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Stable cycling of high-voltage lithium metal batteries in ether electrolytes

Author

Listed:
  • Shuhong Jiao

    (Energy and Environment Directorate, Pacific Northwest National Laboratory
    University of Science and Technology of China)

  • Xiaodi Ren

    (Energy and Environment Directorate, Pacific Northwest National Laboratory)

  • Ruiguo Cao

    (Energy and Environment Directorate, Pacific Northwest National Laboratory
    University of Science and Technology of China)

  • Mark H. Engelhard

    (Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory)

  • Yuzi Liu

    (Centre for Nanoscale Materials, Argonne National Laboratory)

  • Dehong Hu

    (Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory)

  • Donghai Mei

    (Physical and Computational Directorate, Pacific Northwest National Laboratory)

  • Jianming Zheng

    (Energy and Environment Directorate, Pacific Northwest National Laboratory)

  • Wengao Zhao

    (Energy and Environment Directorate, Pacific Northwest National Laboratory
    Xiamen University)

  • Qiuyan Li

    (Energy and Environment Directorate, Pacific Northwest National Laboratory)

  • Ning Liu

    (Physical and Computational Directorate, Pacific Northwest National Laboratory
    Beijing University of Chemical Technology)

  • Brian D. Adams

    (Energy and Environment Directorate, Pacific Northwest National Laboratory)

  • Cheng Ma

    (University of Science and Technology of China)

  • Jun Liu

    (Energy and Environment Directorate, Pacific Northwest National Laboratory)

  • Ji-Guang Zhang

    (Energy and Environment Directorate, Pacific Northwest National Laboratory)

  • Wu Xu

    (Energy and Environment Directorate, Pacific Northwest National Laboratory)

Abstract

The key to enabling long-term cycling stability of high-voltage lithium (Li) metal batteries is the development of functional electrolytes that are stable against both Li anodes and high-voltage (above 4 V versus Li/Li+) cathodes. Due to their limited oxidative stability ( 90% over 300 cycles and ~80% over 500 cycles with a charge cut-off voltage of 4.3 V. This study offers a promising approach to enable ether-based electrolytes for high-voltage Li metal battery applications.

Suggested Citation

  • Shuhong Jiao & Xiaodi Ren & Ruiguo Cao & Mark H. Engelhard & Yuzi Liu & Dehong Hu & Donghai Mei & Jianming Zheng & Wengao Zhao & Qiuyan Li & Ning Liu & Brian D. Adams & Cheng Ma & Jun Liu & Ji-Guang Z, 2018. "Stable cycling of high-voltage lithium metal batteries in ether electrolytes," Nature Energy, Nature, vol. 3(9), pages 739-746, September.
    • Handle: RePEc:nat:natene:v:3:y:2018:i:9:d:10.1038_s41560-018-0199-8
    DOI: 10.1038/s41560-018-0199-8
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    Cited by:

    1. Zhuo Li & Rui Yu & Suting Weng & Qinghua Zhang & Xuefeng Wang & Xin Guo, 2023. "Tailoring polymer electrolyte ionic conductivity for production of low- temperature operating quasi-all-solid-state lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Lingfei Tang & Bowen Chen & Zhonghan Zhang & Changqi Ma & Junchao Chen & Yage Huang & Fengrui Zhang & Qingyu Dong & Guoyong Xue & Daiqian Chen & Chenji Hu & Shuzhou Li & Zheng Liu & Yanbin Shen & Qi C, 2023. "Polyfluorinated crosslinker-based solid polymer electrolytes for long-cycling 4.5 V lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Qidi Wang & Chenglong Zhao & Jianlin Wang & Zhenpeng Yao & Shuwei Wang & Sai Govind Hari Kumar & Swapna Ganapathy & Stephen Eustace & Xuedong Bai & Baohua Li & Marnix Wagemaker, 2023. "High entropy liquid electrolytes for lithium batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Zhi Chang & Huijun Yang & Anqiang Pan & Ping He & Haoshen Zhou, 2022. "An improved 9 micron thick separator for a 350 Wh/kg lithium metal rechargeable pouch cell," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    5. Yu Gu & En-Ming You & Jian-De Lin & Jun-Hao Wang & Si-Heng Luo & Ru-Yu Zhou & Chen-Jie Zhang & Jian-Lin Yao & Hui-Yang Li & Gen Li & Wei-Wei Wang & Yu Qiao & Jia-Wei Yan & De-Yin Wu & Guo-Kun Liu & Li, 2023. "Resolving nanostructure and chemistry of solid-electrolyte interphase on lithium anodes by depth-sensitive plasmon-enhanced Raman spectroscopy," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Zheng Li & Harsha Rao & Rasha Atwi & Bhuvaneswari M. Sivakumar & Bharat Gwalani & Scott Gray & Kee Sung Han & Thomas A. Everett & Tanvi A. Ajantiwalay & Vijayakumar Murugesan & Nav Nidhi Rajput & Vila, 2023. "Non-polar ether-based electrolyte solutions for stable high-voltage non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    7. Danfeng Zhang & Ming Liu & Jiabin Ma & Ke Yang & Zhen Chen & Kaikai Li & Chen Zhang & Yinping Wei & Min Zhou & Peng Wang & Yuanbiao He & Wei Lv & Quan-Hong Yang & Feiyu Kang & Yan-Bing He, 2022. "Lithium hexamethyldisilazide as electrolyte additive for efficient cycling of high-voltage non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    8. Shuoqing Zhang & Ruhong Li & Nan Hu & Tao Deng & Suting Weng & Zunchun Wu & Di Lu & Haikuo Zhang & Junbo Zhang & Xuefeng Wang & Lixin Chen & Liwu Fan & Xiulin Fan, 2022. "Tackling realistic Li+ flux for high-energy lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    9. Muhammad Mominur Rahman & Sha Tan & Yang Yang & Hui Zhong & Sanjit Ghose & Iradwikanari Waluyo & Adrian Hunt & Lu Ma & Xiao-Qing Yang & Enyuan Hu, 2023. "An inorganic-rich but LiF-free interphase for fast charging and long cycle life lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Fei Pei & Lin Wu & Yi Zhang & Yaqi Liao & Qi Kang & Yan Han & Huangwei Zhang & Yue Shen & Henghui Xu & Zhen Li & Yunhui Huang, 2024. "Interfacial self-healing polymer electrolytes for long-cycle solid-state lithium-sulfur batteries," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    11. Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    12. Zhuangzhuang Cui & Zhuangzhuang Jia & Digen Ruan & Qingshun Nian & Jiajia Fan & Shunqiang Chen & Zixu He & Dazhuang Wang & Jinyu Jiang & Jun Ma & Xing Ou & Shuhong Jiao & Qingsong Wang & Xiaodi Ren, 2024. "Molecular anchoring of free solvents for high-voltage and high-safety lithium metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    13. Hyeokjin Kwon & Hongsin Kim & Jaemin Hwang & Wonsik Oh & Youngil Roh & Dongseok Shin & Hee-Tak Kim, 2024. "Borate–pyran lean electrolyte-based Li-metal batteries with minimal Li corrosion," Nature Energy, Nature, vol. 9(1), pages 57-69, January.
    14. Junbo Zhang & Haikuo Zhang & Suting Weng & Ruhong Li & Di Lu & Tao Deng & Shuoqing Zhang & Ling Lv & Jiacheng Qi & Xuezhang Xiao & Liwu Fan & Shujiang Geng & Fuhui Wang & Lixin Chen & Malachi Noked & , 2023. "Multifunctional solvent molecule design enables high-voltage Li-ion batteries," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    15. Xiaozhe Zhang & Pan Xu & Jianing Duan & Xiaodong Lin & Juanjuan Sun & Wenjie Shi & Hewei Xu & Wenjie Dou & Qingyi Zheng & Ruming Yuan & Jiande Wang & Yan Zhang & Shanshan Yu & Zehan Chen & Mingsen Zhe, 2024. "A dicarbonate solvent electrolyte for high performance 5 V-Class Lithium-based batteries," Nature Communications, Nature, vol. 15(1), pages 1-18, December.
    16. Yan Zhao & Tianhong Zhou & Mounir Mensi & Jang Wook Choi & Ali Coskun, 2023. "Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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