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Real-Time Monitoring of the Thermal Effect for the Redox Flow Battery by an Infrared Thermal Imaging Technology

Author

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  • Shu-Ling Huang

    (Program in Materials and Chemical Engineering, National United University, Miaoli 36063, Taiwan
    Department of Chemical Engineering, National United University, Miaoli 36063, Taiwan)

  • Chi-Ping Li

    (Department of Chemical Engineering, National United University, Miaoli 36063, Taiwan)

  • Chia-Chin Chang

    (Department of Chemical Engineering, National United University, Miaoli 36063, Taiwan)

  • Chen-Chen Tseng

    (Department of Chemical Engineering, National United University, Miaoli 36063, Taiwan)

  • Ming-Wei Wang

    (Department of Chemical Engineering, National United University, Miaoli 36063, Taiwan)

  • Mei-Ling Chen

    (Department of Electrical Engineering, National United University, Miaoli 36063, Taiwan)

Abstract

In this study, a new monitoring method was developed, titled infrared thermal imaging technology, which can effectively evaluate the thermal effect of the charge-discharge test in the vanadium/iodine redox flow battery (V/I RFB). The results show that the all-vanadium redox flow battery (all-V RFB) has a greater molar reaction Gibbs free energy change than that of the V/I RFB, representing a large thermal effect of the all-V RFB than the V/I RFB. The charge-discharge parameters, flow rate and current density, are important factors for inducing the thermal effect, because of the concentration polarization and the ohmic resistor. The new membrane (HS-SO 3 H) shows a high ion exchange capacity and a good ions crossover inhibitory for the V/I RFB system, and has a high coulomb efficiency that reaches 96%. The voltage efficiency was enhanced from 61% to 86% using the C-TiO 2 -Pd composite electrode as a cathode with the serpentine-type flow field for the V/I RFB. By adopting the high-resolution images of an infrared thermal imaging technology with the function of the temperature profile data, it is useful to evaluate the key components’ performance of the V/I RFB, and is a favorable candidate in the developing of the redox flow battery system.

Suggested Citation

  • Shu-Ling Huang & Chi-Ping Li & Chia-Chin Chang & Chen-Chen Tseng & Ming-Wei Wang & Mei-Ling Chen, 2020. "Real-Time Monitoring of the Thermal Effect for the Redox Flow Battery by an Infrared Thermal Imaging Technology," Energies, MDPI, vol. 13(24), pages 1-19, December.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:24:p:6717-:d:465142
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    References listed on IDEAS

    as
    1. Wei, Zhongbao & Zhao, Jiyun & Xiong, Binyu, 2014. "Dynamic electro-thermal modeling of all-vanadium redox flow battery with forced cooling strategies," Applied Energy, Elsevier, vol. 135(C), pages 1-10.
    2. Guarnieri, Massimo & Trovò, Andrea & Picano, Francesco, 2020. "Enhancing the efficiency of kW-class vanadium redox flow batteries by flow factor modulation: An experimental method," Applied Energy, Elsevier, vol. 262(C).
    3. Zheng, Qiong & Zhang, Huamin & Xing, Feng & Ma, Xiangkun & Li, Xianfeng & Ning, Guiling, 2014. "A three-dimensional model for thermal analysis in a vanadium flow battery," Applied Energy, Elsevier, vol. 113(C), pages 1675-1685.
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