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Comparison of Biodiesel Obtained from Virgin Cooking Oil and Waste Cooking Oil Using Supercritical and Catalytic Transesterification

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  • Jeeban Poudel

    (Waste & Biomass Energy Technology Center, Kongju National University, 1223-24 Cheonan-Daero, Seobuk-gu, Cheonan-si, Chungnam 31080, Korea)

  • Sujeeta Karki

    (Department of Environmental Engineering, Kongju National University, 1223-24 Cheonan-Daero, Seobuk-gu, Cheonan-si, Chungnam 31080, Korea)

  • Nawaraj Sanjel

    (Energize Nepal Project, Kathmandu University, 45200 Dhulikhel, Nepal)

  • Malesh Shah

    (Department of Mechanical Engineering, Kathmandu University, 45200 Dhulikhel, Nepal)

  • Sea Cheon Oh

    (Department of Environmental Engineering, Kongju National University, 1223-24 Cheonan-Daero, Seobuk-gu, Cheonan-si, Chungnam 31080, Korea)

Abstract

Comparative analysis of transesterification of virgin cooking oil (VCO) and waste cooking oil (WCO) in catalyzed and supercritical transesterification process using methanol and ethanol as solvents has been conducted in this study. The luminous point of this research was the direct comparison of catalytic and supercritical process using the ester composition obtained from virgin cooking oil and waste cooking oil transesterification. Oil to alcohol molar ratio of 1:6 and reaction condition of 65 °C and 1 bar pressure were considered for the catalytic process, while 260 °C and high pressure (65 and 75 bar for methanol and ethanol, respectively) were accounted for the supercritical process. Distinct layer separation was observed for both processes. Ester, fatty acid and glycerol composition was studied for both the upper and lower layers separately, from which 100% ester composition in the upper layer and a mixture of ester and other composition in the lower layer was obtained for the catalytic process owing to succeeding filtration and washing. However, mixture of ester (>75%) and other composition was obtained in both layers for the supercritical process where purification process was not implemented. The similarity in the result obtained demonstrates the superiority of waste cooking oil compared to virgin cooking oil, taking cost into consideration.

Suggested Citation

  • Jeeban Poudel & Sujeeta Karki & Nawaraj Sanjel & Malesh Shah & Sea Cheon Oh, 2017. "Comparison of Biodiesel Obtained from Virgin Cooking Oil and Waste Cooking Oil Using Supercritical and Catalytic Transesterification," Energies, MDPI, vol. 10(4), pages 1-14, April.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:4:p:546-:d:96038
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    2. Omar Aboelazayem & Mamdouh Gadalla & Basudeb Saha, 2022. "Comprehensive Optimisation of Biodiesel Production Conditions via Supercritical Methanolysis of Waste Cooking Oil," Energies, MDPI, vol. 15(10), pages 1-22, May.
    3. Sergio Nogales-Delgado & José María Encinar & Juan Félix González, 2019. "Safflower Biodiesel: Improvement of its Oxidative Stability by Using BHA and TBHQ," Energies, MDPI, vol. 12(10), pages 1-13, May.
    4. Andrius Tamošiūnas & Dovilė Gimžauskaitė & Mindaugas Aikas & Rolandas Uscila & Marius Praspaliauskas & Justas Eimontas, 2019. "Gasification of Waste Cooking Oil to Syngas by Thermal Arc Plasma," Energies, MDPI, vol. 12(13), pages 1-13, July.
    5. Hoang Chinh Nguyen & Dinh Thi My Huong & Horng-Yi Juan & Chia-Hung Su & Chien-Chung Chien, 2018. "Liquid Lipase-Catalyzed Esterification of Oleic Acid with Methanol for Biodiesel Production in the Presence of Superabsorbent Polymer: Optimization by Using Response Surface Methodology," Energies, MDPI, vol. 11(5), pages 1-12, April.
    6. Jemima Romola, C.V. & Meganaharshini, M. & Rigby, S.P. & Ganesh Moorthy, I. & Shyam Kumar, R. & Karthikumar, Sankar, 2021. "A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).

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