IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-51550-z.html
   My bibliography  Save this article

Stabilization of highly efficient perovskite solar cells with a tailored supramolecular interface

Author

Listed:
  • Chenxu Zhao

    (École Polytechnique Fédérale de Lausanne
    North China Electric Power University
    Fudan University)

  • Zhiwen Zhou

    (École Polytechnique Fédérale de Lausanne
    The Chinese University of Hong Kong)

  • Masaud Almalki

    (École Polytechnique Fédérale de Lausanne
    King Abdulaziz City for Science and Technology (KACST))

  • Michael A. Hope

    (École Polytechnique Fédérale de Lausanne)

  • Jiashang Zhao

    (Delft University of Technology)

  • Thibaut Gallet

    (University of)

  • Anurag Krishna

    (École Polytechnique Fédérale de Lausanne)

  • Aditya Mishra

    (École Polytechnique Fédérale de Lausanne)

  • Felix T. Eickemeyer

    (École Polytechnique Fédérale de Lausanne)

  • Jia Xu

    (North China Electric Power University)

  • Yingguo Yang

    (Fudan University)

  • Shaik M. Zakeeruddin

    (École Polytechnique Fédérale de Lausanne)

  • Alex Redinger

    (University of)

  • Tom J. Savenije

    (Delft University of Technology)

  • Lyndon Emsley

    (École Polytechnique Fédérale de Lausanne)

  • Jianxi Yao

    (North China Electric Power University)

  • Hong Zhang

    (Fudan University)

  • Michael Grätzel

    (École Polytechnique Fédérale de Lausanne)

Abstract

The presence of defects at the interface between the perovskite film and the carrier transport layer poses significant challenges to the performance and stability of perovskite solar cells (PSCs). Addressing this issue, we introduce a dual host-guest (DHG) complexation strategy to modulate both the bulk and interfacial properties of FAPbI3-rich PSCs. Through NMR spectroscopy, a synergistic effect of the dual treatment is observed. Additionally, electro-optical characterizations demonstrate that the DHG strategy not only passivates defects but also enhances carrier extraction and transport. Remarkably, employing the DHG strategy yields PSCs with power conversion efficiencies (PCE) of 25.89% (certified at 25.53%). Furthermore, these DHG-modified PSCs exhibit enhanced operational stability, retaining over 96.6% of their initial PCE of 25.55% after 1050 hours of continuous operation under one-sun illumination, which was the highest initial value in the recently reported articles. This work establishes a promising pathway for stabilizing high-efficiency perovskite photovoltaics through supramolecular engineering, marking a significant advancement in the field.

