IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v252y2019ic71.html
   My bibliography  Save this article

Bioalcohol production from acidogenic products via a two-step process: A case study of butyric acid to butanol

Author

Listed:
  • Cho, Seong-Heon
  • Kim, Juyeon
  • Han, Jeehoon
  • Lee, Daewon
  • Kim, Hyung Ju
  • Kim, Yong Tae
  • Cheng, Xun
  • Xu, Ye
  • Lee, Jechan
  • Kwon, Eilhann E.

Abstract

This article presents the full study (lab-scale experimental study and large-scale techno-economic analysis) results of a two-step catalytic process for the conversion of organic waste–derived butyric acid to butanol. The two-step process consists of the (1) esterification of butyric acid to methyl butyrate and (2) hydrogenolysis of this methyl butyrate to butanol. The first reaction, esterification of butyric acid, was optimized using carbon-based catalysts. The production of butanol from methyl butyrate via hydrogenolysis was investigated using bimetallic Pt–Co catalysts. The hydrogenolysis of methyl butyrate on these catalysts under optimal conditions of 250 °C, 5 MPa H2, and a feed/catalyst weight ratio of 11.2 led to 54.1% selectivity toward 1-butanol. Based on the experimental results, an integrated process simulation model was developed to determine the economic potential of the two-step production of butanol from butyric acid. Using this model, the techno-economic feasibility of the two-step process was analyzed. The minimum selling price (MSP) of 1-butanol produced from butyric acid using this process was US$ 3.388 per gallon of gasoline equivalent (GGE). This MSP is in the range of recent biofuel market prices of US$ 2.03/GGE to US$ 3.83/GGE.

