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Improving Thermal Stability of Perovskite Solar Cells by Thermoplastic Additive Engineering

Author

Listed:
  • Zaheen Uddin

    (College of Materials Science and Engineering, Hunan University, Changsha 410082, China)

  • Junhui Ran

    (College of Materials Science and Engineering, Hunan University, Changsha 410082, China)

  • Elias Stathatos

    (Nanotechnology & Advanced Materials Laboratory, Department of Electrical and Computer Engineering, University of the Peloponnese, 26334 Patras, Greece)

  • Bin Yang

    (College of Materials Science and Engineering, Hunan University, Changsha 410082, China)

Abstract

The commercialization of perovskite solar cells is hindered by the poor thermal stability of organic–inorganic hybrid perovskite materials. Herein, we demonstrate that crystalline thermoplastic polymer additives, such as a mixture of polyethylene oxide (PEO, 100,000 MW) and polyethylene glycol (PEG, 12,000 MW), can improve the thermal stability of CH 3 NH 3 PbI 3 (MAPbI 3 ) perovskites and thereby enhance device stability. High-quality less-defect perovskite films were obtained by establishing a strong reaction between hydroxy groups in the PEO + PEG mixture and the uncoordinated Pb 2+ in MAPbI 3 perovskites, leading to a high power conversion efficiency of over 18% despite the presence of insulating thermoplastic polymers in the MAPbI 3 film. More importantly, as compared with pristine MAPbI 3 perovskite solar cells, the PEO + PEG-modified counterparts showed significantly improved stability under thermal treatment at 85 °C in ambient air with a relative humidity of 50–60%, remaining at nearly 71% of their initial efficiency values after 120 h. These demonstrations offer a feasible thermoplastic polymer additive engineering strategy to improve the thermal stability of perovskite solar cells.

Suggested Citation

  • Zaheen Uddin & Junhui Ran & Elias Stathatos & Bin Yang, 2023. "Improving Thermal Stability of Perovskite Solar Cells by Thermoplastic Additive Engineering," Energies, MDPI, vol. 16(9), pages 1-12, April.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:9:p:3621-:d:1130187
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    1. Jason J. Yoo & Gabkyung Seo & Matthew R. Chua & Tae Gwan Park & Yongli Lu & Fabian Rotermund & Young-Ki Kim & Chan Su Moon & Nam Joong Jeon & Juan-Pablo Correa-Baena & Vladimir Bulović & Seong Sik Shi, 2021. "Efficient perovskite solar cells via improved carrier management," Nature, Nature, vol. 590(7847), pages 587-593, February.
    2. Eui Hyuk Jung & Nam Joong Jeon & Eun Young Park & Chan Su Moon & Tae Joo Shin & Tae-Youl Yang & Jun Hong Noh & Jangwon Seo, 2019. "Efficient, stable and scalable perovskite solar cells using poly(3-hexylthiophene)," Nature, Nature, vol. 567(7749), pages 511-515, March.
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