IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v134y2019icp982-988.html
   My bibliography  Save this article

High-performance and low-leakage phosphoric acid fuel cell with synergic composite membrane stacking of micro glass microfiber and nano PTFE

Author

Listed:
  • Lu, Chia-Lien
  • Chang, Cheng-Ping
  • Guo, Yi-Hsuan
  • Yeh, Tsung-Kuang
  • Su, Yu-Chuan
  • Wang, Pen-Cheng
  • Hsueh, Kan-Lin
  • Tseng, Fan-Gang

Abstract

A novel composite membrane consisting glass microfiber (GMF) and polytetrafluoroethylene (PTFE) nanoporous film is applied to phosphoric acid fuel cell (PAFC) for performance enhancement and reducing electrolyte leakage. With 93% high porosity, the GMF can fully load phosphoric acid to maintain high proton conductivity. However, the large opening of the GMF membrane cannot effectively prevent the leakage of phosphoric acid. Therefore, in this study, a 25 μm thick PTFE thin film with pore size 50–400 nm is employed to cover the surface of GMF for preventing phosphoric acid leakage. This composite proton exchange membrane possesses both thermal and chemical stability at the working temperature of phosphoric acid fuel cell, while providing high proton conductivity. The proton conductivity of the composite membrane (0.71 S/cm at 150 °C) is much higher than those of reported phosphoric acid porous membranes (∼10−2 S/cm at 150 °C). The fuel cell using the composite membrane with Pt/C catalyst exhibits excellent performance with peak power density of 614 mW/cm2 and current density of 1761 mA/cm2 at 140 °C under pure H2 and O2 supply, while proton conductivity is maintained 2.6 times higher than that of the pure GMF membrane due to the less phosphoric acid leakage by using PTFE film.