Suggested Citation

  • Cho, Seong-Heon & Kim, Juyeon & Han, Jeehoon & Lee, Daewon & Kim, Hyung Ju & Kim, Yong Tae & Cheng, Xun & Xu, Ye & Lee, Jechan & Kwon, Eilhann E., 2019. "Bioalcohol production from acidogenic products via a two-step process: A case study of butyric acid to butanol," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    • Handle: RePEc:eee:appene:v:252:y:2019:i:c:71
    DOI: 10.1016/j.apenergy.2019.113482
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261919311560
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2019.113482?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Basher, Syed Abul & Masini, Andrea & Aflaki, Sam, 2015. "Time series properties of the renewable energy diffusion process: Implications for energy policy design and assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1680-1692.
    2. Kumar, Manish & Goyal, Yogesh & Sarkar, Abhijit & Gayen, Kalyan, 2012. "Comparative economic assessment of ABE fermentation based on cellulosic and non-cellulosic feedstocks," Applied Energy, Elsevier, vol. 93(C), pages 193-204.
    3. Byun, Jaewon & Han, Jeehoon, 2016. "Process synthesis and analysis for catalytic conversion of lignocellulosic biomass to fuels: Separate conversion of cellulose and hemicellulose using 2-sec-butylphenol (SBP) solvent," Applied Energy, Elsevier, vol. 171(C), pages 483-490.
    4. Cheng, Chieh-Lun & Che, Pei-Yi & Chen, Bor-Yann & Lee, Wen-Jhy & Lin, Chiu-Yue & Chang, Jo-Shu, 2012. "Biobutanol production from agricultural waste by an acclimated mixed bacterial microflora," Applied Energy, Elsevier, vol. 100(C), pages 3-9.
    5. Juan-Rodrigo Bastidas-Oyanedel & Jens Ejbye Schmidt, 2018. "Increasing Profits in Food Waste Biorefinery—A Techno-Economic Analysis," Energies, MDPI, vol. 11(6), pages 1-14, June.
    6. Kumar, Manish & Gayen, Kalyan, 2011. "Developments in biobutanol production: New insights," Applied Energy, Elsevier, vol. 88(6), pages 1999-2012, June.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kim, Juyeon & Han, Jeehoon, 2021. "Bio-based process for the catalytic production of ethyl levulinate from cellulose," Applied Energy, Elsevier, vol. 300(C).
    2. Onwudili, Jude A. & Nouwe Edou, Danielle J., 2022. "Process modelling and economic evaluation of biopropane production from aqueous butyric acid feedstock," Renewable Energy, Elsevier, vol. 184(C), pages 80-90.
    3. Kwon, Oseok & Han, Jeehoon, 2021. "Supply chain management of butyric acid-derived butanol: Stochastic approach," Applied Energy, Elsevier, vol. 297(C).
    4. Kim, Juyeon & Byun, Jaewon & Han, Jeehoon, 2022. "Process integration and economics of gamma-valerolactone using a cellulose-derived ethyl levulinate intermediate and ethanol solvent," Energy, Elsevier, vol. 239(PA).
    5. Wirawan, Ferdian & Cheng, Chieh-Lun & Lo, Yung-Chung & Chen, Chun-Yen & Chang, Jo-Shu & Leu, Shao-Yuan & Lee, Duu-Jong, 2020. "Continuous cellulosic bioethanol co-fermentation by immobilized Zymomonas mobilis and suspended Pichia stipitis in a two-stage process," Applied Energy, Elsevier, vol. 266(C).
    6. Tsai, Tsung-Yu & Lo, Yung-Chung & Dong, Cheng-Di & Nagarajan, Dillirani & Chang, Jo-Shu & Lee, Duu-Jong, 2020. "Biobutanol production from lignocellulosic biomass using immobilized Clostridium acetobutylicum," Applied Energy, Elsevier, vol. 277(C).
    7. Kwon, Oseok & Kim, Juyeon & Han, Jeehoon, 2022. "Organic waste derived biodiesel supply chain network: Deterministic multi-period planning model," Applied Energy, Elsevier, vol. 305(C).
    8. Jung, Sungyup & Kim, Jung-Hun & Jeon, Young Jae & Park, Young-Kwon & Kwon, Eilhann E., 2020. "Synergistic use of carbon dioxide in catalytic pyrolysis of chlorella vulgaris over Ni and Co catalysts," Energy, Elsevier, vol. 211(C).
    9. Han, Jeehoon & Byun, Jaewon & Kwon, Oseok & Lee, Jechan, 2022. "Climate variability and food waste treatment: Analysis for bioenergy sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 160(C).
    10. Kwon, Oseok & Han, Jeehoon, 2021. "Waste-to-bioethanol supply chain network: A deterministic model," Applied Energy, Elsevier, vol. 300(C).
    11. Heeyoung Choi & Jeehoon Han & Jechan Lee, 2021. "Renewable Butanol Production via Catalytic Routes," IJERPH, MDPI, vol. 18(22), pages 1-14, November.
    12. Zhao, Weihua & Yan, Junhao & Gao, Suya & Lee, Timothy H. & Li, Xiangrong, 2022. "The combustion and emission characteristics of a common-rail diesel engine fueled with diesel and higher alcohols blends with a high blend ratio," Energy, Elsevier, vol. 261(PB).
    13. Hakyoung Kim & Saeyeon Kim & Jeongmin Lee & Minyoung Kim & Dohee Kwon & Sungyup Jung, 2023. "Pyrolysis of rice husk using CO2 for enhanced energy production and soil amendment," Energy & Environment, , vol. 34(4), pages 873-885, June.
    14. Park, Hoyoung & Byun, Jaewon & Han, Jeehoon, 2021. "Economically feasible thermochemical process for methanol production from kenaf," Energy, Elsevier, vol. 230(C).
    15. Byun, Jaewon & Han, Jeehoon, 2021. "Economically feasible production of green methane from vegetable and fruit-rich food waste," Energy, Elsevier, vol. 235(C).
    16. Dorota Burchart-Korol & Magdalena Gazda-Grzywacz & Katarzyna Zarębska, 2020. "Research and Prospects for the Development of Alternative Fuels in the Transport Sector in Poland: A Review," Energies, MDPI, vol. 13(11), pages 1-16, June.
