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Research Progress in Metal-Organic Framework Based Nanomaterials Applied in Battery Cathodes

Author

Listed:
  • Maria Mechili

    (Laboratory of Inorganic Materials Technology, School of Chemical Engineering, National Technical University of Athens, 9 Heroon Polytechniou Str., Zografou, 15780 Athens, Greece)

  • Christos Vaitsis

    (Laboratory of Inorganic Materials Technology, School of Chemical Engineering, National Technical University of Athens, 9 Heroon Polytechniou Str., Zografou, 15780 Athens, Greece)

  • Nikolaos Argirusis

    (mat4nrg GmbH, Burgstätter Str. 42, 38678 Clausthal-Zellerfeld, Germany)

  • Pavlos K. Pandis

    (Laboratory of Inorganic Materials Technology, School of Chemical Engineering, National Technical University of Athens, 9 Heroon Polytechniou Str., Zografou, 15780 Athens, Greece)

  • Georgia Sourkouni

    (TU Clausthal, Clausthaler Zentrum für Materialtechnologie, Leibnizstr. 9, 38678 Clausthal-Zellerfeld, Germany)

  • Antonis A. Zorpas

    (Laboratory of Chemical Engineering and Engineering Sustainability, Faculty of Pure and Applied Sciences, Open University of Cyprus, 33 Giannou Kranidioti Ave., Latsia, Nicosia 2220, Cyprus)

  • Christos Argirusis

    (Laboratory of Inorganic Materials Technology, School of Chemical Engineering, National Technical University of Athens, 9 Heroon Polytechniou Str., Zografou, 15780 Athens, Greece
    TU Clausthal, Clausthaler Zentrum für Materialtechnologie, Leibnizstr. 9, 38678 Clausthal-Zellerfeld, Germany)

Abstract

Metal-Organic Frameworks have attracted profound attention the latest years for use in environmental applications. They can offer a broad variety of functions due to their tunable porosity, high surface area and metal activity centers. Not more than ten years ago, they have been applied experimentally for the first time in energy storage devices, such as batteries. Specifically, MOFs have been investigated thoroughly as potential materials hosting the oxidizing agent in the cathode electrode of several battery systems such as Lithium Batteries, Metal-Ion Batteries and Metal-Air Batteries. The aim of this review is to provide researchers with a summary of the electrochemical properties and performance of MOFs recently implemented in battery cathodes in order to provide fertile ground for further exploration of performance-oriented materials. In the following sections, the basic working principles of each battery system are briefly defined, and special emphasis is dedicated to MOF-based or MOF-derived nanomaterials, especially nanocomposites, which have been tested as potential battery cathodes.

Suggested Citation

  • Maria Mechili & Christos Vaitsis & Nikolaos Argirusis & Pavlos K. Pandis & Georgia Sourkouni & Antonis A. Zorpas & Christos Argirusis, 2022. "Research Progress in Metal-Organic Framework Based Nanomaterials Applied in Battery Cathodes," Energies, MDPI, vol. 15(15), pages 1-30, July.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:15:p:5460-:d:873781
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    References listed on IDEAS

    as
    1. Qi Liu & Xin Su & Dan Lei & Yan Qin & Jianguo Wen & Fangmin Guo & Yimin A. Wu & Yangchun Rong & Ronghui Kou & Xianghui Xiao & Frederic Aguesse & Javier Bareño & Yang Ren & Wenquan Lu & Yangxing Li, 2018. "Approaching the capacity limit of lithium cobalt oxide in lithium ion batteries via lanthanum and aluminium doping," Nature Energy, Nature, vol. 3(11), pages 936-943, November.
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    3. Mechili, Maria & Vaitsis, Christos & Argirusis, Nikolaos & Pandis, Pavlos K. & Sourkouni, Georgia & Argirusis, Christos, 2022. "Research progress in transition metal oxide based bifunctional electrocatalysts for aqueous electrically rechargeable zinc-air batteries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    4. Hao Tian & Huajun Tian & Shijian Wang & Shuangming Chen & Fan Zhang & Li Song & Hao Liu & Jian Liu & Guoxiu Wang, 2020. "High-power lithium–selenium batteries enabled by atomic cobalt electrocatalyst in hollow carbon cathode," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    5. Hao Tian & Huajun Tian & Shijian Wang & Shuangming Chen & Fan Zhang & Li Song & Hao Liu & Jian Liu & Guoxiu Wang, 2020. "Author Correction: High-power lithium–selenium batteries enabled by atomic cobalt electrocatalyst in hollow carbon cathode," Nature Communications, Nature, vol. 11(1), pages 1-1, December.
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