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Effect of antioxidants on oxidation stability of biodiesel derived from vegetable and animal based feedstocks

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  • Rizwanul Fattah, I.M.
  • Masjuki, H.H.
  • Kalam, M.A.
  • Hazrat, M.A.
  • Masum, B.M.
  • Imtenan, S.
  • Ashraful, A.M.

Abstract

The increase of energy demand coped with utilization of fossil resources have engendered serious environmental impact. The progressively stringent worldwide emission legislation and increasing greenhouse gas emission require significant research effort on alternative fuels. Therefore, biodiesels are becoming important increasingly due to its ease in adaptation, environmental benefits and prospect in energy security. Biodiesel derived from vegetable oils, waste cooking oils and animal fats are long chain fatty acid alkyl esters, which contains unsaturated portions that are susceptible to oxidation. Biodiesel oxidation is a complex process having a number of mechanisms involved. Autoxidation radical chain reactions are the primary cause of biodiesel degradation that leads to formation of hydroperoxide, which, after that decompose to form an array of secondary oxidation products like aldehydes, ketones, carboxylic acids, oligomers, gum, sediment etc. Antioxidants are often used to inhibit biodiesel oxidative degradation. The present review attempts to cover the inhibition action of natural and synthetic antioxidants, methods used to analyze biodiesel oxidation and their effect on biodiesel derived from various feedstocks. Phenolic antioxidants are more effective compared to amine antioxidants. Pyrogallol is found to be the most effective antioxidant to improve the oxidation stability in case of almost all biodiesels reviewed.

Suggested Citation

  • Rizwanul Fattah, I.M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Masum, B.M. & Imtenan, S. & Ashraful, A.M., 2014. "Effect of antioxidants on oxidation stability of biodiesel derived from vegetable and animal based feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 356-370.
    • Handle: RePEc:eee:rensus:v:30:y:2014:i:c:p:356-370
    DOI: 10.1016/j.rser.2013.10.026
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    5. Sundus, F. & Fazal, M.A. & Masjuki, H.H., 2017. "Tribology with biodiesel: A study on enhancing biodiesel stability and its fuel properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 399-412.
    6. Wang, Wenchao & Liu, Huili & Li, Fashe & Wang, Hua & Ma, Xin & Li, Jingjing & Zhou, Li & Xiao, Quan, 2021. "Effects of unsaturated fatty acid methyl esters on the oxidation stability of biodiesel determined by gas chromatography-mass spectrometry and information entropy methods," Renewable Energy, Elsevier, vol. 175(C), pages 880-886.
    7. Khounani, Zahra & Hosseinzadeh-Bandbafha, Homa & Nizami, Abdul-Sattar & Sulaiman, Alawi & Goli, Sayed Amir Hossein & Tavassoli-Kafrani, Elham & Ghaffari, Akram & Rajaeifar, Mohammad Ali & Kim, Ki-Hyun, 2020. "Unlocking the potential of walnut husk extract in the production of waste cooking oil-based biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    8. Lanjekar, R.D. & Deshmukh, D., 2016. "A review of the effect of the composition of biodiesel on NOx emission, oxidative stability and cold flow properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1401-1411.
    9. Jemima Romola, C.V. & Meganaharshini, M. & Rigby, S.P. & Ganesh Moorthy, I. & Shyam Kumar, R. & Karthikumar, Sankar, 2021. "A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    10. M. Naveed & A. Arslan & H. M. A. Javed & T. Manzoor & M. M. Quazi & T. Imran & Z. M. Zulfattah & M. Khurram & I. M. R. Fattah, 2021. "State-of-the-Art and Future Perspectives of Environmentally Friendly Machining Using Biodegradable Cutting Fluids," Energies, MDPI, vol. 14(16), pages 1-35, August.
    11. Roveda, Ana Carolina & Comin, Marina & Caires, Anderson Rodrigues Lima & Ferreira, Valdir Souza & Trindade, Magno Aparecido Gonçalves, 2016. "Thermal stability enhancement of biodiesel induced by a synergistic effect between conventional antioxidants and an alternative additive," Energy, Elsevier, vol. 109(C), pages 260-265.
    12. R. S. Gavhane & A. M. Kate & Manzoore Elahi M. Soudagar & V. D. Wakchaure & Sagar Balgude & I. M. Rizwanul Fattah & Nik-Nazri Nik-Ghazali & H. Fayaz & T. M. Yunus Khan & M. A. Mujtaba & Ravinder Kumar, 2021. "Influence of Silica Nano-Additives on Performance and Emission Characteristics of Soybean Biodiesel Fuelled Diesel Engine," Energies, MDPI, vol. 14(5), pages 1-16, March.
    13. S. M. Ashrafur Rahman & I. M. Rizwanul Fattah & Hwai Chyuan Ong & M. F. M. A. Zamri, 2021. "State-of-the-Art of Strategies to Reduce Exhaust Emissions from Diesel Engine Vehicles," Energies, MDPI, vol. 14(6), pages 1-24, March.
    14. Khadijah Nabilah Mohd Zahri & Azham Zulkharnain & Suriana Sabri & Claudio Gomez-Fuentes & Siti Aqlima Ahmad, 2021. "Research Trends of Biodegradation of Cooking Oil in Antarctica from 2001 to 2021: A Bibliometric Analysis Based on the Scopus Database," IJERPH, MDPI, vol. 18(4), pages 1-15, February.
    15. Yaakob, Zahira & Narayanan, Binitha N. & Padikkaparambil, Silija & Unni K., Surya & Akbar P., Mohammed, 2014. "A review on the oxidation stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 136-153.
    16. Mat Yasin, Mohd Hafizil & Mamat, Rizalman & Najafi, G. & Ali, Obed Majeed & Yusop, Ahmad Fitri & Ali, Mohd Hafiz, 2017. "Potentials of palm oil as new feedstock oil for a global alternative fuel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1034-1049.

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