    17. Lee, Taewoo & Jung, Sungyup & Kim, Ki-Hyun & Kwon, Eilhann E., 2021. "Catalytic pyrolysis of pine bark over Ni/SiO2 in a CO2 atmosphere," Energy, Elsevier, vol. 220(C).
    18. Jung, Sungyup & Lee, Jechan & Moon, Deok Hyun & Kim, Ki-Hyun & Kwon, Eilhann E., 2021. "Upgrading biogas into syngas through dry reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Pixiang & Chen, Yong Mei & Wang, Yifen & Lee, Yoon Y. & Zong, Wenming & Taylor, Steven & McDonald, Timothy & Wang, Yi, 2019. "Towards comprehensive lignocellulosic biomass utilization for bioenergy production: Efficient biobutanol production from acetic acid pretreated switchgrass with Clostridium saccharoperbutylacetonicum ," Applied Energy, Elsevier, vol. 236(C), pages 551-559.
    2. Kwon, Oseok & Kim, Juyeon & Han, Jeehoon, 2022. "Organic waste derived biodiesel supply chain network: Deterministic multi-period planning model," Applied Energy, Elsevier, vol. 305(C).
    3. Byun, Jaewon & Han, Jeehoon, 2021. "Economically feasible production of green methane from vegetable and fruit-rich food waste," Energy, Elsevier, vol. 235(C).
    4. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part II," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1446-1466.
    5. Kumari, Dolly & Singh, Radhika, 2018. "Pretreatment of lignocellulosic wastes for biofuel production: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 877-891.
    6. Kwon, Oseok & Han, Jeehoon, 2021. "Supply chain management of butyric acid-derived butanol: Stochastic approach," Applied Energy, Elsevier, vol. 297(C).
    7. Huzir, Nurhamieza Md & Aziz, Md Maniruzzaman A. & Ismail, S.B. & Abdullah, Bawadi & Mahmood, Nik Azmi Nik & Umor, N.A. & Syed Muhammad, Syed Anuar Faua’ad, 2018. "Agro-industrial waste to biobutanol production: Eco-friendly biofuels for next generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 476-485.
    8. Cheng, Chieh-Lun & Che, Pei-Yi & Chen, Bor-Yann & Lee, Wen-Jhy & Lin, Chiu-Yue & Chang, Jo-Shu, 2012. "Biobutanol production from agricultural waste by an acclimated mixed bacterial microflora," Applied Energy, Elsevier, vol. 100(C), pages 3-9.
    9. Harish, B.S & Janaki Ramaiah, M. & Babu Uppuluri, Kiran, 2015. "Bioengineering strategies on catalysis for the effective production of renewable and sustainable energy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 533-547.
    10. Srirangan, Kajan & Akawi, Lamees & Moo-Young, Murray & Chou, C. Perry, 2012. "Towards sustainable production of clean energy carriers from biomass resources," Applied Energy, Elsevier, vol. 100(C), pages 172-186.
    11. Zheng, Jin & Tashiro, Yukihiro & Wang, Qunhui & Sakai, Kenji & Sonomoto, Kenji, 2015. "Feasibility of acetone–butanol–ethanol fermentation from eucalyptus hydrolysate without nutrients supplementation," Applied Energy, Elsevier, vol. 140(C), pages 113-119.
    12. Wojciech Dziemianowicz & Katarzyna Kotarska & Anna Świerczyńska, 2022. "Increase Butanol Production from Corn Straw by Mineral Compounds Supplementation," Energies, MDPI, vol. 15(19), pages 1-14, September.
    13. Spyridoula Gerassimidou & Olwenn V. Martin & Gilenny Yamily Feliz Diaz & Chaoying Wan & Dimitrios Komilis & Eleni Iacovidou, 2022. "Systematic Evidence Mapping to Assess the Sustainability of Bioplastics Derived from Food Waste: Do We Know Enough?," Sustainability, MDPI, vol. 15(1), pages 1-27, December.
    14. Atsonios, Konstantinos & Kougioumtzis, Michael-Alexander & D. Panopoulos, Kyriakos & Kakaras, Emmanuel, 2015. "Alternative thermochemical routes for aviation biofuels via alcohols synthesis: Process modeling, techno-economic assessment and comparison," Applied Energy, Elsevier, vol. 138(C), pages 346-366.
    15. Kwon, Oseok & Han, Jeehoon, 2021. "Waste-to-bioethanol supply chain network: A deterministic model," Applied Energy, Elsevier, vol. 300(C).
    16. Muth, D.J. & Bryden, K.M. & Nelson, R.G., 2013. "Sustainable agricultural residue removal for bioenergy: A spatially comprehensive US national assessment," Applied Energy, Elsevier, vol. 102(C), pages 403-417.
    17. Best, Rohan & Burke, Paul J., 2018. "Adoption of solar and wind energy: The roles of carbon pricing and aggregate policy support," Energy Policy, Elsevier, vol. 118(C), pages 404-417.
    18. Cremonez, Paulo André & Feroldi, Michael & de Araújo, Amanda Viana & Negreiros Borges, Maykon & Weiser Meier, Thompson & Feiden, Armin & Gustavo Teleken, Joel, 2015. "Biofuels in Brazilian aviation: Current scenario and prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1063-1072.
    19. Barbera, Elena & Menegon, Silvia & Banzato, Donatella & D'Alpaos, Chiara & Bertucco, Alberto, 2019. "From biogas to biomethane: A process simulation-based techno-economic comparison of different upgrading technologies in the Italian context," Renewable Energy, Elsevier, vol. 135(C), pages 663-673.
    20. Nanda, Sonil & Azargohar, Ramin & Dalai, Ajay K. & Kozinski, Janusz A., 2015. "An assessment on the sustainability of lignocellulosic biomass for biorefining," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 925-941.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:252:y:2019:i:c:71. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.