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Electrochemical reduction of carbon dioxide at low overpotential on a polyaniline/Cu2O nanocomposite based electrode

Author

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  • Grace, Andrews Nirmala
  • Choi, Song Yi
  • Vinoba, Mari
  • Bhagiyalakshmi, Margandan
  • Chu, Dae Hyun
  • Yoon, Yeoil
  • Nam, Sung Chan
  • Jeong, Soon Kwan

Abstract

The electrochemical reduction of CO2 using Cu2O nanoparticle decorated polyaniline matrix (PANI/Cu2O) in 0.1M tetrabutylammonium perchlorate (TBAP) and methanol electrolyte was investigated under ambient conditions. The experiment was carried out in a divided H-type two-compartment cell with a Nafion membrane as diaphragm separating the cathodic and anodic compartments. The catalyst was synthesized electrochemically as a thin film by using cyclic voltammetry and constant current mode deposition technique. The as-fabricated electrode was analyzed with various techniques to probe the nature and composition of the nanoparticles deposited onto the polyaniline matrix, which confirmed the presence of well-defined Cu (I) species in the film. The reduction of CO2 was carried out at various polarization potentials; the main products were formic and acetic acid with faradaic efficiencies of 30.4% and 63.0% at a polarization potential of −0.3V vs. SCE (sat. KCl). A possible reduction pathway is through the formation of Had atoms and subsequent transfer to CO2 through the polymer film to form the products. An appreciable efficiency was achieved in the formation of formic acid and acetic acid with the developed catalyst.

Suggested Citation

  • Grace, Andrews Nirmala & Choi, Song Yi & Vinoba, Mari & Bhagiyalakshmi, Margandan & Chu, Dae Hyun & Yoon, Yeoil & Nam, Sung Chan & Jeong, Soon Kwan, 2014. "Electrochemical reduction of carbon dioxide at low overpotential on a polyaniline/Cu2O nanocomposite based electrode," Applied Energy, Elsevier, vol. 120(C), pages 85-94.
    • Handle: RePEc:eee:appene:v:120:y:2014:i:c:p:85-94
    DOI: 10.1016/j.apenergy.2014.01.022
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    References listed on IDEAS

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    1. Wang, Fuhuan & Xie, Heping & Liu, Tao & Wu, Yifan & Chen, Bin, 2020. "Highly dispersed CuFe-nitrogen active sites electrode for synergistic electrochemical CO2 reduction at low overpotential," Applied Energy, Elsevier, vol. 269(C).
    2. Kim, Dongin & Han, Jeehoon, 2020. "Comprehensive analysis of two catalytic processes to produce formic acid from carbon dioxide," Applied Energy, Elsevier, vol. 264(C).
    3. Ganesh, Ibram, 2016. "Electrochemical conversion of carbon dioxide into renewable fuel chemicals – The role of nanomaterials and the commercialization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 1269-1297.
    4. Tufa, Ramato Ashu & Chanda, Debabrata & Ma, Ming & Aili, David & Demissie, Taye Beyene & Vaes, Jan & Li, Qingfeng & Liu, Shanhu & Pant, Deepak, 2020. "Towards highly efficient electrochemical CO2 reduction: Cell designs, membranes and electrocatalysts," Applied Energy, Elsevier, vol. 277(C).
    5. Del Castillo, A. & Alvarez-Guerra, M. & Solla-Gullón, J. & Sáez, A. & Montiel, V. & Irabien, A., 2015. "Electrocatalytic reduction of CO2 to formate using particulate Sn electrodes: Effect of metal loading and particle size," Applied Energy, Elsevier, vol. 157(C), pages 165-173.
    6. Ruiz-López, Estela & Gandara-Loe, Jesús & Baena-Moreno, Francisco & Reina, Tomas Ramirez & Odriozola, José Antonio, 2022. "Electrocatalytic CO2 conversion to C2 products: Catalysts design, market perspectives and techno-economic aspects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    7. Al-Kalbani, Haitham & Xuan, Jin & García, Susana & Wang, Huizhi, 2016. "Comparative energetic assessment of methanol production from CO2: Chemical versus electrochemical process," Applied Energy, Elsevier, vol. 165(C), pages 1-13.

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