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Evaluating the Properties of a Coating Material with Polycaprolactone-Degradable Fluorinated Silicon-Containing Waterborne Polyurethane

Author

Listed:
  • Yao-Tang Hsu

    (Department of Management Information Systems, National Chengchi University, Taipei 11605, Taiwan)

  • Wen-Hsin Wang

    (Department of Management Information Systems, National Chengchi University, Taipei 11605, Taiwan)

  • Wei-Hsi Hung

    (Department of Management Information Systems, National Chengchi University, Taipei 11605, Taiwan)

Abstract

This study successfully synthesized fluorinated silicon-containing waterborne polyurethanes (FSWPUs) by using polycaprolactone (PCL) diol, 2,2,3,3-Tetrafluoro-1,4-butanediol, and [3-(2-Aminoethylamino)propyl] trimethoxysilane (AEAPTES ). The FSWPU’s particle size was examined using dynamic light scattering. After the FSWPUs were processed into a dry film, their molecular weight and basic properties were analyzed using gel permeation chromatography (GPC), Fourier-transform infrared spectroscopy (FTIR), and energy-dispersive X-ray spectroscopy (EDS). Additionally, the thermal stability of the FSWPUs was inspected by thermogravimetric analysis and dynamic mechanical analysis. The tensile strength and elongation at the break of the FSWPUs before and after hydrolysis were also analyzed, using a tensile testing machine. Subsequently, FSWPU emulsions were cast between the tiles, and hydrophilicity, hydrophobicity, and surface tension were then measured on a contact-angle measurement instrument. The tensile testing machine was again employed to test the sheer strength of the FSWPUs between the tiles, and a tape test was conducted to analyze their adhesion to the tiles. The results revealed that AEAPTES functional groups can reinforce the thermal stability, tensile strength, and water resistance of FSWPUs. Moreover, the AEAPTES functional groups increased the adhesion of FSWPUs to the tiles and reduced the surface energy of the tiles.

Suggested Citation

  • Yao-Tang Hsu & Wen-Hsin Wang & Wei-Hsi Hung, 2020. "Evaluating the Properties of a Coating Material with Polycaprolactone-Degradable Fluorinated Silicon-Containing Waterborne Polyurethane," Sustainability, MDPI, vol. 12(9), pages 1-15, May.
  • Handle: RePEc:gam:jsusta:v:12:y:2020:i:9:p:3745-:d:354250
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    References listed on IDEAS

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    1. Mateusz Kozicki & Michał Piasecki & Anna Goljan & Halina Deptuła & Adam Niesłochowski, 2018. "Emission of Volatile Organic Compounds (VOCs) from Dispersion and Cementitious Waterproofing Products," Sustainability, MDPI, vol. 10(7), pages 1-16, June.
    2. Lu Deng & Yang Yu & Haiyan Zhang & Qian Wang & Ruide Yu, 2019. "The Effects of Biodegradable Mulch Film on the Growth, Yield, and Water Use Efficiency of Cotton and Maize in an Arid Region," Sustainability, MDPI, vol. 11(24), pages 1-15, December.
    3. Jolanda Palmisani & Alessia Di Gilio & Ezia Cisternino & Maria Tutino & Gianluigi de Gennaro, 2020. "Volatile Organic Compound (VOC) Emissions from a Personal Care Polymer-Based Item: Simulation of the Inhalation Exposure Scenario Indoors under Actual Conditions of Use," Sustainability, MDPI, vol. 12(7), pages 1-13, March.
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    Cited by:

    1. Da-Sheng Zhang & Xiao-Hua Gu & Si-Wen Liu & Yan Liu & Qing-Yun Zhou & Shang-Wen Zhu & Yan-Wei Zhu, 2022. "Study on Properties of Regenerated Fluorinated Polyurethane Rigid Foam Prepared by Degrading Waste Polyurethane," Sustainability, MDPI, vol. 14(23), pages 1-17, November.

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