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Synergistic effect of metal deactivator and antioxidant on oxidation stability of metal contaminated Jatropha biodiesel

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  • Sarin, Amit
  • Arora, Rajneesh
  • Singh, N.P.
  • Sarin, Rakesh
  • Malhotra, R.K.
  • Sharma, Meeta
  • Khan, Arif Ali

Abstract

Biodiesel is relatively unstable on storage and European biodiesel standard EN-14214 calls for determining oxidation stability at 110 °C with a minimum induction time of 6 h by the Rancimat method (EN-14112). According to proposed National Mission on biodiesel in India, we have undertaken studies on stability of biodiesel from tree borne non-edible oil seeds Jatropha. Neat Jatropha biodiesel exhibited oxidation stability of 3.95 h. It is found possible to meet the desired EN specification for neat Jatropha biodiesel and metal contaminated Jatropha biodiesel by using antioxidants; it will have a cost implication, as antioxidants are costly chemicals. Research was conducted to increase the oxidation stability of metal contaminated Jatropha biodiesel by doping metal deactivator with antioxidant, with varying concentrations in order to meet the aforementioned standard required for oxidation stability. It was found that usage of antioxidant can be reduced by 30–50%, therefore the cost, even if very small amount of metal deactivator is doped in Jatropha biodiesel to meet EN-14112 specification.

Suggested Citation

  • Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K. & Sharma, Meeta & Khan, Arif Ali, 2010. "Synergistic effect of metal deactivator and antioxidant on oxidation stability of metal contaminated Jatropha biodiesel," Energy, Elsevier, vol. 35(5), pages 2333-2337.
    • Handle: RePEc:eee:energy:v:35:y:2010:i:5:p:2333-2337
    DOI: 10.1016/j.energy.2010.02.032
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    1. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sharma, Meeta & Malhotra, R.K., 2009. "Influence of metal contaminants on oxidation stability of Jatropha biodiesel," Energy, Elsevier, vol. 34(9), pages 1271-1275.
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    1. Sarin, Amit & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K., 2010. "Natural and synthetic antioxidants: Influence on the oxidative stability of biodiesel synthesized from non-edible oil," Energy, Elsevier, vol. 35(12), pages 4645-4648.
    2. Rizwanul Fattah, I.M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Masum, B.M. & Imtenan, S. & Ashraful, A.M., 2014. "Effect of antioxidants on oxidation stability of biodiesel derived from vegetable and animal based feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 356-370.
    3. Sorate, Kamalesh A. & Bhale, Purnanand V., 2015. "Biodiesel properties and automotive system compatibility issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 777-798.
    4. A. K. Azad, 2017. "Biodiesel from Mandarin Seed Oil: A Surprising Source of Alternative Fuel," Energies, MDPI, vol. 10(11), pages 1-22, October.
    5. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Hazrat, M.A., 2015. "Prospect of biofuels as an alternative transport fuel in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 331-351.
    6. Meher, L.C. & Churamani, C.P. & Arif, Md. & Ahmed, Z. & Naik, S.N., 2013. "Jatropha curcas as a renewable source for bio-fuels—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 397-407.
    7. Shahabuddin, M. & Kalam, M.A. & Masjuki, H.H. & Bhuiya, M.M.K. & Mofijur, M., 2012. "An experimental investigation into biodiesel stability by means of oxidation and property determination," Energy, Elsevier, vol. 44(1), pages 616-622.
    8. Roveda, Ana Carolina & Comin, Marina & Caires, Anderson Rodrigues Lima & Ferreira, Valdir Souza & Trindade, Magno Aparecido Gonçalves, 2016. "Thermal stability enhancement of biodiesel induced by a synergistic effect between conventional antioxidants and an alternative additive," Energy, Elsevier, vol. 109(C), pages 260-265.
    9. Fernandes, David M. & Squissato, André L. & Lima, Alexandre F. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2019. "Corrosive character of Moringa oleifera Lam biodiesel exposed to carbon steel under simulated storage conditions," Renewable Energy, Elsevier, vol. 139(C), pages 1263-1271.
    10. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K., 2010. "Blends of biodiesels synthesized from non-edible and edible oils: Influence on the OS (oxidation stability)," Energy, Elsevier, vol. 35(8), pages 3449-3453.
    11. Md Mofijur Rahman & Mohammad Rasul & Nur Md Sayeed Hassan, 2017. "Study on the Tribological Characteristics of Australian Native First Generation and Second Generation Biodiesel Fuel," Energies, MDPI, vol. 10(1), pages 1-16, January.
    12. Chen, Tao & Hu, Run-Ze & Yao, Xiao-Hui & Yang, Qiang & Shuai, Shi-Min & Wang, Jun & Xu, Ming & Zhang, Dong-Yang & Fu, Yu-Jie & Li, Long & Zhao, Wei-Guo, 2020. "Effect of Pyrola extract on the stability of palm biodiesel upon exposure to copper," Renewable Energy, Elsevier, vol. 149(C), pages 1282-1289.
    13. Karavalakis, Georgios & Hilari, Despina & Givalou, Lida & Karonis, Dimitrios & Stournas, Stamos, 2011. "Storage stability and ageing effect of biodiesel blends treated with different antioxidants," Energy, Elsevier, vol. 36(1), pages 369-374.

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