Suggested Citation

  • Chenxu Zhao & Zhiwen Zhou & Masaud Almalki & Michael A. Hope & Jiashang Zhao & Thibaut Gallet & Anurag Krishna & Aditya Mishra & Felix T. Eickemeyer & Jia Xu & Yingguo Yang & Shaik M. Zakeeruddin & Al, 2024. "Stabilization of highly efficient perovskite solar cells with a tailored supramolecular interface," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51550-z
    DOI: 10.1038/s41467-024-51550-z
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-51550-z
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-51550-z?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Yameng Ren & Dan Zhang & Jiajia Suo & Yiming Cao & Felix T. Eickemeyer & Nick Vlachopoulos & Shaik M. Zakeeruddin & Anders Hagfeldt & Michael Grätzel, 2023. "Hydroxamic acid pre-adsorption raises the efficiency of cosensitized solar cells," Nature, Nature, vol. 613(7942), pages 60-65, January.
    2. Xiaopeng Zheng & Bo Chen & Jun Dai & Yanjun Fang & Yang Bai & Yuze Lin & Haotong Wei & Xiao Cheng Zeng & Jinsong Huang, 2017. "Defect passivation in hybrid perovskite solar cells using quaternary ammonium halide anions and cations," Nature Energy, Nature, vol. 2(7), pages 1-9, July.
    3. Hao Lin & Miao Yang & Xiaoning Ru & Genshun Wang & Shi Yin & Fuguo Peng & Chengjian Hong & Minghao Qu & Junxiong Lu & Liang Fang & Can Han & Paul Procel & Olindo Isabella & Pingqi Gao & Zhenguo Li & X, 2023. "Silicon heterojunction solar cells with up to 26.81% efficiency achieved by electrically optimized nanocrystalline-silicon hole contact layers," Nature Energy, Nature, vol. 8(8), pages 789-799, August.
    4. Mubai Li & Riming Sun & Jingxi Chang & Jingjin Dong & Qiushuang Tian & Hongze Wang & Zihao Li & Pinghui Yang & Haokun Shi & Chao Yang & Zichao Wu & Renzhi Li & Yingguo Yang & Aifei Wang & Shitong Zhan, 2023. "Orientated crystallization of FA-based perovskite via hydrogen-bonded polymer network for efficient and stable solar cells," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Meifang Yang & Tian Tian & Yuxuan Fang & Wen-Guang Li & Gengling Liu & Wenhuai Feng & Mingyi Xu & Wu-Qiang Wu, 2023. "Reducing lead toxicity of perovskite solar cells with a built-in supramolecular complex," Nature Sustainability, Nature, vol. 6(11), pages 1455-1464, November.
    6. Hong Zhang & Felix Thomas Eickemeyer & Zhiwen Zhou & Marko Mladenović & Farzaneh Jahanbakhshi & Lena Merten & Alexander Hinderhofer & Michael A. Hope & Olivier Ouellette & Aditya Mishra & Paramvir Ahl, 2021. "Multimodal host–guest complexation for efficient and stable perovskite photovoltaics," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    7. Stuart Macpherson & Tiarnan A. S. Doherty & Andrew J. Winchester & Sofiia Kosar & Duncan N. Johnstone & Yu-Hsien Chiang & Krzysztof Galkowski & Miguel Anaya & Kyle Frohna & Affan N. Iqbal & Satyawan N, 2022. "Local nanoscale phase impurities are degradation sites in halide perovskites," Nature, Nature, vol. 607(7918), pages 294-300, July.
    8. Xueyu Tian & Samuel D. Stranks & Fengqi You, 2021. "Life cycle assessment of recycling strategies for perovskite photovoltaic modules," Nature Sustainability, Nature, vol. 4(9), pages 821-829, September.
    9. Sibel Y. Leblebici & Linn Leppert & Yanbo Li & Sebastian E. Reyes-Lillo & Sebastian Wickenburg & Ed Wong & Jiye Lee & Mauro Melli & Dominik Ziegler & Daniel K. Angell & D. Frank Ogletree & Paul D. Ash, 2016. "Facet-dependent photovoltaic efficiency variations in single grains of hybrid halide perovskite," Nature Energy, Nature, vol. 1(8), pages 1-7, August.
    10. Renxing Lin & Yurui Wang & Qianwen Lu & Beibei Tang & Jiayi Li & Han Gao & Yuan Gao & Hongjiang Li & Changzeng Ding & Jin Wen & Pu Wu & Chenshuaiyu Liu & Siyang Zhao & Ke Xiao & Zhou Liu & Changqi Ma , 2023. "All-perovskite tandem solar cells with 3D/3D bilayer perovskite heterojunction," Nature, Nature, vol. 620(7976), pages 994-1000, August.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yehui Wen & Tianchi Zhang & Xingtao Wang & Tiantian Liu & Yu Wang & Rui Zhang & Miao Kan & Li Wan & Weihua Ning & Yong Wang & Deren Yang, 2024. "Amorphous (lysine)2PbI2 layer enhanced perovskite photovoltaics," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    2. Shuai You & Felix T. Eickemeyer & Jing Gao & Jun-Ho Yum & Xin Zheng & Dan Ren & Meng Xia & Rui Guo & Yaoguang Rong & Shaik M. Zakeeruddin & Kevin Sivula & Jiang Tang & Zhongjin Shen & Xiong Li & Micha, 2023. "Bifunctional hole-shuttle molecule for improved interfacial energy level alignment and defect passivation in perovskite solar cells," Nature Energy, Nature, vol. 8(5), pages 515-525, May.
    3. Xufeng Liao & Xuefei Jia & Weisheng Li & Xiting Lang & Jianhua Zhang & Xinyu Zhao & Yitong Ji & Qingguo Du & Chun-Hsiao Kuan & Zhiwei Ren & Wenchao Huang & Yang Bai & Kaicheng Zhang & Chuanxiao Xiao &, 2025. "Methylammonium-free, high-efficiency, and stable all-perovskite tandem solar cells enabled by multifunctional rubidium acetate," Nature Communications, Nature, vol. 16(1), pages 1-9, December.
    4. Olkis, Christopher & AL-Hasni, Shihab & Brandani, Stefano & Vasta, Salvatore & Santori, Giulio, 2021. "Solar powered adsorption desalination for Northern and Southern Europe," Energy, Elsevier, vol. 232(C).