Suggested Citation

  • Lu, Chia-Lien & Chang, Cheng-Ping & Guo, Yi-Hsuan & Yeh, Tsung-Kuang & Su, Yu-Chuan & Wang, Pen-Cheng & Hsueh, Kan-Lin & Tseng, Fan-Gang, 2019. "High-performance and low-leakage phosphoric acid fuel cell with synergic composite membrane stacking of micro glass microfiber and nano PTFE," Renewable Energy, Elsevier, vol. 134(C), pages 982-988.
    • Handle: RePEc:eee:renene:v:134:y:2019:i:c:p:982-988
    DOI: 10.1016/j.renene.2018.11.011
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148118313302
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2018.11.011?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Authayanun, Suthida & Mamlouk, Mohamed & Scott, Keith & Arpornwichanop, Amornchai, 2013. "Comparison of high-temperature and low-temperature polymer electrolyte membrane fuel cell systems with glycerol reforming process for stationary applications," Applied Energy, Elsevier, vol. 109(C), pages 192-201.
    2. Zuliani, Nicola & Taccani, Rodolfo, 2012. "Microcogeneration system based on HTPEM fuel cell fueled with natural gas: Performance analysis," Applied Energy, Elsevier, vol. 97(C), pages 802-808.
    3. Oh, Si-Doek & Kim, Ki-Young & Oh, Shuk-Bum & Kwak, Ho-Young, 2012. "Optimal operation of a 1-kW PEMFC-based CHP system for residential applications," Applied Energy, Elsevier, vol. 95(C), pages 93-101.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Guoxiao Xu & Xinwei Dong & Bin Xue & Jianyou Huang & Junli Wu & Weiwei Cai, 2023. "Recent Approaches to Achieve High Temperature Operation of Nafion Membranes," Energies, MDPI, vol. 16(4), pages 1-21, February.
    2. Kannan, Vishvak & Xue, Hansong & Raman, K. Ashoke & Chen, Jiasheng & Fisher, Adrian & Birgersson, Erik, 2020. "Quantifying operating uncertainties of a PEMFC – Monte Carlo-machine learning based approach," Renewable Energy, Elsevier, vol. 158(C), pages 343-359.
    3. Chang, Cheng-Ping & Wu, Yen-Chih & Chen, Wei-Yen & Pan, Chin & Su, Yu-Chuan & Huang, Yuh-Jeen & Tseng, Fan-Gang, 2020. "A hybrid phosphorus-acid fuel cell system incorporated with oxidative steam reforming of methanol (OSRM) reformer," Renewable Energy, Elsevier, vol. 153(C), pages 530-538.
    4. Guo, Xinru & Zhang, Houcheng & Hu, Ziyang & Hou, Shujin & Ni, Meng & Liao, Tianjun, 2021. "Energetic, exergetic and ecological evaluations of a hybrid system based on a phosphoric acid fuel cell and an organic Rankine cycle," Energy, Elsevier, vol. 217(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Gabriele Loreti & Andrea Luigi Facci & Stefano Ubertini, 2021. "High-Efficiency Combined Heat and Power through a High-Temperature Polymer Electrolyte Membrane Fuel Cell and Gas Turbine Hybrid System," Sustainability, MDPI, vol. 13(22), pages 1-24, November.
    2. Jannelli, Elio & Minutillo, Mariagiovanna & Perna, Alessandra, 2013. "Analyzing microcogeneration systems based on LT-PEMFC and HT-PEMFC by energy balances," Applied Energy, Elsevier, vol. 108(C), pages 82-91.
    3. Li, Yan & Shi, Yan & Mehio, Nada & Tan, Mingsheng & Wang, Zhiyong & Hu, Xiaohong & Chen, George Z. & Dai, Sheng & Jin, Xianbo, 2016. "More sustainable electricity generation in hot and dry fuel cells with a novel hybrid membrane of Nafion/nano-silica/hydroxyl ionic liquid," Applied Energy, Elsevier, vol. 175(C), pages 451-458.
    4. Di Marcoberardino, G. & Chiarabaglio, L. & Manzolini, G. & Campanari, S., 2019. "A Techno-economic comparison of micro-cogeneration systems based on polymer electrolyte membrane fuel cell for residential applications," Applied Energy, Elsevier, vol. 239(C), pages 692-705.
    5. Authayanun, Suthida & Saebea, Dang & Patcharavorachot, Yaneeporn & Arpornwichanop, Amornchai, 2014. "Effect of different fuel options on performance of high-temperature PEMFC (proton exchange membrane fuel cell) systems," Energy, Elsevier, vol. 68(C), pages 989-997.
    6. Chang, Huawei & Wan, Zhongmin & Zheng, Yao & Chen, Xi & Shu, Shuiming & Tu, Zhengkai & Chan, Siew Hwa & Chen, Rui & Wang, Xiaodong, 2017. "Energy- and exergy-based working fluid selection and performance analysis of a high-temperature PEMFC-based micro combined cooling heating and power system," Applied Energy, Elsevier, vol. 204(C), pages 446-458.
    7. Al Moussawi, Houssein & Fardoun, Farouk & Louahlia, Hasna, 2017. "Selection based on differences between cogeneration and trigeneration in various prime mover technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 491-511.
    8. Thomas, Sobi & Vang, Jakob Rabjerg & Araya, Samuel Simon & Kær, Søren Knudsen, 2017. "Experimental study to distinguish the effects of methanol slip and water vapour on a high temperature PEM fuel cell at different operating conditions," Applied Energy, Elsevier, vol. 192(C), pages 422-436.
    9. Víctor Sanz i López & Ramon Costa-Castelló & Carles Batlle, 2022. "Literature Review of Energy Management in Combined Heat and Power Systems Based on High-Temperature Proton Exchange Membrane Fuel Cells for Residential Comfort Applications," Energies, MDPI, vol. 15(17), pages 1-22, September.
    10. Chen, Huicui & Zhang, Ruirui & Xia, Zhifeng & Weng, Qianyao & Zhang, Tong & Pei, Pucheng, 2023. "Experimental investigation on PEM fuel cell flooding mitigation under heavy loading condition," Applied Energy, Elsevier, vol. 349(C).
    11. Pei, Pucheng & Chen, Huicui, 2014. "Main factors affecting the lifetime of Proton Exchange Membrane fuel cells in vehicle applications: A review," Applied Energy, Elsevier, vol. 125(C), pages 60-75.
    12. Jouin, Marine & Bressel, Mathieu & Morando, Simon & Gouriveau, Rafael & Hissel, Daniel & Péra, Marie-Cécile & Zerhouni, Noureddine & Jemei, Samir & Hilairet, Mickael & Ould Bouamama, Belkacem, 2016. "Estimating the end-of-life of PEM fuel cells: Guidelines and metrics," Applied Energy, Elsevier, vol. 177(C), pages 87-97.
    13. Zuo, Jian & Lv, Hong & Zhou, Daming & Xue, Qiong & Jin, Liming & Zhou, Wei & Yang, Daijun & Zhang, Cunman, 2021. "Deep learning based prognostic framework towards proton exchange membrane fuel cell for automotive application," Applied Energy, Elsevier, vol. 281(C).
    14. Singdeo, Debanand & Dey, Tapobrata & Gaikwad, Shrihari & Andreasen, Søren Juhl & Ghosh, Prakash C., 2017. "A new modified-serpentine flow field for application in high temperature polymer electrolyte fuel cell," Applied Energy, Elsevier, vol. 195(C), pages 13-22.
    15. Song, Jeonghun & Oh, Si-Doek & Song, Seung Jin, 2019. "Effect of increased building-integrated renewable energy on building energy portfolio and energy flows in an urban district of Korea," Energy, Elsevier, vol. 189(C).
    16. Esbo, M. Rahimi- & Ranjbar, A.A. & Rahgoshay, S.M., 2020. "Analysis of water management in PEM fuel cell stack at dead-end mode using direct visualization," Renewable Energy, Elsevier, vol. 162(C), pages 212-221.
    17. Ercolino, Giuliana & Ashraf, Muhammad A. & Specchia, Vito & Specchia, Stefania, 2015. "Performance evaluation and comparison of fuel processors integrated with PEM fuel cell based on steam or autothermal reforming and on CO preferential oxidation or selective methanation," Applied Energy, Elsevier, vol. 143(C), pages 138-153.
    18. Jeon, Seung Won & Cha, Dowon & Kim, Hyung Soon & Kim, Yongchan, 2016. "Analysis of the system efficiency of an intermediate temperature proton exchange membrane fuel cell at elevated temperature and relative humidity conditions," Applied Energy, Elsevier, vol. 166(C), pages 165-173.
    19. Chen, Yong-Song & Yang, Chih-Wei & Lee, Jiunn-Yih, 2014. "Implementation and evaluation for anode purging of a fuel cell based on nitrogen concentration," Applied Energy, Elsevier, vol. 113(C), pages 1519-1524.
    20. Jochem, Patrick & Schönfelder, Martin & Fichtner, Wolf, 2015. "An efficient two-stage algorithm for decentralized scheduling of micro-CHP units," European Journal of Operational Research, Elsevier, vol. 245(3), pages 862-874.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:134:y:2019:i:c:p:982-988. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.