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Formic-acid-induced depolymerization of oxidized lignin to aromatics

Author

Listed:
  • Alireza Rahimi

    (University of Wisconsin–Madison, 1101 University Avenue)

  • Arne Ulbrich

    (University of Wisconsin–Madison, 1101 University Avenue)

  • Joshua J. Coon

    (University of Wisconsin–Madison, 1101 University Avenue
    University of Wisconsin–Madison)

  • Shannon S. Stahl

    (University of Wisconsin–Madison, 1101 University Avenue)

Abstract

A method for the depolymerization of oxidized lignin under mild conditions in aqueous formic acid is described that results in more than 60 wt% yield of low-molecular-mass aromatics.

Suggested Citation

  • Alireza Rahimi & Arne Ulbrich & Joshua J. Coon & Shannon S. Stahl, 2014. "Formic-acid-induced depolymerization of oxidized lignin to aromatics," Nature, Nature, vol. 515(7526), pages 249-252, November.
    • Handle: RePEc:nat:nature:v:515:y:2014:i:7526:d:10.1038_nature13867
    DOI: 10.1038/nature13867
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    Citations

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    Cited by:

    1. Leiming Hu & Jacob A. Wrubel & Carlos M. Baez-Cotto & Fry Intia & Jae Hyung Park & Arthur Jeremy Kropf & Nancy Kariuki & Zhe Huang & Ahmed Farghaly & Lynda Amichi & Prantik Saha & Ling Tao & David A. , 2023. "A scalable membrane electrode assembly architecture for efficient electrochemical conversion of CO2 to formic acid," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Chio, Chonlong & Sain, Mohini & Qin, Wensheng, 2019. "Lignin utilization: A review of lignin depolymerization from various aspects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 232-249.
    3. Long, Jinxing & Shu, Riyang & Yuan, Zhengqiu & Wang, Tiejun & Xu, Ying & Zhang, Xinghua & Zhang, Qi & Ma, Longlong, 2015. "Efficient valorization of lignin depolymerization products in the present of NixMg1−xO," Applied Energy, Elsevier, vol. 157(C), pages 540-545.
    4. Zhang, Yan & Song, Kuiyan, 2018. "Thermal and chemical characteristics of torrefied biomass derived from a generated volatile atmosphere," Energy, Elsevier, vol. 165(PB), pages 235-245.
    5. Cao, Yang & He, Mingjing & Dutta, Shanta & Luo, Gang & Zhang, Shicheng & Tsang, Daniel C.W., 2021. "Hydrothermal carbonization and liquefaction for sustainable production of hydrochar and aromatics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    6. Li Xu & Meifang Cao & Jiefeng Zhou & Yuxia Pang & Zhixian Li & Dongjie Yang & Shao-Yuan Leu & Hongming Lou & Xuejun Pan & Xueqing Qiu, 2024. "Aqueous amine enables sustainable monosaccharide, monophenol, and pyridine base coproduction in lignocellulosic biorefineries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    7. Haoyu Wang & Yipei Jiang & Evan Park & Xue Han & Yimin Zeng & Chunbao Xu, 2023. "Hydrothermal Liquefaction of Pinewood Sawdust: Influence of Reaction Atmosphere," Sustainability, MDPI, vol. 15(8), pages 1-18, April.
    8. Yuting Zhou & Grace E. Klinger & Eric L. Hegg & Christopher M. Saffron & James E. Jackson, 2022. "Skeletal Ni electrode-catalyzed C-O cleavage of diaryl ethers entails direct elimination via benzyne intermediates," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    9. Md Sumon Reza & Zhanar Baktybaevna Iskakova & Shammya Afroze & Kairat Kuterbekov & Asset Kabyshev & Kenzhebatyr Zh. Bekmyrza & Marzhan M. Kubenova & Muhammad Saifullah Abu Bakar & Abul K. Azad & Hrido, 2023. "Influence of Catalyst on the Yield and Quality of Bio-Oil for the Catalytic Pyrolysis of Biomass: A Comprehensive Review," Energies, MDPI, vol. 16(14), pages 1-39, July.

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