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Phenyl Vinylsulfonate, a Novel Electrolyte Additive to Improve Electrochemical Performance of Lithium-Ion Batteries

Author

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  • Behrooz Mosallanejad

    (Department of Chemistry, Amirkabir University of Technology (Tehran Polytechnic), Tehran 159163-4311, Iran)

  • Mehran Javanbakht

    (Department of Chemistry, Amirkabir University of Technology (Tehran Polytechnic), Tehran 159163-4311, Iran
    Renewable Energy Research Center, Amirkabir University of Technology, Tehran 15916-34311, Iran)

  • Zahra Shariatinia

    (Department of Chemistry, Amirkabir University of Technology (Tehran Polytechnic), Tehran 159163-4311, Iran)

  • Mohammad Akrami

    (Department of Engineering, University of Exeter, Exeter EX4 4QF, UK)

Abstract

Irreversible capacity fading, originating from the formation of the solid electrolyte interphase (SEI), is a common challenge encountered in lithium-ion batteries (LIBs) containing an electrolyte based on ethylene carbonate (EC). In this research, phenyl vinyl sulfonate (PVS) is examined as a novel electrolyte additive to mitigate this issue and subsequently enhance the cyclic stability of LIBs. As evidenced by density functional theory (DFT) calculations, PVS has a higher reduction potential than that of EC, which is in accordance with the cyclic voltammetry (CV) measurements. Accordingly, the PVS-containing electrolyte demonstrated a reduction peak at ~1.9 V, which was higher than that of the electrolyte without an additive (at ~1.7 V). In contrast to the SEI derived from the reference electrolyte, the one built-in PVS-containing electrolyte was capable of completely inhibiting the electrolyte reduction. In terms of the Raman spectroscopy and electrochemical impedance spectroscopy (EIS) analysis, SEI formation as the result of PVS reduction can lead to less structural disorder in the graphite electrode; the battery with the additive showed less interfacial and charge transfer resistance. The Li/graphite cell with 1 wt % of PVS delivered capacity retention much higher than that of its counterpart without the additive after 35 cycles at 1 C.

Suggested Citation

  • Behrooz Mosallanejad & Mehran Javanbakht & Zahra Shariatinia & Mohammad Akrami, 2022. "Phenyl Vinylsulfonate, a Novel Electrolyte Additive to Improve Electrochemical Performance of Lithium-Ion Batteries," Energies, MDPI, vol. 15(17), pages 1-12, August.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:17:p:6205-:d:898327
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    References listed on IDEAS

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    1. Weronika Urbańska & Magdalena Osial, 2020. "Investigation of the Physico-Chemical Properties of the Products Obtained after Mixed Organic-Inorganic Leaching of Spent Li-Ion Batteries," Energies, MDPI, vol. 13(24), pages 1-15, December.
    2. Perveen, Tahira & Siddiq, Muhammad & Shahzad, Nadia & Ihsan, Rida & Ahmad, Abrar & Shahzad, Muhammad Imran, 2020. "Prospects in anode materials for sodium ion batteries - A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
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    4. Shunli Wang & Pu Ren & Paul Takyi-Aninakwa & Siyu Jin & Carlos Fernandez, 2022. "A Critical Review of Improved Deep Convolutional Neural Network for Multi-Timescale State Prediction of Lithium-Ion Batteries," Energies, MDPI, vol. 15(14), pages 1-27, July.
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