IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-46186-y.html
   My bibliography  Save this article

Molecular anchoring of free solvents for high-voltage and high-safety lithium metal batteries

Author

Listed:
  • Zhuangzhuang Cui

    (University of Science and Technology of China)

  • Zhuangzhuang Jia

    (University of Science and Technology of China)

  • Digen Ruan

    (University of Science and Technology of China)

  • Qingshun Nian

    (University of Science and Technology of China)

  • Jiajia Fan

    (University of Science and Technology of China)

  • Shunqiang Chen

    (University of Science and Technology of China)

  • Zixu He

    (University of Science and Technology of China)

  • Dazhuang Wang

    (University of Science and Technology of China)

  • Jinyu Jiang

    (University of Science and Technology of China)

  • Jun Ma

    (University of Science and Technology of China)

  • Xing Ou

    (Central South University)

  • Shuhong Jiao

    (University of Science and Technology of China)

  • Qingsong Wang

    (University of Science and Technology of China)

  • Xiaodi Ren

    (University of Science and Technology of China)

Abstract

Constraining the electrochemical reactivity of free solvent molecules is pivotal for developing high-voltage lithium metal batteries, especially for ether solvents with high Li metal compatibility but low oxidation stability ( 4.4 V) and extensive exothermic reactions between Li metal and reactive anions. Herein, we propose a molecular anchoring approach to restrict the interfacial reactivity of free ether solvents in diluted electrolytes. The hydrogen-bonding interactions from the anchoring solvent effectively suppress excessive ether side reactions and enhances the stability of nickel rich cathodes at 4.7 V, despite the extremely low Li+/ether molar ratio (1:9) and the absence of typical anion-derived interphase. Furthermore, the exothermic processes under thermal abuse conditions are mitigated due to the reduced reactivity of anions, which effectively postpones the battery thermal runaway.

