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Adsorbed oxygen dynamics at forced convection interface in the oxygen evolution reaction

Author

Listed:
  • Zhixuan Chen

    (Tongji University)

  • Ze Lin

    (Tongji University)

  • Xiaoyu Zhu

    (Tongji University)

  • Yahui Li

    (Tongji University)

  • Ying Wang

    (Tongji University)

Abstract

The oxygen evolution reaction is a prevalent anodic reaction in electrocatalytic processes. Modulation of adsorbed oxygen (*O) at the electrochemical interface is an effective means to reduce the overpotential of the oxygen evolution reaction. However, the contribution of various *O conversions to the overpotential remains unclear. Herein, the development of a multi-component forced convection electrochemical mass spectrometry constructs *O-labeled electrochemical interfaces with specific coverages to track the *O conversions. The relationships between the Faradic contributions and the specific *O conversion pathways are established by considering the anomalous fractionation of molecule oxygen. Our experiments confirm that *O coupling contributes up to 48% with a specific overpotential on full coverage platinum. Distinguishing the *O conversion contributions with various coverages reveals that balancing the *O formation and conversions, especially *O coupling enables further minimization of the overpotential of the oxygen evolution reaction. Thus, tracking the intermediate conversions has implications for designing high-performance electrocatalytic interfaces.

Suggested Citation

  • Zhixuan Chen & Ze Lin & Xiaoyu Zhu & Yahui Li & Ying Wang, 2025. "Adsorbed oxygen dynamics at forced convection interface in the oxygen evolution reaction," Nature Communications, Nature, vol. 16(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-63181-z
    DOI: 10.1038/s41467-025-63181-z
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