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Coprecipitation Synthesis and Impedance Studies on Electrode Interface Characteristics of 0.5Li 2 MnO 3 ·0.5Li(Ni 0.44 Mn 0.44 Co 0.12 )O 2 Cathode Material

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  • Xing Zhao

    (China Automotive Engineering Research Institute Co., Ltd., Chongqing 401122, China
    Technology Innovation Center of New Energy Vehicle Digital Supervision, Technology and Application for State Market Regulation, Beijing 100028, China
    Defective Product Administrative Center, State Administration for Market Regulation, Beijing 100088, China)

  • Peng Wang

    (China Automotive Engineering Research Institute Co., Ltd., Chongqing 401122, China
    Technology Innovation Center of New Energy Vehicle Digital Supervision, Technology and Application for State Market Regulation, Beijing 100028, China)

  • Yan Wang

    (Defective Product Administrative Center, State Administration for Market Regulation, Beijing 100088, China)

  • Peipei Chao

    (China Automotive Engineering Research Institute Co., Ltd., Chongqing 401122, China)

  • Honglei Dong

    (Defective Product Administrative Center, State Administration for Market Regulation, Beijing 100088, China)

Abstract

The nanoscale 0.5Li 2 MnO 3 ·0.5Li(Ni 0.44 Mn 0.44 Co 0.12 )O 2 Li-manganese-rich electrode material was synthesized by the co-precipitate method, and its electrochemical properties were systematically analyzed, especially the electrochemical impedance spectroscopy. The failure of the electrode interface and the structural transformation of the material at high potential are the main reasons for the deterioration of the Li-manganese-rich electrode, and high temperatures accelerate the deterioration. Based on the systematic analysis of the induced reactance change with electrode polarization potential, it is found that the induced reactance of a Li-manganese-rich electrode is not only related to the degree of delithiation/lithiation but also has a great relationship with the performance of the electrode/electrolyte interface. This conclusion is beneficial for the manufacturing of battery failure analysis by providing a theoretical basis for guidance.

Suggested Citation

  • Xing Zhao & Peng Wang & Yan Wang & Peipei Chao & Honglei Dong, 2023. "Coprecipitation Synthesis and Impedance Studies on Electrode Interface Characteristics of 0.5Li 2 MnO 3 ·0.5Li(Ni 0.44 Mn 0.44 Co 0.12 )O 2 Cathode Material," Energies, MDPI, vol. 16(16), pages 1-16, August.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:16:p:5919-:d:1214424
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    References listed on IDEAS

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    4. J.-M. Tarascon & M. Armand, 2001. "Issues and challenges facing rechargeable lithium batteries," Nature, Nature, vol. 414(6861), pages 359-367, November.
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