Suggested Citation

  • Zhuangzhuang Cui & Zhuangzhuang Jia & Digen Ruan & Qingshun Nian & Jiajia Fan & Shunqiang Chen & Zixu He & Dazhuang Wang & Jinyu Jiang & Jun Ma & Xing Ou & Shuhong Jiao & Qingsong Wang & Xiaodi Ren, 2024. "Molecular anchoring of free solvents for high-voltage and high-safety lithium metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46186-y
    DOI: 10.1038/s41467-024-46186-y
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-46186-y
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-46186-y?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Junxian Hou & Languang Lu & Li Wang & Atsushi Ohma & Dongsheng Ren & Xuning Feng & Yan Li & Yalun Li & Issei Ootani & Xuebing Han & Weining Ren & Xiangming He & Yoshiaki Nitta & Minggao Ouyang, 2020. "Thermal runaway of Lithium-ion batteries employing LiN(SO2F)2-based concentrated electrolytes," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    2. Yuki Yamada & Jianhui Wang & Seongjae Ko & Eriko Watanabe & Atsuo Yamada, 2019. "Advances and issues in developing salt-concentrated battery electrolytes," Nature Energy, Nature, vol. 4(4), pages 269-280, April.
    3. Chaojiang Niu & Dianying Liu & Joshua A. Lochala & Cassidy S. Anderson & Xia Cao & Mark E. Gross & Wu Xu & Ji-Guang Zhang & M. Stanley Whittingham & Jie Xiao & Jun Liu, 2021. "Balancing interfacial reactions to achieve long cycle life in high-energy lithium metal batteries," Nature Energy, Nature, vol. 6(7), pages 723-732, July.
    4. Shuhong Jiao & Xiaodi Ren & Ruiguo Cao & Mark H. Engelhard & Yuzi Liu & Dehong Hu & Donghai Mei & Jianming Zheng & Wengao Zhao & Qiuyan Li & Ning Liu & Brian D. Adams & Cheng Ma & Jun Liu & Ji-Guang Z, 2018. "Stable cycling of high-voltage lithium metal batteries in ether electrolytes," Nature Energy, Nature, vol. 3(9), pages 739-746, September.
    5. Jack Fawdon & Johannes Ihli & Fabio La Mantia & Mauro Pasta, 2021. "Characterising lithium-ion electrolytes via operando Raman microspectroscopy," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    6. Thomas Meier & Florian Trybel & Saiana Khandarkhaeva & Dominique Laniel & Takayuki Ishii & Alena Aslandukova & Natalia Dubrovinskaia & Leonid Dubrovinsky, 2022. "Structural independence of hydrogen-bond symmetrisation dynamics at extreme pressure conditions," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    7. John Holoubek & Haodong Liu & Zhaohui Wu & Yijie Yin & Xing Xing & Guorui Cai & Sicen Yu & Hongyao Zhou & Tod A. Pascal & Zheng Chen & Ping Liu, 2021. "Tailoring electrolyte solvation for Li metal batteries cycled at ultra-low temperature," Nature Energy, Nature, vol. 6(3), pages 303-313, March.
    8. Yawei Chen & Menghao Li & Yue Liu & Yulin Jie & Wanxia Li & Fanyang Huang & Xinpeng Li & Zixu He & Xiaodi Ren & Yunhua Chen & Xianhui Meng & Tao Cheng & Meng Gu & Shuhong Jiao & Ruiguo Cao, 2023. "Origin of dendrite-free lithium deposition in concentrated electrolytes," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    9. Chu, Zhengyu & Feng, Xuning & Lu, Languang & Li, Jianqiu & Han, Xuebing & Ouyang, Minggao, 2017. "Non-destructive fast charging algorithm of lithium-ion batteries based on the control-oriented electrochemical model," Applied Energy, Elsevier, vol. 204(C), pages 1240-1250.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yan Zhao & Tianhong Zhou & Mounir Mensi & Jang Wook Choi & Ali Coskun, 2023. "Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Mengyao Tang & Shuai Dong & Jiawei Wang & Liwei Cheng & Qiaonan Zhu & Yanmei Li & Xiuyi Yang & Lin Guo & Hua Wang, 2023. "Low-temperature anode-free potassium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Guangzhao Zhang & Jian Chang & Liguang Wang & Jiawei Li & Chaoyang Wang & Ruo Wang & Guoli Shi & Kai Yu & Wei Huang & Honghe Zheng & Tianpin Wu & Yonghong Deng & Jun Lu, 2023. "A monofluoride ether-based electrolyte solution for fast-charging and low-temperature non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    4. Zhi Chang & Huijun Yang & Anqiang Pan & Ping He & Haoshen Zhou, 2022. "An improved 9 micron thick separator for a 350 Wh/kg lithium metal rechargeable pouch cell," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    5. Weili Zhang & Yang Lu & Lei Wan & Pan Zhou & Yingchun Xia & Shuaishuai Yan & Xiaoxia Chen & Hangyu Zhou & Hao Dong & Kai Liu, 2022. "Engineering a passivating electric double layer for high performance lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    6. Xiaozhe Zhang & Pan Xu & Jianing Duan & Xiaodong Lin & Juanjuan Sun & Wenjie Shi & Hewei Xu & Wenjie Dou & Qingyi Zheng & Ruming Yuan & Jiande Wang & Yan Zhang & Shanshan Yu & Zehan Chen & Mingsen Zhe, 2024. "A dicarbonate solvent electrolyte for high performance 5 V-Class Lithium-based batteries," Nature Communications, Nature, vol. 15(1), pages 1-18, December.