    5. Jin Wen & Yicheng Zhao & Pu Wu & Yuxuan Liu & Xuntian Zheng & Renxing Lin & Sushu Wan & Ke Li & Haowen Luo & Yuxi Tian & Ludong Li & Hairen Tan, 2023. "Heterojunction formed via 3D-to-2D perovskite conversion for photostable wide-bandgap perovskite solar cells," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Neill Bartie & Lucero Cobos‐Becerra & Florian Mathies & Janardan Dagar & Eva Unger & Magnus Fröhling & Markus A. Reuter & Rutger Schlatmann, 2023. "Cost versus environment? Combined life cycle, techno‐economic, and circularity assessment of silicon‐ and perovskite‐based photovoltaic systems," Journal of Industrial Ecology, Yale University, vol. 27(3), pages 993-1007, June.
    7. Songhua Cai & Zhipeng Li & Yalan Zhang & Tanghao Liu & Peng Wang & Ming-Gang Ju & Shuping Pang & Shu Ping Lau & Xiao Cheng Zeng & Yuanyuan Zhou, 2024. "Intragrain impurity annihilation for highly efficient and stable perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Wenbo Li & Zhe Li & Shun Zhou & Yanzhuo Gou & Guang Li & Jinghao Li & Cheng Wang & Yan Zeng & Jiakai Yan & Yan Li & Wei Dai & Yaoguang Rong & Weijun Ke & Ti Wang & Hongxing Xu, 2025. "Unveiling the nexus between irradiation and phase reconstruction in tin-lead perovskite solar cells," Nature Communications, Nature, vol. 16(1), pages 1-10, December.
    9. Guus J. W. Aalbers & Tom P. A. Pol & Kunal Datta & Willemijn H. M. Remmerswaal & Martijn M. Wienk & René A. J. Janssen, 2024. "Effect of sub-bandgap defects on radiative and non-radiative open-circuit voltage losses in perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    10. Jianan Wang & Shuaifeng Hu & He Zhu & Sanwan Liu & Zhongyong Zhang & Rui Chen & Junke Wang & Chenyang Shi & Jiaqi Zhang & Wentao Liu & Xia Lei & Bin Liu & Yongyan Pan & Fumeng Ren & Hasan Raza & Qisen, 2025. "Mercapto-functionalized scaffold improves perovskite buried interfaces for tandem photovoltaics," Nature Communications, Nature, vol. 16(1), pages 1-11, December.
    11. Omar M. Saif & Yasmine Elogail & Tarek M. Abdolkader & Ahmed Shaker & Abdelhalim Zekry & Mohamed Abouelatta & Marwa S. Salem & Mostafa Fedawy, 2023. "Comprehensive Review on Thin Film Homojunction Solar Cells: Technologies, Progress and Challenges," Energies, MDPI, vol. 16(11), pages 1-23, May.
    12. Bhati, Naveen & Nazeeruddin, Mohammad Khaja & Maréchal, François, 2024. "Environmental impacts as the key objectives for perovskite solar cells optimization," Energy, Elsevier, vol. 299(C).
    13. Carlo Spampinato & Salvatore Valastro & Gaetano Calogero & Emanuele Smecca & Giovanni Mannino & Valentina Arena & Raffaella Balestrini & Fabiano Sillo & Lucio Ciná & Antonino La Magna & Alessandra Alb, 2025. "Improved radicchio seedling growth under CsPbI3 perovskite rooftop in a laboratory-scale greenhouse for Agrivoltaics application," Nature Communications, Nature, vol. 16(1), pages 1-14, December.
    14. Peng Jin & Yingjie Tang & Dingwei Li & Yan Wang & Peng Ran & Chuanyu Zhou & Ye Yuan & Wenjuan Zhu & Tianyu Liu & Kun Liang & Cuifang Kuang & Xu Liu & Bowen Zhu & Yang (Michael) Yang, 2023. "Realizing nearly-zero dark current and ultrahigh signal-to-noise ratio perovskite X-ray detector and image array by dark-current-shunting strategy," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    15. Jin Zhou & Shiqiang Fu & Shun Zhou & Lishuai Huang & Cheng Wang & Hongling Guan & Dexin Pu & Hongsen Cui & Chen Wang & Ti Wang & Weiwei Meng & Guojia Fang & Weijun Ke, 2024. "Mixed tin-lead perovskites with balanced crystallization and oxidation barrier for all-perovskite tandem solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    16. Rashmi Mehrotra & Dongrak Oh & Ji-Wook Jang, 2021. "Unassisted selective solar hydrogen peroxide production by an oxidised buckypaper-integrated perovskite photocathode," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    17. Shihao Yuan & Daming Zheng & Ting Zhang & Yafei Wang & Feng Qian & Lei Wang & Xiaobo Li & Hualin Zheng & Zecheng Diao & Peng Zhang & Thierry Pauporté & Shibin Li, 2025. "Scalable preparation of perovskite films with homogeneous structure via immobilizing strategy for high-performance solar modules," Nature Communications, Nature, vol. 16(1), pages 1-9, December.
    18. Teixeira, Bernardo & Brito, Miguel Centeno & Mateus, António, 2024. "Raw materials for the Portuguese decarbonization roadmap: The case of solar photovoltaics and wind energy," Resources Policy, Elsevier, vol. 90(C).
    19. Qiong Liang & Kuan Liu & Yu Han & Hao Xia & Zhiwei Ren & Dongyang Li & Tao Zhu & Lei Cheng & Zhenrong Wang & Cheng Zhu & Patrick W. K. Fong & Jiaming Huang & Qi Chen & Yang Yang & Gang Li, 2025. "Highly stable perovskite solar cells with 0.30 voltage deficit enabled by a multi-functional asynchronous cross-linking," Nature Communications, Nature, vol. 16(1), pages 1-10, December.
    20. Aşkın, Asmin & Kılkış, Şiir & Akınoğlu, Bülent Gültekin, 2023. "Recycling photovoltaic modules within a circular economy approach and a snapshot for Türkiye," Renewable Energy, Elsevier, vol. 208(C), pages 583-596.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51550-z. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.