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Effect of nanoscale zero-valent iron on sludge anaerobic digestion

Author

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  • Jia, Tongtong
  • Wang, Zaizhao
  • Shan, Haiqiang
  • Liu, Yuanfeng
  • Gong, Lei

Abstract

Nanoscale zero-valent iron(NZVI) was prepared with a method of reduction in liquid phase by the reaction of FeSO4 and NaBH4, and characterized by SEM. This study investigated the effect of different concentration of NZVI on biogas production and methane content during the anaerobic digestion process at the medium temperature of 35°C. The results indicated that the group with 1000mg/L NZVI maintained ammonia at the level of 600–800mg/L, pH between 6.5-8.0, and improved CODcr degradation rates at 2.91%; this concentration of NZVI produced maximum concentration of VFAs, which can reach 3846mg/L, and strengthen the use of acetic acid. Relative to the control group, the system increased cumulative biogas production of 18.11%, decreased biogas production cycles of three days and increased the methane content by 6.93%.

Suggested Citation

  • Jia, Tongtong & Wang, Zaizhao & Shan, Haiqiang & Liu, Yuanfeng & Gong, Lei, 2017. "Effect of nanoscale zero-valent iron on sludge anaerobic digestion," Resources, Conservation & Recycling, Elsevier, vol. 127(C), pages 190-195.
    • Handle: RePEc:eee:recore:v:127:y:2017:i:c:p:190-195
    DOI: 10.1016/j.resconrec.2017.09.007
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    References listed on IDEAS

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    1. Li, Yebo & Park, Stephen Y. & Zhu, Jiying, 2011. "Solid-state anaerobic digestion for methane production from organic waste," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 821-826, January.
    2. Madsen, Michael & Holm-Nielsen, Jens Bo & Esbensen, Kim H., 2011. "Monitoring of anaerobic digestion processes: A review perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(6), pages 3141-3155, August.
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    1. Luiza Usevičiūtė & Tomas Januševičius & Vaidotas Danila & Aušra Mažeikienė & Alvydas Zagorskis & Mantas Pranskevičius & Eglė Marčiulaitienė, 2025. "Performance and Kinetics of Anaerobic Digestion of Sewage Sludge Amended with Zero-Valent Iron Nanoparticles, Analyzed Using Sigmoidal Models," Energies, MDPI, vol. 18(6), pages 1-24, March.
    2. Dar, Rouf Ahmad & Tsui, To-Hung & Zhang, Le & Smoliński, Adam & Tong, Yen Wah & Mohamed Rasmey, Abdel-Hamied & Liu, Ronghou, 2025. "Recent achievements in magnetic-field-assisted anaerobic digestion for bioenergy production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 207(C).
    3. Youzhou Jiao & Huizan Xue & Chao He & Zigang Wang & Xiaoran Ma & Xinxin Liu & Liang Liu & Chun Chang & Francesco Petracchini & Panpan Li, 2022. "Effect of combined addition amount of nano zero-valent iron and biochar on methane production by anaerobic digestion of corn straw," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 24(4), pages 4709-4726, April.
    4. Cerrillo, Míriam & Burgos, Laura & Ruiz, Beatriz & Barrena, Raquel & Moral-Vico, Javier & Font, Xavier & Sánchez, Antoni & Bonmatí, August, 2021. "In-situ methane enrichment in continuous anaerobic digestion of pig slurry by zero-valent iron nanoparticles addition under mesophilic and thermophilic conditions," Renewable Energy, Elsevier, vol. 180(C), pages 372-382.
    5. Cerrillo, Míriam & Guivernau, Miriam & Burgos, Laura & Riau, Victor & Bonmatí, August, 2025. "Nano zerovalent iron boosts methane content in biogas and reshapes microbial communities in long-term anaerobic digestion of pig slurry," Renewable Energy, Elsevier, vol. 239(C).
    6. Lingling Wei & Jinquan Wan & Zhicheng Yan & Yan Wang, 2025. "Fe-N-Modified Sludge Biochar for Enhanced Acetic Acid Production from Sludge Anaerobic Fermentation," Sustainability, MDPI, vol. 17(7), pages 1-16, April.

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