    7. Yan Zhao & Tianhong Zhou & Timur Ashirov & Mario El Kazzi & Claudia Cancellieri & Lars P. H. Jeurgens & Jang Wook Choi & Ali Coskun, 2022. "Fluorinated ether electrolyte with controlled solvation structure for high voltage lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    8. Junyeob Moon & Dong Ok Kim & Lieven Bekaert & Munsoo Song & Jinkyu Chung & Danwon Lee & Annick Hubin & Jongwoo Lim, 2022. "Non-fluorinated non-solvating cosolvent enabling superior performance of lithium metal negative electrode battery," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    9. Hyeokjin Kwon & Hongsin Kim & Jaemin Hwang & Wonsik Oh & Youngil Roh & Dongseok Shin & Hee-Tak Kim, 2024. "Borate–pyran lean electrolyte-based Li-metal batteries with minimal Li corrosion," Nature Energy, Nature, vol. 9(1), pages 57-69, January.
    10. Junbo Zhang & Haikuo Zhang & Suting Weng & Ruhong Li & Di Lu & Tao Deng & Shuoqing Zhang & Ling Lv & Jiacheng Qi & Xuezhang Xiao & Liwu Fan & Shujiang Geng & Fuhui Wang & Lixin Chen & Malachi Noked & , 2023. "Multifunctional solvent molecule design enables high-voltage Li-ion batteries," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    11. Muhammad Mominur Rahman & Sha Tan & Yang Yang & Hui Zhong & Sanjit Ghose & Iradwikanari Waluyo & Adrian Hunt & Lu Ma & Xiao-Qing Yang & Enyuan Hu, 2023. "An inorganic-rich but LiF-free interphase for fast charging and long cycle life lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    12. Zheng Li & Harsha Rao & Rasha Atwi & Bhuvaneswari M. Sivakumar & Bharat Gwalani & Scott Gray & Kee Sung Han & Thomas A. Everett & Tanvi A. Ajantiwalay & Vijayakumar Murugesan & Nav Nidhi Rajput & Vila, 2023. "Non-polar ether-based electrolyte solutions for stable high-voltage non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    13. Shuoqing Zhang & Ruhong Li & Nan Hu & Tao Deng & Suting Weng & Zunchun Wu & Di Lu & Haikuo Zhang & Junbo Zhang & Xuefeng Wang & Lixin Chen & Liwu Fan & Xiulin Fan, 2022. "Tackling realistic Li+ flux for high-energy lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    14. Yuxiang Xie & Yixin Huang & Yinggan Zhang & Tairui Wu & Shishi Liu & Miaolan Sun & Bruce Lee & Zhen Lin & Hui Chen & Peng Dai & Zheng Huang & Jian Yang & Chenguang Shi & Deyin Wu & Ling Huang & Yingji, 2023. "Surface modification using heptafluorobutyric acid to produce highly stable Li metal anodes," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    15. Angeles Cabañero, Maria & Altmann, Johannes & Gold, Lukas & Boaretto, Nicola & Müller, Jana & Hein, Simon & Zausch, Jochen & Kallo, Josef & Latz, Arnulf, 2019. "Investigation of the temperature dependence of lithium plating onset conditions in commercial Li-ion batteries," Energy, Elsevier, vol. 171(C), pages 1217-1228.
    16. Wang, Bin & Wang, Shifeng & Tang, Yuanyuan & Tsang, Chi-Wing & Dai, Jinchuan & Leung, Michael K.H. & Lu, Xiao-Ying, 2019. "Micro/nanostructured MnCo2O4.5 anodes with high reversible capacity and excellent rate capability for next generation lithium-ion batteries," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    17. Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    18. Hyeokjin Kwon & Hyun-Ji Choi & Jung-kyu Jang & Jinhong Lee & Jinkwan Jung & Wonjun Lee & Youngil Roh & Jaewon Baek & Dong Jae Shin & Ju-Hyuk Lee & Nam-Soon Choi & Ying Shirley Meng & Hee-Tak Kim, 2023. "Weakly coordinated Li ion in single-ion-conductor-based composite enabling low electrolyte content Li-metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    19. Cheng Chi & Gongze Liu & Meng An & Yufeng Zhang & Dongxing Song & Xin Qi & Chunyu Zhao & Zequn Wang & Yanzheng Du & Zizhen Lin & Yang Lu & He Huang & Yang Li & Chongjia Lin & Weigang Ma & Baoling Huan, 2023. "Reversible bipolar thermopower of ionic thermoelectric polymer composite for cyclic energy generation," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    20. Jiaqi Cao & Yuansheng Shi & Aosong Gao & Guangyuan Du & Muhtar Dilxat & Yongfei Zhang & Mohang Cai & Guoyu Qian & Xueyi Lu & Fangyan Xie & Yang Sun & Xia Lu, 2024. "Hierarchical Li electrochemistry using alloy-type anode for high-energy-density Li metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46186-y. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.