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Fast Pyrolysis of Four Lignins from Different Isolation Processes Using Py-GC/MS

Author

Listed:
  • Xiaona Lin

    (MOE Key Laboratory of Bio-based Material Science and Technology, Northeast Forestry University, Harbin 150040, Heilongjiang, China)

  • Shujuan Sui

    (MOE Key Laboratory of Bio-based Material Science and Technology, Northeast Forestry University, Harbin 150040, Heilongjiang, China)

  • Shun Tan

    (MOE Key Laboratory of Bio-based Material Science and Technology, Northeast Forestry University, Harbin 150040, Heilongjiang, China)

  • Charles U. Pittman

    (Department of Chemistry, Mississippi State University, Mississippi State, MS 39762, USA)

  • Jianping Sun

    (MOE Key Laboratory of Bio-based Material Science and Technology, Northeast Forestry University, Harbin 150040, Heilongjiang, China
    School of Municipal and Environmental Engineering, Shenyang Jianzhu University, Shenyang 110168, Liaoning, China)

  • Zhijun Zhang

    (MOE Key Laboratory of Bio-based Material Science and Technology, Northeast Forestry University, Harbin 150040, Heilongjiang, China)

Abstract

Pyrolysis is a promising approach that is being investigated to convert lignin into higher value products including biofuels and phenolic chemicals. In this study, fast pyrolysis of four types of lignin, including milled Amur linden wood lignin (MWL), enzymatic hydrolysis corn stover lignin (EHL), wheat straw alkali lignin (AL) and wheat straw sulfonate lignin (SL), were performed using pyrolysis gas-chromatography/mass spectrometry (Py-GC/MS). Thermogravimetric analysis (TGA) showed that the four lignins exhibited widely different thermolysis behaviors. The four lignins had similar functional groups according to the FTIR analysis. Syringyl, guaiacyl and p-hydroxyphenylpropane structural units were broken down during pyrolysis. Fast pyrolysis product distributions from the four lignins depended strongly on the lignin origin and isolation process. Phenols were the most abundant pyrolysis products from MWL, EHL and AL. However, SL produced a large number of furan compounds and sulfur compounds originating from kraft pulping. The effects of pyrolysis temperature and time on the product distributions from corn stover EHL were also studied. At 350 °C, EHL pyrolysis mainly produced acids and alcohols, while phenols became the main products at higher temperature. No obvious influence of pyrolysis time was observed on EHL pyrolysis product distributions.

Suggested Citation

  • Xiaona Lin & Shujuan Sui & Shun Tan & Charles U. Pittman & Jianping Sun & Zhijun Zhang, 2015. "Fast Pyrolysis of Four Lignins from Different Isolation Processes Using Py-GC/MS," Energies, MDPI, vol. 8(6), pages 1-15, June.
    • Handle: RePEc:gam:jeners:v:8:y:2015:i:6:p:5107-5121:d:50495
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    Cited by:

    1. Ha, Jeong-Myeong & Hwang, Kyung-Ran & Kim, Young-Min & Jae, Jungho & Kim, Kwang Ho & Lee, Hyung Won & Kim, Jae-Young & Park, Young-Kwon, 2019. "Recent progress in the thermal and catalytic conversion of lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 422-441.
    2. Guangzai Nong & Zongwen Zhou & Shuangfei Wang, 2015. "Generation of Hydrogen, Lignin and Sodium Hydroxide from Pulping Black Liquor by Electrolysis," Energies, MDPI, vol. 9(1), pages 1-11, December.
    3. Roksana Muzyka & Szymon Sobek & Mariusz Dudziak & Miloud Ouadi & Marcin Sajdak, 2023. "A Comparative Analysis of Waste Biomass Pyrolysis in Py-GC-MS and Fixed-Bed Reactors," Energies, MDPI, vol. 16(8), pages 1-15, April.
    4. Thoharudin, & Hsiau, Shu-San & Chen, Yi-Shun & Yang, Shouyin, 2023. "Design optimization of fluidized bed pyrolysis for energy and exergy analysis using a simplified comprehensive multistep kinetic model," Energy, Elsevier, vol. 276(C).
    5. Asina, FNU & Brzonova, Ivana & Kozliak, Evguenii & Kubátová, Alena & Ji, Yun, 2017. "Microbial treatment of industrial lignin: Successes, problems and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1179-1205.
    6. Huang, Youwang & Wang, Haiyong & Zhang, Xinghua & Zhang, Qi & Wang, Chenguang & Ma, Longlong, 2022. "Accurate prediction of chemical exergy of technical lignins for exergy-based assessment on sustainable utilization processes," Energy, Elsevier, vol. 243(C).
    7. Ryu, Hae Won & Lee, Hyung Won & Jae, Jungho & Park, Young-Kwon, 2019. "Catalytic pyrolysis of lignin for the production of aromatic hydrocarbons: Effect of magnesium oxide catalyst," Energy, Elsevier, vol. 179(C), pages 669-675.
    8. Santos, Catarina I. & Silva, Constança C. & Mussatto, Solange I. & Osseweijer, Patricia & van der Wielen, Luuk A.M. & Posada, John A., 2018. "Integrated 1st and 2nd generation sugarcane bio-refinery for jet fuel production in Brazil: Techno-economic and greenhouse gas emissions assessment," Renewable Energy, Elsevier, vol. 129(PB), pages 733-747.
    9. Nam, Hoseok & Konishi, Satoshi, 2019. "Potentiality of biomass-nuclear hybrid system deployment scenario: Techno-economic feasibility perspective in South Korea," Energy, Elsevier, vol. 175(C), pages 1038-1054.

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