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Study on thermal efficiency of low- to medium-temperature organic Rankine cycles using HFO−1234yf

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  • Yamada, Noboru
  • Mohamad, Md Nor Anuar
  • Kien, Trinh Trung

Abstract

HFO−1234yf is a new refrigerant with a nearly zero global warming potential (GWP) and ozone depletion potential (ODP); it exhibits thermodynamic properties similar to HFC−134a. The potential of HFO−1234yf as a working fluid for organic Rankine cycles (ORC) is elucidated through a first-order simulation. A fundamental thermodynamic model of ORC with five types of cycles—trilateral, saturated, superheated, sub-critical, and supercritical—is used to compare the thermal efficiency of HFO−1234yf with that of other working fluids. HFO−1234yf was found to offer a thermal efficiency that was comparable to that of HFC−134a. This paper provides a useful map that clearly shows the best possible thermal efficiency among the five types of cycles for various expander inlet and condensation temperatures. The highest thermal efficiency range (8.8%–11.4%) was obtained when the supercritical ORC was used at an expander inlet temperature of 170 ± 10 °C and a condensation temperature range of 20–40 °C for the given pump and expander efficiency. It is concluded that HFO−1234yf is a potential working fluid for ORC applications, especially for those with low- to medium-temperature heat sources.

Suggested Citation

  • Yamada, Noboru & Mohamad, Md Nor Anuar & Kien, Trinh Trung, 2012. "Study on thermal efficiency of low- to medium-temperature organic Rankine cycles using HFO−1234yf," Renewable Energy, Elsevier, vol. 41(C), pages 368-375.
    • Handle: RePEc:eee:renene:v:41:y:2012:i:c:p:368-375
    DOI: 10.1016/j.renene.2011.11.028
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    1. Lecompte, S. & Huisseune, H. & van den Broek, M. & De Paepe, M., 2015. "Methodical thermodynamic analysis and regression models of organic Rankine cycle architectures for waste heat recovery," Energy, Elsevier, vol. 87(C), pages 60-76.
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    6. Chen, Yubo & Yang, Zhao & Lv, Zijian & Zhang, Yong & Li, Jie & Fei, Teng, 2023. "Combustion mechanism and product characteristics of 2,3,3,3-tetrafluoropropene as an environmentally friendly working fluid for organic Rankine cycle," Energy, Elsevier, vol. 268(C).
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    14. Zhang, Cheng & Liu, Chao & Xu, Xiaoxiao & Li, Qibin & Wang, Shukun, 2019. "Energetic, exergetic, economic and environmental (4E) analysis and multi-factor evaluation method of low GWP fluids in trans-critical organic Rankine cycles," Energy, Elsevier, vol. 168(C), pages 332-345.
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    18. Yang, Jingye & Ye, Zhenhong & Yu, Binbin & Ouyang, Hongsheng & Chen, Jiangping, 2019. "Simultaneous experimental comparison of low-GWP refrigerants as drop-in replacements to R245fa for Organic Rankine cycle application: R1234ze(Z), R1233zd(E), and R1336mzz(E)," Energy, Elsevier, vol. 173(C), pages 721-731.
    19. Moloney, Francesca & Almatrafi, Eydhah & Goswami, D.Y., 2020. "Working fluid parametric analysis for recuperative supercritical organic Rankine cycles for medium geothermal reservoir temperatures," Renewable Energy, Elsevier, vol. 147(P3), pages 2874-2881.
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    22. Yazawa, Kazuaki & Koh, Yee Rui & Shakouri, Ali, 2013. "Optimization of thermoelectric topping combined steam turbine cycles for energy economy," Applied Energy, Elsevier, vol. 109(C), pages 1-9.
    23. Giuffrida, Antonio, 2018. "A theoretical study on the performance of a scroll expander in an organic Rankine cycle with hydrofluoroolefins (HFOs) in place of R245fa," Energy, Elsevier, vol. 161(C), pages 1172-1180.

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