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Raman analysis on methane production from natural gas hydrate by carbon dioxide–methane replacement

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  • Xu, Chun-Gang
  • Cai, Jing
  • Lin, Fu-hua
  • Chen, Zhao-Yang
  • Li, Xiao-Sen

Abstract

Using CO2–CH4 (carbon dioxide–methane) replacement to produce CH4 from NGH (natural gas hydrate) is not only a new CH4 production technology but also a direct way to disposal CO2 by CO2 hydrates. Although there are many studies focusing on the mechanism of CH4 replacement in hydrates by CO2, the mechanism of the replacement is still not clear. In this work, the replacement process and hydrate structure change are tracked and investigated by Raman and NMR (nuclear magnetic resonance) spectra. By comprehensively analyzing the Raman and NMR spectra, we infer the mechanism of the replacement and the hydrate structures. Conclusions are drawn as, on one hand, CH4 molecules are fully replaced with the gas–solid interface, but partly replaced in deeply inner hydrates by CO2 molecules; on the other hand, the CO2 hydrate and CH4 hydrate coexist in a type of structure I (sI) and there is no structure transformation during the replacement. The research results are important to further confirm the mechanism of the replacement and reveal factors restraining efficiency of the CH4 production.

Suggested Citation

  • Xu, Chun-Gang & Cai, Jing & Lin, Fu-hua & Chen, Zhao-Yang & Li, Xiao-Sen, 2015. "Raman analysis on methane production from natural gas hydrate by carbon dioxide–methane replacement," Energy, Elsevier, vol. 79(C), pages 111-116.
    • Handle: RePEc:eee:energy:v:79:y:2015:i:c:p:111-116
    DOI: 10.1016/j.energy.2014.10.068
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    7. Cai, Jing & Zhang, Yu & Xu, Chun-Gang & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen, 2018. "Raman spectroscopic studies on carbon dioxide separation from fuel gas via clathrate hydrate in the presence of tetrahydrofuran," Applied Energy, Elsevier, vol. 214(C), pages 92-102.
    8. Lin, Decai & Lu, Jingsheng & Liu, Jia & Liang, Deqing & Li, Dongliang & Jin, Guangrong & Xia, Zhiming & Li, Xiaosen, 2023. "Numerical study on natural gas hydrate production by hot water injection combined with depressurization," Energy, Elsevier, vol. 282(C).
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    10. Choi, Wonjung & Lee, Yohan & Mok, Junghoon & Seo, Yongwon, 2020. "Influence of feed gas composition on structural transformation and guest exchange behaviors in sH hydrate – Flue gas replacement for energy recovery and CO2 sequestration," Energy, Elsevier, vol. 207(C).
    11. Jyoti Shanker Pandey & Charilaos Karantonidis & Adam Paul Karcz & Nicolas von Solms, 2020. "Enhanced CH 4 -CO 2 Hydrate Swapping in the Presence of Low Dosage Methanol," Energies, MDPI, vol. 13(20), pages 1-30, October.
    12. Song, Rui & Sun, Shuyu & Liu, Jianjun & Yang, Chunhe, 2021. "Pore scale modeling on dissociation and transportation of methane hydrate in porous sediments," Energy, Elsevier, vol. 237(C).
    13. Pivezhani, Farzane & Roosta, Hadi & Dashti, Ali & Mazloumi, S. Hossein, 2016. "Investigation of CO2 hydrate formation conditions for determining the optimum CO2 storage rate and energy: Modeling and experimental study," Energy, Elsevier, vol. 113(C), pages 215-226.
    14. Cai, Jing & Xu, Chun-Gang & Lin, Fu-Hua & Yu, Hai-Zhu & Li, Xiao-Sen, 2016. "A novel method for evaluating effects of promoters on hydrate formation," Energy, Elsevier, vol. 102(C), pages 567-575.
    15. Li, Xiao-Yan & Wan, Kun & Wang, Yi & Li, Xiao-Sen, 2022. "The double-edged characteristics of the soaking time during hydrate dissociation by periodic depressurization combined with hot water injection," Applied Energy, Elsevier, vol. 325(C).
    16. Sergey Misyura & Pavel Strizhak & Anton Meleshkin & Vladimir Morozov & Olga Gaidukova & Nikita Shlegel & Maria Shkola, 2023. "A Review of Gas Capture and Liquid Separation Technologies by CO 2 Gas Hydrate," Energies, MDPI, vol. 16(8), pages 1-20, April.
    17. Chen, Xuejun & Lu, Hailong & Gu, Lijuan & Shang, Shilong & Zhang, Yi & Huang, Xin & Zhang, Le, 2022. "Preliminary evaluation of the economic potential of the technologies for gas hydrate exploitation," Energy, Elsevier, vol. 243(C).
    18. Lee, Yohan & Lee, Dongyoung & Lee, Jong-Won & Seo, Yongwon, 2016. "Enclathration of CO2 as a co-guest of structure H hydrates and its implications for CO2 capture and sequestration," Applied Energy, Elsevier, vol. 163(C), pages 51-59.
    19. Huang, Li & Su, Zheng & Wu, Neng-You, 2015. "Evaluation on the gas production potential of different lithological hydrate accumulations in marine environment," Energy, Elsevier, vol. 91(C), pages 782-798.
    20. Xuke Ruan & Xiao-Sen Li & Chun-Gang Xu, 2017. "Numerical Investigation of the Production Behavior of Methane Hydrates under Depressurization Conditions Combined with Well-Wall Heating," Energies, MDPI, vol. 10(2), pages 1-17, January.
    21. Li, Xiao-Sen & Xu, Chun-Gang & Zhang, Yu & Ruan, Xu-Ke & Li, Gang & Wang, Yi, 2016. "Investigation into gas production from natural gas hydrate: A review," Applied Energy, Elsevier, vol. 172(C), pages 286-322.
    22. Xu, Chun-Gang & Xie, Wen-Jun & Chen, Guo-Shu & Yan, Xiao-Xue & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2020. "Study on the influencing factors of gas consumption in hydrate-based CO2 separation in the presence of CP by Raman analysis," Energy, Elsevier, vol. 198(C).
    23. Zhou, Xuebing & Li, Dongliang & Zhang, Shaohong & Liang, Deqing, 2017. "Swapping methane with carbon dioxide in spherical hydrate pellets," Energy, Elsevier, vol. 140(P1), pages 136-143.

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