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Experimental Investigation on CO 2 Methanation Process for Solar Energy Storage Compared to CO 2 -Based Methanol Synthesis

Author

Listed:
  • Beatrice Castellani

    (Engineering Department, University of Perugia, CIRIAF, Via G. Duranti 67, 06125 Perugia, Italy)

  • Alberto Maria Gambelli

    (Engineering Department, University of Perugia, CIRIAF, Via G. Duranti 67, 06125 Perugia, Italy)

  • Elena Morini

    (Engineering Department, University of Perugia, CIRIAF, Via G. Duranti 67, 06125 Perugia, Italy)

  • Benedetto Nastasi

    (Department of Architectural Engineering & Technology, Environmental & Computational Design Section, TU Delft University of Technology, Julianalaan 134, 2628 BL Delft, The Netherlands)

  • Andrea Presciutti

    (Engineering Department, University of Perugia, CIRIAF, Via G. Duranti 67, 06125 Perugia, Italy)

  • Mirko Filipponi

    (Engineering Department, University of Perugia, CIRIAF, Via G. Duranti 67, 06125 Perugia, Italy)

  • Andrea Nicolini

    (Engineering Department, University of Perugia, CIRIAF, Via G. Duranti 67, 06125 Perugia, Italy)

  • Federico Rossi

    (Engineering Department, University of Perugia, CIRIAF, Via G. Duranti 67, 06125 Perugia, Italy)

Abstract

The utilization of the captured CO 2 as a carbon source for the production of energy storage media offers a technological solution for overcoming crucial issues in current energy systems. Solar energy production generally does not match with energy demand because of its intermittent and non-programmable nature, entailing the adoption of storage technologies. Hydrogen constitutes a chemical storage for renewable electricity if it is produced by water electrolysis and is also the key reactant for CO 2 methanation (Sabatier reaction). The utilization of CO 2 as a feedstock for producing methane contributes to alleviate global climate changes and sequestration related problems. The produced methane is a carbon neutral gas that fits into existing infrastructure and allows issues related to the aforementioned intermittency and non-programmability of solar energy to be overcome. In this paper, an experimental apparatus, composed of an electrolyzer and a tubular fixed bed reactor, is built and used to produce methane via Sabatier reaction. The objective of the experimental campaign is the evaluation of the process performance and a comparison with other CO 2 valorization paths such as methanol production. The investigated pressure range was 2–20 bar, obtaining a methane volume fraction in outlet gaseous mixture of 64.75% at 8 bar and 97.24% at 20 bar, with conversion efficiencies of, respectively, 84.64% and 99.06%. The methanol and methane processes were compared on the basis of an energy parameter defined as the spent energy/stored energy. It is higher for the methanol process (0.45), with respect to the methane production process (0.41–0.43), which has a higher energy storage capability.

Suggested Citation

  • Beatrice Castellani & Alberto Maria Gambelli & Elena Morini & Benedetto Nastasi & Andrea Presciutti & Mirko Filipponi & Andrea Nicolini & Federico Rossi, 2017. "Experimental Investigation on CO 2 Methanation Process for Solar Energy Storage Compared to CO 2 -Based Methanol Synthesis," Energies, MDPI, vol. 10(7), pages 1-13, June.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:7:p:855-:d:102822
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    References listed on IDEAS

