: 10.1016/j.apenergy.2015.06.036
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    References listed on IDEAS

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    Cited by:

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    3. Hafizi, A. & Rahimpour, M.R. & Hassanajili, S., 2016. "High purity hydrogen production via sorption enhanced chemical looping reforming: Application of 22Fe2O3/MgAl2O4 and 22Fe2O3/Al2O3 as oxygen carriers and cerium promoted CaO as CO2 sorbent," Applied Energy, Elsevier, vol. 169(C), pages 629-641.
    4. Woo, Seungchul & Kim, Woongil & Lee, Jungkoo & Lee, Kihyung, 2022. "Performance evaluation of the LPG engine applied to catalytic reforming system for producing hydrogen," Applied Energy, Elsevier, vol. 312(C).
    5. Pasel, Joachim & Samsun, Remzi Can & Tschauder, Andreas & Peters, Ralf & Stolten, Detlef, 2017. "Advances in autothermal reformer design," Applied Energy, Elsevier, vol. 198(C), pages 88-98.
    6. Hafizi, A. & Rahimpour, M.R. & Hassanajili, Sh., 2016. "Hydrogen production via chemical looping steam methane reforming process: Effect of cerium and calcium promoters on the performance of Fe2O3/Al2O3 oxygen carrier," Applied Energy, Elsevier, vol. 165(C), pages 685-694.

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