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Intercalation-driven ferroelectric-to-ferroelastic conversion in a layered hybrid perovskite crystal

Author

Listed:
  • Zhenyue Wu

    (National University of Singapore)

  • Shunning Li

    (Peking University Shenzhen Graduate School)

  • Yasmin Mohamed Yousry

    (A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis)

  • Walter P. D. Wong

    (National University of Singapore)

  • Xinyun Wang

    (National University of Singapore)

  • Teng Ma

    (National University of Singapore)

  • Zhefeng Chen

    (Peking University Shenzhen Graduate School)

  • Yan Shao

    (National University of Singapore)

  • Weng Heng Liew

    (A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis)

  • Kui Yao

    (A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis)

  • Feng Pan

    (Peking University Shenzhen Graduate School)

  • Kian Ping Loh

    (National University of Singapore)

Abstract

Two-dimensional (2D) organic-inorganic hybrid perovskites have attracted intense interests due to their quantum well structure and tunable excitonic properties. As an alternative to the well-studied divalent metal hybrid perovskite based on Pb2+, Sn2+ and Cu2+, the trivalent metal-based (eg. Sb3+ with ns2 outer-shell electronic configuration) hybrid perovskite with the A3M2X9 formula (A = monovalent cations, M = trivalent metal, X = halide) offer intriguing possibilities for engineering ferroic properties. Here, we synthesized 2D ferroelectric hybrid perovskite (TMA)3Sb2Cl9 with measurable in-plane and out-of-plane polarization. Interestingly, (TMA)3Sb2Cl9 can be intercalated with FeCl4 ions to form a ferroelastic and piezoelectric single crystal, (TMA)4-Fe(iii)Cl4-Sb2Cl9. Density functional theory calculations were carried out to investigate the unusual mechanism of ferroelectric-ferroelastic crossover in these crystals.

Suggested Citation

  • Zhenyue Wu & Shunning Li & Yasmin Mohamed Yousry & Walter P. D. Wong & Xinyun Wang & Teng Ma & Zhefeng Chen & Yan Shao & Weng Heng Liew & Kui Yao & Feng Pan & Kian Ping Loh, 2022. "Intercalation-driven ferroelectric-to-ferroelastic conversion in a layered hybrid perovskite crystal," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30822-6
    DOI: 10.1038/s41467-022-30822-6
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    References listed on IDEAS

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    1. Xitao Liu & Zhenyue Wu & Tong Guan & Haidong Jiang & Peiqing Long & Xiaoqi Li & Chengmin Ji & Shuang Chen & Zhihua Sun & Junhua Luo, 2021. "Giant room temperature electrocaloric effect in a layered hybrid perovskite ferroelectric: [(CH3)2CHCH2NH3]2PbCl4," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    2. Wei-Qiang Liao & Yi Zhang & Chun-Li Hu & Jiang-Gao Mao & Heng-Yun Ye & Peng-Fei Li & Songping D. Huang & Ren-Gen Xiong, 2015. "A lead-halide perovskite molecular ferroelectric semiconductor," Nature Communications, Nature, vol. 6(1), pages 1-7, November.
    3. Michael L. Aubrey & Abraham Saldivar Valdes & Marina R. Filip & Bridget A. Connor & Kurt P. Lindquist & Jeffrey B. Neaton & Hemamala I. Karunadasa, 2021. "Directed assembly of layered perovskite heterostructures as single crystals," Nature, Nature, vol. 597(7876), pages 355-359, September.
    4. Jinsong Zhang & Ankun Yang & Xi Wu & Jorik Groep & Peizhe Tang & Shaorui Li & Bofei Liu & Feifei Shi & Jiayu Wan & Qitong Li & Yongming Sun & Zhiyi Lu & Xueli Zheng & Guangmin Zhou & Chun-Lan Wu & Sho, 2018. "Reversible and selective ion intercalation through the top surface of few-layer MoS2," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    5. W. Eerenstein & N. D. Mathur & J. F. Scott, 2006. "Multiferroic and magnetoelectric materials," Nature, Nature, vol. 442(7104), pages 759-765, August.
    6. Takeshi Yajima & Masaki Koshiko & Yaoqing Zhang & Tamio Oguchi & Wen Yu & Daichi Kato & Yoji Kobayashi & Yuki Orikasa & Takafumi Yamamoto & Yoshiharu Uchimoto & Mark A. Green & Hiroshi Kageyama, 2016. "Selective and low temperature transition metal intercalation in layered tellurides," Nature Communications, Nature, vol. 7(1), pages 1-8, December.
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    1. Sasa Wang & Asif Abdullah Khan & Sam Teale & Jian Xu & Darshan H. Parmar & Ruyan Zhao & Luke Grater & Peter Serles & Yu Zou & Tobin Filleter & Dwight S. Seferos & Dayan Ban & Edward H. Sargent, 2023. "Large piezoelectric response in a Jahn-Teller distorted molecular metal halide," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    2. Weng Fu Io & Sin -Yi Pang & Lok Wing Wong & Yuqian Zhao & Ran Ding & Jianfeng Mao & Yifei Zhao & Feng Guo & Shuoguo Yuan & Jiong Zhao & Jiabao Yi & Jianhua Hao, 2023. "Direct observation of intrinsic room-temperature ferroelectricity in 2D layered CuCrP2S6," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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