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Oil Extraction from the Spent Coffee Grounds and Its Conversion into Biodiesel

Author

Listed:
  • Rita Harb

    (Department of Chemical and Petroleum Engineering, School of Engineering, Holy Spirit University of Kaslik, Jounieh P.O. Box 446, Lebanon)

  • Lara Salloum Abou Jaoudeh

    (Department of Chemical and Petroleum Engineering, School of Engineering, Holy Spirit University of Kaslik, Jounieh P.O. Box 446, Lebanon)

Abstract

The depletion of fossil fuel reserves and their environmental impact have driven the search for sustainable energy alternatives. Biodiesel has emerged as a promising substitute. Being a major byproduct of the coffee industry, spent coffee grounds (SCGs) offer a viable feedstock due to their abundance, high fatty acid content, and calorific value. This study explores biodiesel production from SCGs. First, oil was experimentally extracted from SCGs using Soxhlet extraction with hexane as the solvent. The oil yield varied between 12 and 13.4% with a density of 0.9 g/mL. Reactor modeling and kinetic analysis were performed, showing that CSTRs in series are favorable for the esterification and transesterification reactions. Furthermore, Aspen Plus was used to simulate the extracted oil conversion into biodiesel through a two-step esterification and purification process. The simulation results are verified against previous experimental research. Sensitivity analyses were performed to evaluate the influence of key process parameters, including methanol-to-oil ratio, reactor residence time, and transesterification temperature. The simulation results indicate an optimal biodiesel mass yield of 90.31%, with a purity of 99.63 wt%, at a methanol-to-oil ratio of 12:1 and a transesterification temperature of 60 °C.

Suggested Citation

  • Rita Harb & Lara Salloum Abou Jaoudeh, 2025. "Oil Extraction from the Spent Coffee Grounds and Its Conversion into Biodiesel," Energies, MDPI, vol. 18(17), pages 1-21, August.
    • Handle: RePEc:gam:jeners:v:18:y:2025:i:17:p:4603-:d:1737806
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    References listed on IDEAS

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    1. M. Mofijur & F. Kusumo & I. M. Rizwanul Fattah & H. M. Mahmudul & M. G. Rasul & A. H. Shamsuddin & T. M. I. Mahlia, 2020. "Resource Recovery from Waste Coffee Grounds Using Ultrasonic-Assisted Technology for Bioenergy Production," Energies, MDPI, vol. 13(7), pages 1-15, April.
    2. Ingryd Mayer Krinski & Vinícius Reisdorfer Leite & Luis Mauro Moura & Viviana Cocco Mariani, 2025. "Critical Extraction Parameters for Maximizing Oil Yield from Spent Coffee Grounds," Energies, MDPI, vol. 18(6), pages 1-17, March.
    3. Abdullah, Mudafer & Bulent Koc, A., 2013. "Oil removal from waste coffee grounds using two-phase solvent extraction enhanced with ultrasonication," Renewable Energy, Elsevier, vol. 50(C), pages 965-970.
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