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Transesterificarion of soybean oil using ethanol and mesoporous silica catalyst

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  • Quintella, Solange A.
  • Saboya, Rosana M.A.
  • Salmin, Davi C.
  • Novaes, Denise S.
  • Araújo, Antonio S.
  • Albuquerque, Monica C.G.
  • Cavalcante, Célio L.

Abstract

Mesoporous silica catalyst was evaluated in the ethanolysis of soybean oil. Ethanol can be environmentally advantageous over methanol (more frequently used as reagent in biodiesel production) because it can be obtained from renewable sources whilst methanol is usually derived from mineral sources. A silica molecular sieve containing lanthanum oxide as active phase (La50SBA-15) was obtained by isomorphous substitution into the SBA-15 network using Pluronic (P123) dissolved in aqueous HCl solution with tetraethyl orthosilicate and a given amount of hydrated lanthanum chloride (Si:La = 50) at 333 K. The reaction was performed using the molar ratio ethanol:soybean oil of 20:1 at inert atmosphere (N2) at 343 K with 1wt% of catalyst mass relative to total oil mass added to the reaction mixture. The reaction was evaluated for ethyl ester conversion after 6 h. The ethyl esters content was measured using low frequency 1H NMR spectroscopy (60 MHz). The La50SBA-15 heterogeneous catalyst presented conversion of soybean oil in ethyl esters as high as 80% after reaction time of 6 h., comparing well with previous reports for methanolysis of soybean oil. Moreover, lixiviation of the active phase was not observed, thus excluding the contribution of the homogeneous catalysis to the studied transesterification process.

Suggested Citation

  • Quintella, Solange A. & Saboya, Rosana M.A. & Salmin, Davi C. & Novaes, Denise S. & Araújo, Antonio S. & Albuquerque, Monica C.G. & Cavalcante, Célio L., 2012. "Transesterificarion of soybean oil using ethanol and mesoporous silica catalyst," Renewable Energy, Elsevier, vol. 38(1), pages 136-140.
  • Handle: RePEc:eee:renene:v:38:y:2012:i:1:p:136-140
    DOI: 10.1016/j.renene.2011.07.011
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    References listed on IDEAS

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    1. Basha, Syed Ameer & Gopal, K. Raja & Jebaraj, S., 2009. "A review on biodiesel production, combustion, emissions and performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1628-1634, August.
    2. Meher, L.C. & Vidya Sagar, D. & Naik, S.N., 2006. "Technical aspects of biodiesel production by transesterification--a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(3), pages 248-268, June.
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    1. Amani, H. & Ahmad, Z. & Hameed, B.H., 2014. "Synthesis of fatty acid methyl esters via the methanolysis of palm oil over Ca3.5xZr0.5yAlxO3 mixed oxide catalyst," Renewable Energy, Elsevier, vol. 66(C), pages 680-685.
    2. Bet-Moushoul, Elsie & Farhadi, Khalil & Mansourpanah, Yaghoub & Molaie, Rahim & Forough, Mehrdad & Nikbakht, Ali Mohammad, 2016. "Development of novel Ag/bauxite nanocomposite as a heterogeneous catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 92(C), pages 12-21.

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