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    1. Lo Basso, Gianluigi & Nastasi, Benedetto & Astiaso Garcia, Davide & Cumo, Fabrizio, 2017. "How to handle the Hydrogen enriched Natural Gas blends in combustion efficiency measurement procedure of conventional and condensing boilers," Energy, Elsevier, vol. 123(C), pages 615-636.
    2. Momirlan, Magdalena & Muresan, L. & Sayigh, A.A.M. & Veziroglu, T.N., 1996. "The use of solar energy in hydrogen production," Renewable Energy, Elsevier, vol. 9(1), pages 1258-1261.
    3. Xianzheng Zhou & Chuangxin Guo & Yifei Wang & Wanqi Li, 2017. "Optimal Expansion Co-Planning of Reconfigurable Electricity and Natural Gas Distribution Systems Incorporating Energy Hubs," Energies, MDPI, vol. 10(1), pages 1-22, January.
    4. Ali Elkamel & Gholam Reza Zahedi & Chris Marton & Ali Lohi, 2009. "Optimal Fixed Bed Reactor Network Configuration for the Efficient Recycling of CO 2 into Methanol," Energies, MDPI, vol. 2(2), pages 1-10, April.
    5. Gallo, A.B. & Simões-Moreira, J.R. & Costa, H.K.M. & Santos, M.M. & Moutinho dos Santos, E., 2016. "Energy storage in the energy transition context: A technology review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 65(C), pages 800-822.
    6. Nastasi, Benedetto & Lo Basso, Gianluigi, 2016. "Hydrogen to link heat and electricity in the transition towards future Smart Energy Systems," Energy, Elsevier, vol. 110(C), pages 5-22.
    7. Mohamed Magdeldin & Thomas Kohl & Cataldo De Blasio & Mika Järvinen & Song Won Park & Reinaldo Giudici, 2016. "The BioSCWG Project: Understanding the Trade-Offs in the Process and Thermal Design of Hydrogen and Synthetic Natural Gas Production," Energies, MDPI, vol. 9(10), pages 1-27, October.
    8. Davide Astiaso Garcia & Federica Barbanera & Fabrizio Cumo & Umberto Di Matteo & Benedetto Nastasi, 2016. "Expert Opinion Analysis on Renewable Hydrogen Storage Systems Potential in Europe," Energies, MDPI, vol. 9(11), pages 1-22, November.
    9. Beatrice Castellani & Elena Morini & Mirko Filipponi & Andrea Nicolini & Massimo Palombo & Franco Cotana & Federico Rossi, 2014. "Comparative Analysis of Monitoring Devices for Particulate Content in Exhaust Gases," Sustainability, MDPI, vol. 6(7), pages 1-21, July.
    10. Beatrice Castellani & Andrea Presciutti & Mirko Filipponi & Andrea Nicolini & Federico Rossi, 2015. "Experimental Investigation on the Effect of Phase Change Materials on Compressed Air Expansion in CAES Plants," Sustainability, MDPI, vol. 7(8), pages 1-14, July.
    11. Kyriakopoulos, Grigorios L. & Arabatzis, Garyfallos, 2016. "Electrical energy storage systems in electricity generation: Energy policies, innovative technologies, and regulatory regimes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1044-1067.
    12. Abrar Inayat & Murni M. Ahmad & Suzana Yusup & Mohamed Ibrahim Abdul Mutalib, 2010. "Biomass Steam Gasification with In-Situ CO2 Capture for Enriched Hydrogen Gas Production: A Reaction Kinetics Modelling Approach," Energies, MDPI, vol. 3(8), pages 1-13, August.
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    1. Gábor Pörzse & Zoltán Csedő & Máté Zavarkó, 2021. "Disruption Potential Assessment of the Power-to-Methane Technology," Energies, MDPI, vol. 14(8), pages 1-21, April.
    2. Chen, Huiyao & Chu, Fengming & Yang, Lijun & Ola, Oluwafunmilola & Du, Xiaoze & Yang, Yongping, 2018. "Enhanced photocatalytic reduction of carbon dioxide in optical fiber monolith reactor with transparent glass balls," Applied Energy, Elsevier, vol. 230(C), pages 1403-1413.
    3. Gambelli, Alberto Maria & Rossi, Federico, 2019. "Natural gas hydrates: Comparison between two different applications of thermal stimulation for performing CO2 replacement," Energy, Elsevier, vol. 172(C), pages 423-434.
    4. Majidi Nezhad, M. & Groppi, D. & Marzialetti, P. & Fusilli, L. & Laneve, G. & Cumo, F. & Garcia, D. Astiaso, 2019. "Wind energy potential analysis using Sentinel-1 satellite: A review and a case study on Mediterranean islands," Renewable and Sustainable Energy Reviews, Elsevier, vol. 109(C), pages 499-513.
    5. Uebbing, Jennifer & Rihko-Struckmann, Liisa K. & Sundmacher, Kai, 2019. "Exergetic assessment of CO2 methanation processes for the chemical storage of renewable energies," Applied Energy, Elsevier, vol. 233, pages 271-282.
    6. Moioli, Emanuele & Mutschler, Robin & Züttel, Andreas, 2019. "Renewable energy storage via CO2 and H2 conversion to methane and methanol: Assessment for small scale applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 497-506.
    7. Jixuan Wang & Wensheng Liu & Xin Meng & Xiaozhen Liu & Yanfeng Gao & Zuodong Yu & Yakai Bai & Xin Yang, 2020. "Study on the Coupling Effect of a Solar-Coal Unit Thermodynamic System with Carbon Capture," Energies, MDPI, vol. 13(18), pages 1-14, September.
    8. McDonagh, Shane & O'Shea, Richard & Wall, David M. & Deane, J.P. & Murphy, Jerry D., 2018. "Modelling of a power-to-gas system to predict the levelised cost of energy of an advanced renewable gaseous transport fuel," Applied Energy, Elsevier, vol. 215(C), pages 444-456.

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