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The viscosity of argon at high densities

Author

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  • van der Gulik, P.S.
  • Trappeniers, N.J.

Abstract

The viscosity coefficient of argon has been measured at 174.45 K as a function of pressure from 161 up to 4707 bar, including the melting point at 4637 bar and one data point in the supercooled region. Use was made of a vibrating wire viscometer described in a previous paper. The reduced data have been compared with results obtained from molecular dynamics calculations and the agreement is found to be satisfactory. Following the Batschinski-Hildebrand representation it was found that the present results, as well as earlier reported data measured at higher temperatures, can be described by three different linear relations between the fluidity and the molar volume, corresponding to three adjacent volume ranges, covering half the experimental density range. A further analysis shows that, while at intermediate densities the viscosity may be described by the Enskog formalism, at higher densities the behaviour of η is markedly influenced by correlated motions of the molecules.

Suggested Citation

  • van der Gulik, P.S. & Trappeniers, N.J., 1986. "The viscosity of argon at high densities," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 135(1), pages 1-20.
  • Handle: RePEc:eee:phsmap:v:135:y:1986:i:1:p:1-20
    DOI: 10.1016/0378-4371(86)90103-2
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    References listed on IDEAS

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    1. Mesnard, Guy & Hien, Vo Hoang & Vidal, Jean, 1973. "Stabilite des calculateurs a reseaux comportant des resistances negatives," Mathematics and Computers in Simulation (MATCOM), Elsevier, vol. 15(3), pages 92-96.
    2. Fritzsche, Bernd & Heilemann, Ullrich & von Loeffelholz, Hans Dietrich, 1984. "Was bringen die Pläne zur Steuerreform?," Wirtschaftsdienst – Zeitschrift für Wirtschaftspolitik (1949 - 2007), ZBW - Leibniz Information Centre for Economics, vol. 64(6), pages 278-286.
    3. Loeff, Sybrand Schim van der & Harkema, Rins, 1981. "Estimation and testing of alternative production function models," Journal of Macroeconomics, Elsevier, vol. 3(1), pages 33-53.
    4. Daniels, Mark R, 1969. "Differences in Efficiency among Industries in Developing Countries," American Economic Review, American Economic Association, vol. 59(1), pages 159-171, March.
    5. Vermesse, J. & Provansal, M. & Brielles, J., 1978. "Mesure de la viscosite du krypton gazeux dense pres de la solidification, et comparaison avec une simulation sur ordinateur," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 92(1), pages 282-294.
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    Cited by:

    1. van der Gulik, P.S., 1997. "Viscosity of carbon dioxide in the liquid phase," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 238(1), pages 81-112.
    2. Mostert, R. & van der Gulik, P.S. & van den Berg, H.R., 1989. "The working equations of a vibrating wire viscometer," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 156(3), pages 909-920.
    3. Schouten, J.A. & Van Der Putten, L., 1989. "The thermodynamic discontinuities ΔS, ΔH, ΔV, and the melting line of molecular systems at high pressure," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 156(1), pages 303-324.
    4. Vos, Willem L. & Schouten, Jan A., 1992. "The phase diagram of the binary mixture nitrogen-helium at high pressure," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 182(3), pages 365-387.
    5. Mostert, R. & van der Gulik, P.S. & van den Berg, H.R., 1989. "Comment on the experimental viscosity of argon at high densities," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 156(3), pages 921-923.

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