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Catalytic pyrolysis of pine bark over Ni/SiO2 in a CO2 atmosphere

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  • Lee, Taewoo
  • Jung, Sungyup
  • Kim, Ki-Hyun
  • Kwon, Eilhann E.

Abstract

Syngas was produced by catalytic pyrolysis of pine bark (PB) using CO2 as a raw feedstock as part of an effort to realize the sustainable utilization of biomass carbon. An examination of both liquid and gaseous pyrolysates from pyrolysis revealed that CO2 expedited gas-phase reactions (GPRs) with volatile pyrolysates (VPs) evolved from thermolysis of PB. The GPRs between CO2 and VPs led to the generation of CO at ≥ 600 °C regardless of Boudouard reactions. Two-step pyrolysis was conducted with an additional heating source, and the synergetic use of Ni/SiO2 and CO2 stimulated syngas formation at ≤ 600 °C. Evolution of H2 and CO from catalytic pyrolysis at 700 °C in CO2 atmosphere was greater by factors of 10 and 5, respectively, compared with those from two-step pyrolysis. The conditions for catalytic deactivation between virgin and used catalysts were compared using temperature-programmed oxidation. An apparent reduction of organic species on the surface of used catalysts by CO2 indicates that the addition of CO2 suppressed the formation of coke for deposition. Accordingly, combinational use of CO2 and Ni/SiO2 in catalytic pyrolysis can be recommended as an advanced technical option for production of syngas under favorably retarded conditions for catalyst deactivation.

Suggested Citation

  • Lee, Taewoo & Jung, Sungyup & Kim, Ki-Hyun & Kwon, Eilhann E., 2021. "Catalytic pyrolysis of pine bark over Ni/SiO2 in a CO2 atmosphere," Energy, Elsevier, vol. 220(C).
    • Handle: RePEc:eee:energy:v:220:y:2021:i:c:s0360544221000761
    DOI: 10.1016/j.energy.2021.119827
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    1. Sharma, Abhishek & Pareek, Vishnu & Zhang, Dongke, 2015. "Biomass pyrolysis—A review of modelling, process parameters and catalytic studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1081-1096.
    2. Lahijani, Pooya & Zainal, Zainal Alimuddin & Mohammadi, Maedeh & Mohamed, Abdul Rahman, 2015. "Conversion of the greenhouse gas CO2 to the fuel gas CO via the Boudouard reaction: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 615-632.
    3. Kwon, Eilhann E. & Lee, Taewoo & Ok, Yong Sik & Tsang, Daniel C.W. & Park, Chanhyuk & Lee, Jechan, 2018. "Effects of calcium carbonate on pyrolysis of sewage sludge," Energy, Elsevier, vol. 153(C), pages 726-731.
    4. Debra J. Davidson, 2019. "Exnovating for a renewable energy transition," Nature Energy, Nature, vol. 4(4), pages 254-256, April.
    5. Prins, Mark J. & Ptasinski, Krzysztof J. & Janssen, Frans J.J.G., 2007. "From coal to biomass gasification: Comparison of thermodynamic efficiency," Energy, Elsevier, vol. 32(7), pages 1248-1259.
    6. Akbari, Maryam & Oyedun, Adetoyese Olajire & Kumar, Amit, 2020. "Techno-economic assessment of wet and dry torrefaction of biomass feedstock," Energy, Elsevier, vol. 207(C).
    7. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    8. Hill, Jason & Tajibaeva, Liaila & Polasky, Stephen, 2016. "Climate consequences of low-carbon fuels: The United States Renewable Fuel Standard," Energy Policy, Elsevier, vol. 97(C), pages 351-353.
    9. Cho, Seong-Heon & Kim, Juyeon & Han, Jeehoon & Lee, Daewon & Kim, Hyung Ju & Kim, Yong Tae & Cheng, Xun & Xu, Ye & Lee, Jechan & Kwon, Eilhann E., 2019. "Bioalcohol production from acidogenic products via a two-step process: A case study of butyric acid to butanol," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    10. Demirbas, Ayhan, 2007. "Importance of biodiesel as transportation fuel," Energy Policy, Elsevier, vol. 35(9), pages 4661-4670, September.
    11. Raud, M. & Kikas, T. & Sippula, O. & Shurpali, N.J., 2019. "Potentials and challenges in lignocellulosic biofuel production technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 44-56.
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    1. Rabia Noor Enam & Muhammad Tahir & Huma Hasan Rizvi & Asim Rafique & Syed Muhammad Nabeel Mustafa, 2022. "A Sustainable Way to Generate Energy through Biomass Flash Pyrolysis in South Asia: A Green Energy Technology," International Journal of Energy Economics and Policy, Econjournals, vol. 12(5), pages 274-279, September.
    2. Xu, Donghua & Lin, Junhao & Ma, Rui & Fang, Lin & Sun, Shichang & Luo, Juan, 2022. "Microwave pyrolysis of biomass for low-oxygen bio-oil: Mechanisms of CO2-assisted in-situ deoxygenation," Renewable Energy, Elsevier, vol. 184(C), pages 124-133.
    3. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part II: Catalytic research," Renewable Energy, Elsevier, vol. 189(C), pages 315-338.

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